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Formation and stabilization mechanism of a nano crystalline phase of Y doped BaZrO3 formed at high temperature

Research Project

Project/Area Number 24760604
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Material processing/treatments
Research InstitutionNational Institute of Technology, Toyama College

Principal Investigator

OYAMA Yukiko  富山高等専門学校, 物質化学工学科, 准教授 (00345373)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2012: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywordsプロトン伝導性酸化物 / ナノ結晶 / プロトン伝導体
Research Abstract

Y doped BaZrO3 (BZ) is one of the candidate materials for the proton conductive oxide with a superior chemical stability in addition to the highest conductivity. The formation mechanism of the nano crystalline phase of Y doped BaZrO3 phase was investigated for improving the grain boundary property which is the one of the problems to be overcome for application of the material. Because the nano crystalline phase which formed after long time 1600 degree C sintering process would be formed from the liquid chose as target phase, the different cooling period from 1600 to 800 degree C after 10h sintering at 1600 degree C was set for the sample preparation. The effect of the cooling period was shown in the composition change due to the BaO evaporation and dopant concentration in the BaZrO3 phase. The effect of liquid phase from the local inhomogeneous composition was also observed.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (2 results)

All 2012

All Presentation (2 results)

  • [Presentation] Crystal Chemistory of Heavily Y- doped BaZrO_3 with orderd superlattice structure2012

    • Author(s)
      Y. Oyama, T. Tsurui, T. Tsuchiya, and S. Yamaguchi
    • Organizer
      The 16th International conference on Solid State ProtonConductor
    • Place of Presentation
      Grenoble, France
    • Related Report
      2013 Final Research Report
  • [Presentation] Crystal Chemistory of Heavily Y- doped BaZrO3 with orderd superlattice structur2012

    • Author(s)
      Y. Oyama, T. Tsurui, T. Tsuchiya, and S. Yamaguchi
    • Organizer
      The 16th International conference on Solid State Proton Conductor
    • Place of Presentation
      Grenoble, France
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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