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Thermodynamics for rare earth oxide and rare earth oxyfluoride and its application to recycling of rare earth wastes

Research Project

Project/Area Number 24760612
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Metal making engineering
Research InstitutionTohoku University

Principal Investigator

TAKEDA Osamu  東北大学, 工学(系)研究科(研究院), 助教 (60447141)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2012: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywords希土類 / レアアース / リサイクル / 酸化弗化物 / 熱力学データ / 標準生成ギブズ自由エネルギー変化 / 磁石
Research Abstract

The purpose of this study is determining standard Gibbs free energy change of oxyfluoride of rare earths that is essential for the development of recycling process of rare earth sintered magnet. From a series of study, standard Gibbs free energy changes of oxyfluoride of lanthanum, neodymium, samarium, and dysprosium were determined. It was considered that the thermodynamic stability of oxyfluoride is greatly affected by the chemical affinity between rare earth cation and oxide ion.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (11 results)

All 2014 2013 2012

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (5 results)

  • [Journal Article] Recycling of Rare Earth Magnet Waste by Removing Rare Earth Oxide with Molten Fluoride2014

    • Author(s)
      Osamu Takeda, Kiyotaka Nakano, Yuzuru Sato
    • Journal Title

      Mater. Trans.

      Volume: Vol. 55 Pages: 334-341

    • NAID

      130004825145

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Recycling of Rare Earth Magnet Waste by Removing Rare Earth Oxide with Molten Fluoride2014

    • Author(s)
      Osamu Takeda, Kiyotaka Nakano and Yuzuru Sato
    • Journal Title

      MATERIALS TRANSACTIONS

      Volume: 55 Issue: 2 Pages: 334-341

    • DOI

      10.2320/matertrans.M-M2013836

    • NAID

      130004825145

    • ISSN
      1345-9678, 1347-5320
    • Related Report
      2013 Annual Research Report
  • [Journal Article] レアアースの乾式製錬とリサイクル2012

    • Author(s)
      竹田修、岡部徹
    • Journal Title

      自動車技術

      Volume: 66巻 Pages: 68-73

    • NAID

      10031128310

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 金属資源有効利用のための熱力学からのアプローチ―鉄鋼,銅,鉛の乾式製錬プロセスにおける元素の分配―2012

    • Author(s)
      竹田修、中島謙一、三木貴博
    • Journal Title

      金属

      Volume: 82巻 Pages: 616-619

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] 金属資源有効利用のための熱力学からのアプローチ ―鉄鋼,銅,鉛の乾式製錬プロセスにおける元素の分配―2012

    • Author(s)
      竹田修,中島謙一,三木貴博
    • Journal Title

      金属

      Volume: 82 Pages: 616-619

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] レアアースの乾式製錬とリサイクル2012

    • Author(s)
      竹田修,岡部徹
    • Journal Title

      自動車技術

      Volume: 66 Pages: 68-73

    • NAID

      10031128310

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 起電力法によるLnOF (Ln = Nd, Dy, La)の標準生成ギブズエネルギー変化の決定2014

    • Author(s)
      竹田修、加藤雅博、鵜飼竜史、佐藤讓、朱鴻民
    • Organizer
      資源・素材学会平成26年度春季大会
    • Place of Presentation
      東京大学生産技術研究所
    • Related Report
      2013 Final Research Report
  • [Presentation] 起電力法によるLnOF(Ln = Nd, Dy, La)の標準生成ギブズエネルギー変化の決定2014

    • Author(s)
      竹田 修、加藤 雅博、鵜飼竜史、佐藤 讓、朱鴻民
    • Organizer
      資源・素材学会 平成26年度春季大会
    • Place of Presentation
      東京大学 生産技術研究所
    • Related Report
      2013 Annual Research Report
  • [Presentation] 起電力法による希土類酸化弗化物の標準生成ギブズエネルギー変化の決定2013

    • Author(s)
      鵜飼竜史、竹田修、佐藤讓
    • Organizer
      日本鉄鋼協会秋季大会(165回)
    • Place of Presentation
      東京電機大学
    • Related Report
      2013 Final Research Report 2012 Research-status Report
  • [Presentation] LnOF (Ln = Nd, Dy, La)の標準生成ギブズエネルギー変化の決定2012

    • Author(s)
      竹田修、加藤雅博、佐藤讓
    • Organizer
      日本鉄鋼協会秋季大会(164回)
    • Place of Presentation
      愛媛大学城北キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] LnOF(Ln=Nd,Dy,La)の標準生成ギブズエネルギー変化の決定2012

    • Author(s)
      竹田修,加藤雅博,佐藤讓
    • Organizer
      日本鉄鋼協会秋季大会(164回)
    • Place of Presentation
      愛媛大学城北キャンパス
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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