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Fundamental study on production process of solar-grade silicon utilizing metal hydrides

Research Project

Project/Area Number 24760615
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Metal making engineering
Research InstitutionKyoto University

Principal Investigator

YASUDA Kouji  京都大学, エネルギー科学研究科, 助教 (20533665)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsシリコン / 還元 / カルシウム / マグネシウム / 水素化物 / 酸化物
Outline of Final Research Achievements

With the recent progress of photovoltaics and solar cell industries, new production process of solar-grade silicon with high productivity is required. In this work, a silicon production process based on a thermite reaction of silicon oxide, which includes simultaneous reduction and refining reactions, was investigated. Through the observation of the silicon products and analysis on in-situ temperature measurement using a thermocouple and a pyrometer, it was found that the produced silicon was melting during the reduction and the temperature was higher than its melting point. The distribution of the impurity elements between the silicon and the oxide byproduct phases was analyzed.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (12 results)

All 2014 2013 2012

All Presentation (12 results)

  • [Presentation] Production of Si in Thermite Reaction of Silica Using Alkaline Earth Metals2014

    • Author(s)
      Kouji Yasuda, Daichi Itakura, Yohsuke Mizutani, Toshiyuki Nohira, Rika Hagiwara and Takayuki Homma
    • Organizer
      The 6th World Conference on Photovoltaic Energy Conversion
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2014-11-23 – 2014-11-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] マグネシウム粉末と水素化マグネシウム粉末によるシリカの還元2013

    • Author(s)
      板倉大地、安田幸司、野平俊之、萩原理加、本間敬之
    • Organizer
      第65回マテリアルズ・テーラリング研究会
    • Place of Presentation
      軽井沢
    • Related Report
      2013 Research-status Report
  • [Presentation] シリカとアルカリ土類金属のテルミット反応によるシリコン生成とその場温度測定2013

    • Author(s)
      板倉大地、安田幸司、野平俊之、萩原理加、本間敬之
    • Organizer
      資源・素材学会平成25年度秋季大会
    • Place of Presentation
      北海道大学
    • Related Report
      2013 Research-status Report
  • [Presentation] アルカリ土類金属およびアルカリ土類金属水素化物とシリカのテルミット反応によるシリコン製造2013

    • Author(s)
      板倉大地、水谷陽介、安田幸司、野平俊之、萩原理加、本間敬之
    • Organizer
      平成25年度第3回関西電気化学研究会
    • Place of Presentation
      産業技術総合研究所 関西センター
    • Related Report
      2013 Research-status Report
  • [Presentation] New Production Process of Silicon Using Fine Powders of Silica and Calcium Hydride2013

    • Author(s)
      Yohsuke Mizutani, Kouji Yasuda, Toshiyuki Nohira, Rika Hagiwara and Takayuki Homma
    • Organizer
      The 8th Workshop on Reactive Metal Processing
    • Place of Presentation
      Cambridge, USA
    • Related Report
      2012 Research-status Report
  • [Presentation] Oxide Metallurgy for the Production of Silicon2013

    • Author(s)
      Kouji Yasuda, Toshiyuki Nohira, Rika Hagiwara
    • Organizer
      The 8th Workshop on Reactive Metal Processing
    • Place of Presentation
      Cambridge, USA
    • Related Report
      2012 Research-status Report
  • [Presentation] 水素化物の熱分解により得たマグネシウム粉末によるシリカの還元2013

    • Author(s)
      板倉大地、水谷陽介、安田幸司、野平俊之、萩原理加、本間敬之
    • Organizer
      資源・素材学会平成25年度春季大会
    • Place of Presentation
      千葉工業大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 水素化アルカリ土類金属の微粉末を用いたシリカ還元によるシリコン製造法2012

    • Author(s)
      水谷陽介、板倉大地、安田幸司、野平俊之、萩原理加、本間敬之
    • Organizer
      第62回マテリアルズ・テーラリング研究会
    • Place of Presentation
      軽井沢
    • Related Report
      2012 Research-status Report
  • [Presentation] Production Process of Silicon by Reduction of Silica Using Calcium Hydride2012

    • Author(s)
      Yohsuke Mizutani, Kouji Yasuda, Toshiyuki Nohira, Rika Hagiwara and Takayuki Homma
    • Organizer
      KIFEE Workshop on Environment, Energy and Materials
    • Place of Presentation
      Trondheim, Norway
    • Related Report
      2012 Research-status Report
  • [Presentation] シリカおよび水素化カルシウム微粉末を用いた新規シリコン製造法の開発2012

    • Author(s)
      水谷陽介、安田幸司、野平俊之、萩原理加、本間敬之
    • Organizer
      資源・素材学会平成24年度秋季大会
    • Place of Presentation
      秋田大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 金属マグネシウムおよび水素化マグネシウムとシリカを用いたシリコン製造法2012

    • Author(s)
      板倉大地、水谷陽介、安田幸司、野平俊之、萩原理加、本間敬之
    • Organizer
      資源・素材学会関西支部第9回若手研究者・学生のための研究発表会
    • Place of Presentation
      京都大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 水素化カルシウムを還元剤に用いた二酸化ケイ素からのシリコン製造法2012

    • Author(s)
      水谷陽介、安田幸司、野平俊之、萩原理加、本間敬之
    • Organizer
      平成24年度第3回関西電気化学研究会
    • Place of Presentation
      京都大学
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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