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surface tension of molten alloys inconsideration of influence of oxygen activity

Research Project

Project/Area Number 24760617
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Metal making engineering
Research InstitutionChiba Institute of Technology

Principal Investigator

OZAWA Shumpei  千葉工業大学, 工学部, 准教授 (80404937)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords表面張力 / 高温融体 / 酸素活量 / 金属融体 / 電磁浮遊法 / 高温金属融体 / 合金融体 / 酸素分圧
Outline of Final Research Achievements

Surface tension of molten metals and alloys were measured by the electromagnetic levitation technique over wide temperature range in consideration of influence of oxygen activity. When oxygen activity was fixed at comparatively high value, boomerang shape temperature dependence of surface tension was observed for molten iron, nickel, and copper.
When the H2-containing gas with a constant concentration was used as an atmosphere for the measurement, a peculiar kink was discovered in the temperature dependence of surface tension for molten iron and nickel. It was explained by considering the competition between the temperature dependence of oxygen activity and that of the equilibrium constant of oxygen adsorption.
Since surface tension of molten silicon is lower than that of molten iron, it was expected that the surface tension of molten Fe-Si alloy is decreased with increasing silicon concentration. However increases of silicon concentration induced higher surface tension of molten sample.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (22 results)

All 2014 2013 2012 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 3 results) Presentation (15 results) (of which Invited: 2 results)

  • [Journal Article] Influence of Oxygen Adsorption on Surface Tension of Molten Nickel Measured under Reducing Gas Atmosphere2014

    • Author(s)
      S. Ozawa, S. Takahashi, N. Watanabe, and H. Fukuyama
    • Journal Title

      International Journal of Thermophysics

      Volume: 35 Issue: 9-10 Pages: 1705-1711

    • DOI

      10.1007/s10765-014-1674-5

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Influence of Oxygen Partial Pressure on Surface Tension of Molten Type 304 and 316 Stainless Steels Measured by Oscillating Droplet Method Using Electromagnetic Levitation2014

    • Author(s)
      S. Ozawa, K. Morohoshi, and T. Hibiya
    • Journal Title

      ISIJ International

      Volume: 54 Issue: 9 Pages: 2097-2103

    • DOI

      10.2355/isijinternational.54.2097

    • NAID

      130004694565

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Surface Tension Measurements of 430 Stainless Steel2014

    • Author(s)
      J. Choe, H. G. Kim, Y. Jeon, H. J. Park, Y. Kang, S. Ozawa, J. Lee
    • Journal Title

      ISIJ International

      Volume: 54 Issue: 9 Pages: 2104-2108

    • DOI

      10.2355/isijinternational.54.2104

    • NAID

      130004694566

    • ISSN
      0915-1559, 1347-5460
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Influence of Oxygen Partial Pressure on Surface Tension of Molten Type 304 and 316 Stainless Steels Measured by Oscillating Droplet Method using Electromagnetic Levitation2014

    • Author(s)
      S. Ozawa, K. Morohoshi, and T. Hibiya
    • Journal Title

      ISIJ international

      Volume: 未定

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Measurement of Surface Tension of Molten Metal under Reducing Gas Atmosphere in Microgravity Condition during Parabolic Flight ― Attempt to control oxygen partial pressure ―2014

    • Author(s)
      S. Ozawa, N. Takenaga, T. Inoue, Y. Takei, T. Hibiya, A. Mizuno, and M. Watanabe
    • Journal Title

      Int. J. Microgravity Sci. Appl.

      Volume: 31 Pages: 11-16

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 溶鉄の表面張力測定に及ぼす試料蒸発の影響2013

    • Author(s)
      高橋優,小澤俊平,福山博之,渡辺直行
    • Journal Title

      熱物性

      Volume: -

    • NAID

      10031185811

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of oxygen partial pressure on the marangoni flow of molten metals2013

    • Author(s)
      T. Hibiya and S. Ozawa
    • Journal Title

      Crystal Research and Technology

      Volume: 48 Issue: 4 Pages: 208-213

    • DOI

      10.1002/crat.201200514

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 酸素雰囲気を制御した環境下における粘性を考慮した液滴振動解析2014

    • Author(s)
      渡邉匡人,小野寺健太,水野章俊,小澤俊平
    • Organizer
      日本マイクログラビティ応用学会
    • Place of Presentation
      イーグレひめじ(兵庫県姫路市)
    • Year and Date
      2014-11-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] 雰囲気酸素分圧依存性を考慮した銅および銀融体の無容器表面張力測定2014

    • Author(s)
      西村大,武井悠翔,工藤優,小澤俊平
    • Organizer
      日本マイクログラビティ応用学会
    • Place of Presentation
      イーグレひめじ(兵庫県姫路市)
    • Year and Date
      2014-11-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] 電磁浮遊法による高温チタン融体の表面張力測定2014

    • Author(s)
      工藤優,小澤俊平
    • Organizer
      鉄鋼協会2014年秋季大会
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 溶融銅の表面張力に対する温度と雰囲気酸素分圧の影響2014

    • Author(s)
      西村大,小澤俊平,武井悠翔
    • Organizer
      鉄鋼協会2014年秋季大会
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 溶融アルミニウムろう材の表面張力2014

    • Author(s)
      小澤俊平,長坂拓実,西谷克樹,山吉知樹,柳川裕
    • Organizer
      鉄鋼協会2014年秋季大会
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] Influence of oxygen partial pressure of measurement atmosphere on surface tension of molten copper2014

    • Author(s)
      S. Ozawa, Y. Takei, T. Inoue, S. Takahashi, and H. Fukuyama
    • Organizer
      20th European Conference on Thermophysical Properties
    • Place of Presentation
      university of Porto(ポルトガル)
    • Year and Date
      2014-09-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] Surface tension of high temperature metallic melts: Perspective shift from space to earth2012

    • Author(s)
      T. Hibiya and S. Ozawa
    • Organizer
      The Fourth International Conference on The Characterization and Control of Interfaces for. High Quality Advanced Materials
    • Place of Presentation
      ホテル日航倉敷(岡山)
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Surface tension of High Temperature Metallic Melts Measured by Oscillating Droplet Method using Electromagnetic Levitation

    • Author(s)
      S. Ozawa, S. Takahashi, and Y Takei
    • Organizer
      International Symposium on Interfacial Joining and Surface Technology
    • Place of Presentation
      Osaka Univ. (Osaka)
    • Related Report
      2013 Research-status Report
  • [Presentation] Surface Tension of Molten Nickel Measured under Gas Phase Equilibrium of Ar-He-H2-H2O Mixtures

    • Author(s)
      S. Ozawa, S. Takahashi, Y. Takei, and H. Fukuyama
    • Organizer
      The 10th Asia Thermophysical Properties Conference
    • Place of Presentation
      Eamada Plaza hotel (Jeju)
    • Related Report
      2013 Research-status Report
  • [Presentation] Surface Tension of Molten Nickel Measured by Oscillating Droplet Method using Electromagnetic Levitation under Well Controlled Oxygen Partial Pressure

    • Author(s)
      S. Ozawa, S. Takahashi, Y. Takei, and H. Fukuyama
    • Organizer
      Symposium on European Low Gravity Research Association
    • Place of Presentation
      (foyer paolo VI) Vatican City
    • Related Report
      2013 Research-status Report
  • [Presentation] Surface Tension Measurement of Molten Metals using Zirconia Oxygen Pump

    • Author(s)
      Y. Takei, S. Ozawa, S. Takahashi, N. Watanabe, M. Watanabe
    • Organizer
      Symposium on European Low Gravity Research Association
    • Place of Presentation
      (foyer paolo VI) Vatican City
    • Related Report
      2013 Research-status Report
  • [Presentation] ニッケル融体の表面張力に対する雰囲気酸素分圧の影響

    • Author(s)
      小澤俊平,高橋優,武井悠翔
    • Organizer
      第34回熱物性シンポジウム
    • Place of Presentation
      富山県民会館 (富山)
    • Related Report
      2013 Research-status Report
  • [Presentation] ジルコニア式酸素ポンプを用いた低酸素分圧下における金属高温融体の表面張力測定

    • Author(s)
      小澤俊平, 高橋優, 武井悠翔, 渡辺直行,渡邊匡人
    • Organizer
      日本マイクログラビティ応用学会
    • Place of Presentation
      九州大学西新プラザ(福岡)
    • Related Report
      2012 Research-status Report
  • [Presentation] 電磁浮遊法によるFe-Si合金融体の表面張力

    • Author(s)
      小澤俊平,高橋優,児玉真二,石田欽也
    • Organizer
      第33回熱物性シンポジウム
    • Place of Presentation
      大阪市立大学杉本キャンパス(大阪)
    • Related Report
      2012 Research-status Report
  • [Presentation] The Influence of a Reducing Gas Atmosphere on the Temperature Dependence of Surface Tension for Molten Metals

    • Author(s)
      S. Ozawa, S. Takahashi, N. Watanabe, H. Fukuyama, and M. Watanabe
    • Organizer
      18th symposium on thermophysical properties
    • Place of Presentation
      University of Colorado Boulder (アメリカ)
    • Related Report
      2012 Research-status Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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