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Link between the local structures of liquid and solid phases during directional solidification of high-temperature melts

Research Project

Project/Area Number 24760618
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Metal making engineering
Research InstitutionGakushuin University

Principal Investigator

MIZUNO Akitoshi  学習院大学, 理学部, 助教 (10348500)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords高温融体 / 凝固 / X線回折 / 液体構造 / 放射光 / 材料科学 / 物性実験 / 放射光X線 / 液体構造解析 / 放射光X線回折 / ゾーンメルト
Research Abstract

In order to clarify a link between the local structures of liquid and solid phases during directional solidification of high-temperature melts over 2000 K, we have developed a laser-heated zone-melting equipment for synchrotron x-ray diffraction experiments. We succeeded in obtaining accurate data of liquid structure of high melting temperature materials such as alumina and Ti. In addition, we demonstrated that precipitation of a metastable phase during solidification of Ti may be detected by obtaining structure data around the interface of liquid and solid phases.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (16 results)

All 2014 2013 Other

All Journal Article (9 results) (of which Peer Reviewed: 4 results) Presentation (7 results) (of which Invited: 2 results)

  • [Journal Article] Experimental and thermodynamic assessment of the Nd–Zr system2014

    • Author(s)
      N. Mattern, Y. Yokoyama, A. Mizuno, J.H. Han, O. Fabrichnaya, T. Harada, S. Kohara, J. Eckert
    • Journal Title

      CALPHAD

      Volume: 46

    • Related Report
      2013 Final Research Report
  • [Journal Article] Concentration dependence of molar volume of binary Si alloys in liquid state2014

    • Author(s)
      Akitoshi Mizuno, Hiroya Kawauchi, Mitsuhiro Tanno, Kentraro Murai, Hidekazu Kobatake, Hiroyuki Fukuyama, Takao Tsukada and Masahito Watanabe
    • Journal Title

      ISIJ International

      Volume: 54

    • NAID

      130004694569

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental and thermodynamic assessment of the Nd-Zr system2014

    • Author(s)
      N. Mattern, Y. Yokoyama, A. Mizuno, J.H. Han, O. Fabrichnaya, T. Harada, S. Kohara, J. Eckert
    • Journal Title

      CALPHAD

      Volume: 46 Pages: 103-107

    • DOI

      10.1016/j.calphad.2014.02.008

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Density and Structure of Liquid Si-M (M=Fe, Ni, and Ge) Alloys2013

    • Author(s)
      Akitoshi Mizuno, Kentaro Murai, Hiroya Kawauchi, Mitsuhiro Tannno, Shinji Kohara and Masahito Watanabe
    • Journal Title

      Materials Research Society Symposium Proceedings

      Volume: 1528

    • Related Report
      2013 Final Research Report
  • [Journal Article] Influence of oxygen impurity on containerless solidification of quasicrystalline-forming Zr80Pt20 alloy2013

    • Author(s)
      Takeshi Harada, Akitoshi Mizuno and Masahito Watanabe
    • Journal Title

      Materials Research Society Symposium Proceedings

      Volume: 1528

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Journal Article] Fe-Si混合系融体のモル体積の組成依存性と局所構造2013

    • Author(s)
      水野章敏,丹野光浩,高橋竜太郎,河内大弥,渡邉匡人
    • Journal Title

      熱物性

      Volume: 27(1) Pages: 3-8

    • NAID

      10031138225

    • Related Report
      2013 Final Research Report
  • [Journal Article] Fe-Si混合系融体のモル体積の組成依存性と局所構造2013

    • Author(s)
      水野章敏, 丹野光浩, 高橋竜太郎, 河内大弥, 渡邉匡人
    • Journal Title

      熱物性

      Volume: 27 Pages: 3-8

    • NAID

      10031138225

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Density and Structure of Liquid Si-M (M=Fe, Ni, and Ge) Alloys,2013

    • Author(s)
      Akitoshi Mizuno, Kentaro Murai, Hiroya Kawauchi, Mitsuhiro Tannno, Shinji Kohara and Masahito Watanabe
    • Journal Title

      Materials Research Society Symposium Proceedings

      Volume: 1528

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Concentration dependence of molar volume of binary Si alloys in liquid state

    • Author(s)
      Akitoshi Mizuno, Hiroya Kawauchi, Mitsuhiro Tanno, Kentraro Murai, Hidekazu Kobatake, Hiroyuki Fukuyama, Takao Tsukada and Masahito Watanabe
    • Journal Title

      ISIJ International

      Volume: 54(9)(In press)

    • NAID

      130004694569

    • Related Report
      2013 Final Research Report
  • [Presentation] 無容器浮遊法を援用した高融点合金液体の構造解析2014

    • Author(s)
      水野章敏
    • Organizer
      日本物理学会,第69回年次大会,領域6シンポジウム
    • Place of Presentation
      東海大学
    • Year and Date
      2014-03-27
    • Related Report
      2013 Final Research Report
  • [Presentation] 無容器浮遊法を援用した高融点合金液体の構造解析2014

    • Author(s)
      水野章敏
    • Organizer
      日本物理学会
    • Place of Presentation
      東海大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 二元系Si合金融体のモル体積と構造の組成依存性2013

    • Author(s)
      水野章敏,小原真司,渡邉匡人
    • Organizer
      日本熱物性学会,第34回熱物性シンポジウム
    • Place of Presentation
      富山県民会館
    • Year and Date
      2013-11-12
    • Related Report
      2013 Final Research Report
  • [Presentation] Zr基2元系合金の無容器凝固過程における溶存酸素の影響2013

    • Author(s)
      原田剛,水野章敏,渡邉匡人
    • Organizer
      日本物理学会,第68回秋期大会
    • Place of Presentation
      徳島大学
    • Year and Date
      2013-09-26
    • Related Report
      2013 Final Research Report
  • [Presentation] Containerless solidification of metallic glass-forming Zr-Pd-Al alloys studied by time-resolved x-ray diffraction2013

    • Author(s)
      Akitoshi Mizuno, Hiroyuki Oka, Yoshihiko Yokoyama, Shinji Kohara, Masahito Watanabe
    • Organizer
      THERMEC 2013
    • Place of Presentation
      Las Vegas, USA
    • Related Report
      2013 Final Research Report
  • [Presentation] Concentration Dependence of Molar Volume and Structure of Binary Si Alloys in the Liquid State2013

    • Author(s)
      Akitoshi Mizuno, Kentaro Murai, Hiroya Kawauchi, Mitsuhiro Tannno, Hidekazu Kobatake, Hiroyuki Fukuyama, Takao Tsukada and Masahito Watanabe
    • Organizer
      ATPC 2013
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2013 Final Research Report
  • [Presentation] 二元系Si合金融体のモル体積と構造の組成依存性2013

    • Author(s)
      水野章敏, 小原真司, 渡邉匡人
    • Organizer
      日本熱物性学会
    • Place of Presentation
      富山県民会館
    • Related Report
      2013 Annual Research Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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