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Investigation of Micro-scale Structural Changes in the Packed Bed of Hydrogen Storage Alloys and the Deformation of the Vessel by On-site Visualization

Research Project

Project/Area Number 24760619
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionTohoku University

Principal Investigator

SAITO YASUHIRO  東北大学, 工学(系)研究科(研究院), 助教 (50621033)

Research Collaborator KAWAKAMI Yoshiaki  高砂熱学工業株式会社
OKUMURA Masahiko  東北大学, 大学院工学研究科, 大学院生
Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2012: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords水素吸蔵合金 / マイクロX線CT / Mm-Ni / Ti-Fe / 微粉化 / マイクロX線CT撮影 / La-Ni
Research Abstract

To investigate the safety of the storage tank of hydrogen storage alloys, the strain on the vessel wall and micro-scale structural change in the vessel along with the hydrogen absorption-desorption process were evaluated. The results of strain measurement indicated that the stress which caused at the bottom of the vessel increased with repeated hydrogen absorption-desorption process. The measurement of local packing ratios showed that alloy particles were concentrated at the lower parts of the packed bed with the absorption-desorption process. The observation results using an X-ray computed tomography showed that the pulverization property of the Ti-Fe alloys, which did not contain any rare earth elements, was different from that of the Mm-Ni. The image processing program for estimating the particle diameter distribution was developed and applied to Mm-Ni alloys, and indicated that the particle diameters in the packed bed decreased by hydrogen absorption.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (21 results)

All 2014 2013 2012 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (14 results) (of which Invited: 3 results) Remarks (5 results)

  • [Journal Article] Pulverization Mechanism of Hydrogen Storage Alloys on Microscale Packing Structure2012

    • Author(s)
      Okumura, M., A. Ikado, Y. Saito, H. Aoki, T. Miura and Y. Kawakami
    • Journal Title

      Int. J. Hydrogen Energy

      Volume: 37 Issue: 14 Pages: 10715-10723

    • DOI

      10.1016/j.ijhydene.2012.04.061

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Investigation of Wall Stress Development and Packing Ratio Distribution in the Metal Hydride Reactor2012

    • Author(s)
      Okumura, M., K. Terui, A. Ikado, Y. Saito, M. Shoji, Y. Matsushita, H. Aoki, T. Miura and Y. Kawakami
    • Journal Title

      Int. J. Hydrogen Energy

      Volume: 37 Issue: 8 Pages: 6686-6693

    • DOI

      10.1016/j.ijhydene.2012.01.097

    • Related Report
      2013 Final Research Report 2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 水素吸蔵合金の利用を目指した充填層解析2014

    • Author(s)
      齋藤泰洋,奥村真彦,松下洋介,青木秀之
    • Organizer
      自動車技術会伝熱技術部門委員会企画シンポジウム『省エネを支える伝熱技術』
    • Place of Presentation
      東京,日本
    • Year and Date
      2014-02-14
    • Related Report
      2013 Final Research Report
  • [Presentation] 水素吸蔵合金の微粉化現象に関するプロセス解析2013

    • Author(s)
      齋藤泰洋
    • Organizer
      第2回水素貯蔵材料・水素エネルギーシステムに関する研究会
    • Place of Presentation
      小国,日本
    • Year and Date
      2013-05-17
    • Related Report
      2013 Final Research Report
  • [Presentation] 水素吸蔵合金を用いた水素貯蔵容器内の充填状態変化と応力発現の検討2013

    • Author(s)
      川上理亮,奥村真彦,齋藤泰洋,青木秀之
    • Organizer
      空気調和・衛生工学会東北支部第2回学術・技術報告会
    • Place of Presentation
      仙台,日本
    • Year and Date
      2013-03-12
    • Related Report
      2013 Final Research Report
  • [Presentation] Three-dimensional Observation of Hydro- gen Storage Alloy in Packed Bed and Its Property2013

    • Author(s)
      Okumura, M., Y. Saito, Y. Matsushita, H. Aoki, Y. Kawakami and K. Taki
    • Organizer
      Int. Symp. EcoTopia Sci. 2013
    • Place of Presentation
      Nagoya, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Three-dimensional Observation of Hydrogen Storage Alloy in Packed Bed and Its Property2013

    • Author(s)
      M. Okumura, Y. Saito, Y. Matsushita, H. Aoki, Y. Kawakami and K. Taki
    • Organizer
      International Symposium on EcoTopia Science 2013
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水素吸蔵合金を用いた水素貯蔵容器内の充填状態変化と応力発現の検討2013

    • Author(s)
      川上理亮, 奥村真彦, 齋藤泰洋, 青木秀之
    • Organizer
      空気調和・衛生工学会東北支部第2回学術・技術報告会
    • Place of Presentation
      仙台,日本
    • Related Report
      2012 Research-status Report
  • [Presentation] 水素吸蔵合金におけるプロセス解析2012

    • Author(s)
      齋藤泰洋
    • Organizer
      水素貯蔵材料・水素エネルギーシステムに関する研究会
    • Place of Presentation
      つくば,日本
    • Year and Date
      2012-07-26
    • Related Report
      2013 Final Research Report
  • [Presentation] An Investigation of the Stress Distribution Changes on the Thick Wall Vessel of Hydrogen Storage Alloys2012

    • Author(s)
      Okumura, M., A. Ikado, Y. Saito, H. Aoki and Y. Kawakami
    • Organizer
      Int. Symp. Metal-Hydrogen Syst. 2012
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Multi-scale Investigation of Segregation of Hydrogen Storage Alloys Bed2012

    • Author(s)
      Okumura, M., A. Ikado, Y. Saito, H. Aoki and Y. Kawakami
    • Organizer
      Int. Conf. Clean Energy 2012
    • Place of Presentation
      Quebec, Canada
    • Related Report
      2013 Final Research Report
  • [Presentation] Multi-scale Investigation of Segregation of Hydrogen Storage Alloys Bed2012

    • Author(s)
      Masahiko Okumura, Ayaka Ikado, Yasuhiro Saito, Hideyuki Aoki, Yoshiaki Kawakami
    • Organizer
      International Conference on Clean Energy 2012
    • Place of Presentation
      Quebec, Canada
    • Related Report
      2012 Research-status Report
  • [Presentation] An Investigation of the Stress Distribution Changes on the Thick Wall Vessel of Hydrogen Storage Alloys2012

    • Author(s)
      Masahiko Okumura, Ayaka Ikado, Yasuhiro Saito, Hideyuki Aoki, Yoshiaki Kawakami
    • Organizer
      International Symposium on Metal-Hydrogen Systems 2012
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2012 Research-status Report
  • [Presentation] 水素吸蔵合金におけるプロセス解析2012

    • Author(s)
      齋藤泰洋
    • Organizer
      水素貯蔵材料・水素エネルギーシステムに関する研究会
    • Place of Presentation
      つくば,日本
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] 水素吸蔵合金の利用を目指した充填層解析

    • Author(s)
      齋藤泰洋, 奥村真彦, 松下洋介, 青木秀之
    • Organizer
      自動車技術会伝熱技術部門委員会企画シンポジウム『省エネを支える伝熱技術』
    • Place of Presentation
      工学院大学(東京都新宿区)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 水素吸蔵合金の微粉化現象に関するプロセス解析

    • Author(s)
      齋藤泰洋
    • Organizer
      第2回水素貯蔵材料・水素エネルギーシステムに関する研究会
    • Place of Presentation
      日本重化学工業小国事業所(山形県小国町)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Remarks]

    • URL

      http://www.che.tohoku.ac.jp/~tranpo/

    • Related Report
      2013 Final Research Report
  • [Remarks] International Symposium on EcoTopia Science 2013, Outstanding Presentation Award, 12月15日(2013) 受賞歴

    • Related Report
      2013 Final Research Report
  • [Remarks] 空気調和・衛生工学会東北支部 第2回学術・技術報告会,優秀発表奨励賞, 5月22日(2013) 受賞歴

    • Related Report
      2013 Final Research Report
  • [Remarks] 東北大学研究者紹介

    • URL

      http://db.tohoku.ac.jp/whois/detail/96f62f49bef17a4ba246e05dedaa6f16.html

    • Related Report
      2013 Annual Research Report
  • [Remarks] 東北大学大学院工学研究科化学工学専攻青木研究室

    • URL

      http://www.che.tohoku.ac.jp/~tranpo

    • Related Report
      2013 Annual Research Report

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Published: 2013-05-31   Modified: 2019-07-29  

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