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Development of the next-generation fuel cell as an alternative of LI-ion battery

Research Project

Project/Area Number 24760628
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Reaction engineering/Process system
Research InstitutionKanazawa University

Principal Investigator

TSUJIGUCHI Takuya  金沢大学, 機械工学系, 助教 (10510894)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords直接ギ酸形燃料電池 / 水の移動 / 撥水性多孔質体 / 触媒担体 / ギ酸 / 触媒被毒 / 燃料電池 / 物質移動 / 出力低下
Outline of Final Research Achievements

We focused on the direct formic acid fuel cell as promising portable electric power generation devices which can operate for a long time. The power density of the DFAFC decreases with the time although the its initial power density is high. In this study, the novel electrode structure which can inhibit the performance decay due to the cathode, and the novel catalyst which can inhibit the poisoning of the anode catalyst were develop to prevent the performance decay of the DFAFC. The performance decay due to the cathode electrode could be successfully inhibited by the novel electrode structure. Regarding on the developed novel catalyst, it showed high resistance for the catalyst poisonings, however, it was found that the improvement for the cell fabrication method using this catalyst is required since the cell performance using developed catalyst was low.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (27 results)

All 2015 2014 2013 2012

All Journal Article (8 results) (of which Acknowledgement Compliant: 1 results,  Peer Reviewed: 7 results) Presentation (17 results) Book (2 results)

  • [Journal Article] Effect of the operation temperature on the overpotential of the direct formic acid fuel cell2014

    • Author(s)
      T. Tsujiguchi, F. Matsuoka, Y. Osaka, A. Kodama
    • Journal Title

      Proceedings of Grand renewable energy 2014 International Conference

      Volume: 1

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Water transport characteristics of the passive direct formic acid fuel cell2014

    • Author(s)
      Takuya Tsujiguchi, Takanori Iwakami, Soshi Hirano, Nobuyoshi Nakagawa
    • Journal Title

      Journal of Power Sources

      Volume: 250 Pages: 266-273

    • DOI

      10.1016/j.jpowsour.2013.10.094

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Improved reaction kinetics and selectivity by the TiO2-embedded carbon nanofiber support for electro-oxidation of ethanol on PtRu nanoparticles2014

    • Author(s)
      Nobuyoshi Nakagawa, Yudai Ito, Takuya Tsujiguchi, Hirokazu Ishitobi, “Improved reaction kinetics and selectivity by the TiO2-embedded carbon nanofiber support for electro-oxidation of ethanol on PtRu nanoparticles
    • Journal Title

      Journal of Power Sources

      Volume: 248 Pages: 330-336

    • DOI

      10.1016/j.jpowsour.2013.09.055

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Ultrahigh methanol electro-oxidation activity of PtRu nanoparticles prepared on TiO2-embedded carbon nanofiber support2013

    • Author(s)
      Yudai Ito, Taizo Takeuchi, Takuya Tsujiguchi, Mohammad Ali Abdelkareem, Nobuyoshi Nakagawa,
    • Journal Title

      Journal of Power Sources

      Volume: 242 Pages: 280-288

    • DOI

      10.1016/j.jpowsour.2013.05.064

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] CarboneCeO2 composite nanofibers as a promising support for a PtRu anode catalyst in a direct methanol fuel cell2013

    • Author(s)
      Chen Feng, Taizo Takeuchi, Mohammad Ali Abdelkareem, Takuya Tsujiguchi, Nobuyoshi Nakagawa,
    • Journal Title

      Journal of Power Sources

      Volume: 242 Pages: 56-64

    • DOI

      10.1016/j.jpowsour.2013.04.157

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effect of the membrane thickness on the over-potential behavior of the direct formic acid fuel cell2013

    • Author(s)
      Takuya Tsujiguchi, Takanori Iwakami, Nobuyoshi Nakagawa
    • Journal Title

      ECS Transaction

      Volume: 58 Pages: 1855-1891

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] The Performance Degradation of a Passive Direct Formic Acid Fuel Cell and its Improvement by a Hydrophobic Filter2013

    • Author(s)
      Takuya Tsujiguchi, Soshi Hirano, Takanori Iwakami Nobuyoshi Nakagawa
    • Journal Title

      Journal of Power Sources

      Volume: 223 Pages: 42-49

    • DOI

      10.1016/j.jpowsour.2012.09.030

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Development of High Performance Direct Formic Acid Fuel Cell Using Hyper-Branched Polymer as a Catalyst Stabilizer2012

    • Author(s)
      Takuya Tsujiguchi, Misaki Kojima, Takanori Iwakami, Nobuyoshi Nakagawa and Keisuke Kojima
    • Journal Title

      ECS Transactions

      Volume: 50(2) Issue: 2 Pages: 1951-1957

    • DOI

      10.1149/05002.1951ecst

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] 直接ギ酸形燃料電池のアノード触媒設計指針2015

    • Author(s)
      辻口 拓也, 大坂 侑吾, 児玉 昭雄
    • Organizer
      化学工学会 第80年会
    • Place of Presentation
      芝浦工科大学
    • Year and Date
      2015-03-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 化学還元時の超音波処理がPd/Cのギ酸酸化活性におよぼす影響2015

    • Author(s)
      大西 諒, 辻口 拓也, 大坂 侑吾, 児玉 昭雄
    • Organizer
      化学工学会 第80年会
    • Place of Presentation
      芝浦工科大学
    • Year and Date
      2015-03-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 直接ギ酸形燃料電池の電極過電圧におよぼすカソード電極構造の影響2015

    • Author(s)
      松岡 史彦, 辻口 拓也, 大坂 侑吾, 児玉 昭雄
    • Organizer
      化学工学会 第80年会
    • Place of Presentation
      芝浦工科大学
    • Year and Date
      2015-03-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 粒子含有CNFを用いたDFAFCの耐被毒・高活性触媒の開発2014

    • Author(s)
      大西 諒, 辻口 拓也,中川 紳好,大坂 侑吾,児玉 昭雄
    • Organizer
      化学工学会 第46回秋季大会
    • Place of Presentation
      九州大学
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 直接ギ酸形燃料電池の電極構造が濃度過電圧におよぼす影響2014

    • Author(s)
      松岡 史彦, 帆苅 優,辻口 拓也,大坂 侑吾,児玉 昭雄
    • Organizer
      化学工学会 第46回秋季大会
    • Place of Presentation
      九州大学
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of the operation temperature on the overpotential of the direct formic acid fuel cell2014

    • Author(s)
      T. Tsujiguchi, F. Matsuoka, Y. Osaka, A. Kodama
    • Organizer
      Grand renewable energy 2014 International Conference
    • Place of Presentation
      東京ビッグサイト
    • Year and Date
      2014-08-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高出力直接ギ酸形燃料電池の開発へ向けた過電圧解析2014

    • Author(s)
      辻口 拓也、松岡 史彦、帆苅 優、大坂 侑吾、児玉 昭雄
    • Organizer
      第21回燃料電池シンポジウム
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2014-05-29 – 2014-05-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] 直接ギ酸形燃料電池の電極過電圧挙動におよぼす発電温度の影響2014

    • Author(s)
      辻口 拓也、松岡 史彦、中川 紳好、大坂 侑吾、児玉 昭雄
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 直接ギ酸形燃料電池の出力低下挙動におよぼす物質移動特性の影響2014

    • Author(s)
      帆苅優、松岡 史彦、辻口 拓也、中川 紳好、大坂 侑吾、児玉 昭雄
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 新規触媒担体による直接ギ酸形燃料電池の触媒被毒の抑制2014

    • Author(s)
      大西諒、辻口 拓也、青山知弘、中川 紳好、大坂 侑吾、児玉 昭雄
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 直接ギ酸形燃料電池の過電圧解析2013

    • Author(s)
      辻口拓也、岩上誉矩、中川紳好
    • Organizer
      第45回化学工学会秋季大会
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Effect of the membrane thickness on the over-potential behavior of the direct formic acid fuel cell2013

    • Author(s)
      Takuya Tsujiguchi, Takanori Iwakami, Nobuyoshi Nakagawa
    • Organizer
      224 th ECS Meeting
    • Place of Presentation
      San Francisco, USA
    • Related Report
      2013 Research-status Report
  • [Presentation] Development of High Performance Direct Formic Acid Fuel Cell Using Hyper-Branched Polymer as a Catalyst Stabilizer2012

    • Author(s)
      Takuya Tsujiguchi, Misaki Kojima, Takanori Iwakami, Nobuyoshi Nakagawa and Keisuke Kojima
    • Organizer
      PRiME2012
    • Place of Presentation
      Honolulu, Hawaii
    • Related Report
      2012 Research-status Report
  • [Presentation] 長時間高出力の維持が可能な小型電源の開発2012

    • Author(s)
      辻口拓也,中川紳好
    • Organizer
      首都圏北部4大学発新技術説明会
    • Place of Presentation
      JST東京別館ホール,東京
    • Related Report
      2012 Research-status Report
  • [Presentation] 直接ギ酸型燃料電池の特異なカソード過電圧の増加2012

    • Author(s)
      岩上誉矩,辻口拓也,中川紳好
    • Organizer
      化学工学会 第44秋季大会
    • Place of Presentation
      仙台,東北大学
    • Related Report
      2012 Research-status Report
  • [Presentation] ハイパーブランチポリマーを用いた直接ギ酸型燃料電池の電極作製方法の検討2012

    • Author(s)
      辻口拓也,小嶌岬,岩上誉矩,中川紳好,小島圭介
    • Organizer
      化学工学会 第44秋季大会
    • Place of Presentation
      仙台,東北大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 長時間駆動が可能な高性能次世代小型電源2012

    • Author(s)
      辻口拓也
    • Organizer
      イノベーションジャパン
    • Place of Presentation
      東京,東京国際フォーラム
    • Related Report
      2012 Research-status Report
  • [Book] ケミカルエンジニアリング 2013年5月号(Vol.58, No.5) "長時間高出力の維持が可能な小型燃料電池の開発"2013

    • Author(s)
      辻口拓也、中川紳好
    • Publisher
      化学工業社
    • Related Report
      2012 Research-status Report
  • [Book] OHM10月号 ”長時間出力の維持が可能な小型電源の開発”2012

    • Author(s)
      辻口拓也、中川紳好
    • Publisher
      オーム社
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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