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Development of a method to control biomass pyrolysis using ionic liquid

Research Project

Project/Area Number 24760631
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Reaction engineering/Process system
Research InstitutionKyushu University

Principal Investigator

KUDO Shinji  九州大学, 先導物質化学研究所, 助教 (70588889)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2012: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywordsバイオマス / セルロース / 熱分解 / イオン液体
Research Abstract

Sulfonate ionic liquids promoted dehydration of cellulose when their mixture was heated under inert gas stream, which resulted in a selective production of levoglucosenone that is a high-value added chemical. Similar results were obtained even when glucose and its oligomer and polymer were used as the source of levoglucosenone, although cellulose was the most promising starting material. On the basis of knowledge obtained in the experiment, a new and more efficient method for levoglucosenone production was proposed for the study in future.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (7 results)

All 2013 2012

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (5 results)

  • [Journal Article] Sulfonate Ionic Liquid as a Stable and Active Catalyst for Levoglucosenone Production from Saccharides via Catalytic Pyrolysis2013

    • Author(s)
      S. Kudo, Z. Zhou, K. Yamasaki, K. Norinaga, J.-i. Hayashi
    • Journal Title

      Catalysts

      Volume: 3 Issue: 4 Pages: 757-773

    • DOI

      10.3390/catal3040757

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Applications of Catalysis in the Selective Conversion of Lignocellulosic Biomass by Pyrolysis2012

    • Author(s)
      S. Kudo, K. Norinaga, J.-i. Hayashi
    • Journal Title

      Journal of Novel Carbon Resource Sciences

      Volume: 6 Pages: 1-8

    • URL

      http://ncrs.cm.kyushu-u.ac.jp/assets/files/JNCRS/JNCRS_Vol6_01-08.pdf

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Presentation] Catalysis of ionic liquid for selective formation of levoglucosenone from pyrolysis of cellulose2013

    • Author(s)
      S. Kudo, K. Yamasaki, Z. Zhou, K. Norinaga, J.-i. Hayashi
    • Organizer
      2nd International Symposium on Green Chemistry
    • Place of Presentation
      La Rochelle, France
    • Related Report
      2013 Annual Research Report 2013 Final Research Report 2012 Research-status Report
  • [Presentation] Intra-monomer- unit dehydration of cellulose under catalysis of ionic liquid toward selective production of levoglucosenone2012

    • Author(s)
      K. Yamasaki, Z. Zhou, S. Kudo, K. Norinaga, J.-i. Hayashi
    • Organizer
      The 25th International Symposium on Chemical Engineering
    • Place of Presentation
      Okiwana, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] セルロース熱分解に対するイオン液体の触媒作用2012

    • Author(s)
      周振巍,工藤真二,則永行庸,林潤一郎
    • Organizer
      化学工学会第44回秋季大会
    • Place of Presentation
      仙台
    • Related Report
      2013 Final Research Report
  • [Presentation] セルロース熱分解に対するイオン液体の触媒作用2012

    • Author(s)
      周 振巍、工藤 真二、則永 行庸、林 潤一郎
    • Organizer
      化学工学会 第44回秋季大会
    • Place of Presentation
      仙台
    • Related Report
      2012 Research-status Report
  • [Presentation] Intra-monomer-unit dehydration of cellulose under catalysis of ionic liquid toward selective production of levoglucosenone2012

    • Author(s)
      Kento Yamasaki, Zhenwei Zhou, Shinji Kudo, Koyo Norinaga, Jun-ichiro Hayashi
    • Organizer
      The 25th International Symposium on Chemical Engineering
    • Place of Presentation
      Okinawa
    • Related Report
      2012 Research-status Report

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Published: 2013-05-31   Modified: 2019-07-29  

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