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Development of catalysts for H2 production by ammonia decomposition under mild reaction condition

Research Project

Project/Area Number 24760641
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Research InstitutionOita University

Principal Investigator

NAGAOKA Katsutoshi  大分大学, 工学部, 准教授 (90381029)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywords再生可能エネルギー / エネルギーキャリア / 水素 / アンモニア分解 / 水素キャリア / 水素製造
Research Abstract

Nowadays NH3 has been regarded as one of the potential H2-storage materials. In this research, novel supported metal catalysts for producing renewable hydrogen by ammonia decomposition under mild reaction condition was developed. For that purpose, basic hydrotalcite-like compound was used as precursor for Mg-Al oxide support. It was revealed that 5 wt%Ru/Cs2O/Mg-Al-oxide converts 51% of NH3 even at 573 K with a space velocity of 3000 h-1. Furthermore, Ru-free Ni catalyst, CeO2/15wt%Ni/ Mg-Al-oxide, was found to exhibit almost complete conversion of NH3 even at 773 K.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (18 results)

All 2014 2013 2012 Other

All Presentation (17 results) (of which Invited: 1 results) Remarks (1 results)

  • [Presentation] 酸性酸化物担持Ru触媒を用いたアンモニアの酸化分解による水素製造反応の常温駆動2014

    • Author(s)
      永星孝明・武石優磨・本多恭子・佐藤勝俊・永岡勝俊
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Final Research Report
  • [Presentation] INFUENCE OF THE BASIC DOPANT ON THE ACTIVITY OF Ru/Pr6O11 FOR AMMONIA DECOMPOSITION2014

    • Author(s)
      T.Eboshi, N.Abe, S.Miyahara, K.Honda, K.Sato, K.Nagaoka
    • Organizer
      International Conference on Hydrogen Production-2014
    • Place of Presentation
      九州大学
    • Related Report
      2013 Final Research Report
  • [Presentation] INFUENCE OF THE BASIC DOPANT ON THE ACTIVITY OF Ru/Pr6O11 FOR AMMONIA DECOMPOSITION2014

    • Author(s)
      T.Eboshi, N.Abe, S.Miyahara, K.Honda, K.Sato, K.Nagaoka
    • Organizer
      International Conference on Hydrogen Production - 2014
    • Place of Presentation
      九州大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Ammonia decomposition for hydrogen production over Ni catalysts prepared from hydrotalcite-like compounds2014

    • Author(s)
      N. Abe, S. Miyahara, K. Honda, K.Sato, K. Nagaoka
    • Organizer
      TOCAT7 KYOTO2014
    • Place of Presentation
      京都テルサ
    • Related Report
      2013 Annual Research Report
  • [Presentation] Development of supported Ru catalyst for hydrogen production by ammonia decomposition2013

    • Author(s)
      N. Abe, S. Miyahara, K. Honda, K.Sato, K. Nagaoka
    • Organizer
      The 14th Japan-Korea Symposium on Catalysis
    • Place of Presentation
      愛知県産業労働センター
    • Year and Date
      2013-07-01
    • Related Report
      2013 Final Research Report
  • [Presentation] 触媒の自己発熱を利用したアンモニアの酸化分解による水素製造反応常温駆動-アンモニアの吸着熱利用-2013

    • Author(s)
      永岡勝俊・永星孝明・本多恭子・佐藤勝俊
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      関西大学
    • Year and Date
      2013-03-26
    • Related Report
      2013 Final Research Report
  • [Presentation] 触媒の自己発熱を利用したアンモニア酸化分解による水素製造反応常温駆動-触媒の酸化熱利用-2013

    • Author(s)
      佐藤勝俊・永星孝明・本多恭子・永岡勝俊
    • Organizer
      第111回触媒討論会
    • Place of Presentation
      関西大学
    • Year and Date
      2013-03-26
    • Related Report
      2013 Final Research Report
  • [Presentation] アンモニアの酸化分解による水素製造反応の常温駆動に用いるRu系触媒の開発2013

    • Author(s)
      武石優磨・永星孝明・本多恭子・永岡勝俊・佐藤勝俊
    • Organizer
      第33回水素エネルギー協会大会
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2013 Final Research Report
  • [Presentation] アンモニアの酸化分解による水素製造反応の常温駆動に用いる担持Ru触媒の担体効果2013

    • Author(s)
      武石優磨・永星孝明・本多恭子・佐藤勝俊・永岡勝俊
    • Organizer
      第43回石油・石油化学討論会
    • Place of Presentation
      北九州国際会議場
    • Related Report
      2013 Final Research Report
  • [Presentation] 担持Ru触媒を用いたアンモニアの酸化分解による水素製造反応の常温駆動メカニズムの検討2013

    • Author(s)
      武石優磨・永星孝明・本多恭子・佐藤勝俊・永岡勝俊
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田大学手形キャンパス
    • Related Report
      2013 Final Research Report
  • [Presentation] Development of supported Ru catalyst for hydrogen production by ammonia decomposition2013

    • Author(s)
      N. Abe, S. Miyahara, K. Honda, K.Sato, K. Nagaoka
    • Organizer
      The 14th Japan-Korea Symposium on Catalysis
    • Place of Presentation
      愛知県産業労働センター
    • Related Report
      2013 Annual Research Report
  • [Presentation] ハイドロタルサイトを前駆体とした担持Ni触媒によるアンモニア分解反応2013

    • Author(s)
      安部成彦・川越貴史・本多恭子・佐藤勝俊 ・永岡勝俊
    • Organizer
      第112回触媒討論会
    • Place of Presentation
      秋田大学手形キャンパス
    • Related Report
      2013 Annual Research Report 2012 Research-status Report
  • [Presentation] 触媒の自己発熱を利用した水素製造反応のコールドスタートプロセスの構築2013

    • Author(s)
      永岡 勝俊
    • Organizer
      平成25年度触媒学会西日本支部触媒技術セミナー
    • Place of Presentation
      徳島大学工学部
    • Related Report
      2012 Research-status Report
    • Invited
  • [Presentation] Development of supported Ru catalyst for hydrogen production by ammonia decomposition2013

    • Author(s)
      Naruhiko Abe, Shinichiro Miyahara, Kyoko Honda, Katsutoshi Sato,Katsutoshi Nagaoka
    • Organizer
      The 14th Japan-Korea Symposium on Catalysis
    • Place of Presentation
      愛知産業労働センター
    • Related Report
      2012 Research-status Report
  • [Presentation] 水素輸送のためのアンモニア合成・分解2012

    • Author(s)
      永岡勝俊
    • Organizer
      第8回触媒道場
    • Place of Presentation
      北九州ハイツ
    • Year and Date
      2012-09-01
    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Presentation] 炭化水素の改質やアンモニアの分解により水素を製造するための触媒開発2012

    • Author(s)
      永岡勝俊
    • Organizer
      第33回触媒学会若手会(夏の研修会)
    • Place of Presentation
      開春楼
    • Year and Date
      2012-08-08
    • Related Report
      2013 Final Research Report
  • [Presentation] アンモニア分解触媒の開発2012

    • Author(s)
      永岡勝俊
    • Organizer
      第1回グリーンマテリアル研究会
    • Place of Presentation
      花菱ホテル
    • Year and Date
      2012-01-07
    • Related Report
      2013 Final Research Report
  • [Remarks]

    • URL

      http://www.appc.oita-u.ac.jp/physchem/

    • Related Report
      2013 Final Research Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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