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Structural analyses of cesium ions adsorbed on clay minerals and attempts of the desorption

Research Project

Project/Area Number 24760688
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Earth system and resources enginnering
Research InstitutionNational Institute of Advanced Industrial Science and Technology (2014)
Ehime University (2012-2013)

Principal Investigator

MORIMOTO KAZUYA  独立行政法人産業技術総合研究所, 地圏資源環境研究部門, 研究員 (10565683)

Research Collaborator KOGURE Toshihiro  
TAMURA Kenji  
SATO Hisako  
YAMAGISHI Akihiko  
Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsイオン交換反応 / セシウムイオン / マグネシウムイオン / 汚染土壌 / 粘土鉱物 / 除染
Outline of Final Research Achievements

Since the explosion accident at the Fukushima nuclear power plant, decontamination of a huge amount of soil polluted with radioactive cesium became the urgent issue. These Cs isotopes stay as ions in the soils near the ground surface for a long period, since they are strongly fixed in the interlayer spaces of clay minerals. Because vermiculite clay has an extremely high adsorption capacity for Cs ions compared to other minerals, it can play an important role in the environmental fate of radioactive cesium in the polluted area. In the present work, we have elucidated the state of Cs ions fixed in a vermiculite clay, and examined the possibility of desorption of Cs ions.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (17 results)

All 2014 2013 2012 Other

All Journal Article (5 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (7 results) (of which Invited: 1 results) Book (1 results) Remarks (4 results)

  • [Journal Article] SYNTHESIS AND PHASE RELATIONS IN MONTMORILLONITE-STEVENSITE SERIES UNDER HYDROTHERMAL CONDITIONS2014

    • Author(s)
      YAMADA HIROHISA, YOKOYAMA SHINGO, TAMURA KENJI, WATANABE YUJIRO, MORIMOTO KAZUYA, HATTA TAMAO, WATANABE TAKASHI
    • Journal Title

      Clay science

      Volume: 18 Pages: 11-18

    • NAID

      110009818042

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 粘土鉱物に取り込まれたセシウムイオンの脱離の試み2013

    • Author(s)
      森本和也
    • Journal Title

      粘土科学

      Volume: 51 Pages: 141-143

    • Related Report
      2013 Research-status Report
  • [Journal Article] 粘土鉱物に取り込まれたセシウムイオンの脱離の試み2013

    • Author(s)
      森本 和也
    • Journal Title

      粘土科学

      Volume: 51 Pages: 23-25

    • Related Report
      2012 Research-status Report
  • [Journal Article] XRD and HRTEM Evidence for Fixation of Cesium Ions in Vermiculite Clay2012

    • Author(s)
      Toshiro Kogure, Kazuya Morimoto, Kenji Tamura, Hisako Sato and Akihiko Yamagishi
    • Journal Title

      Chemistry Letters

      Volume: 41 Issue: 4 Pages: 380-382

    • DOI

      10.1246/cl.2012.380

    • NAID

      10030544530

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Desorption of Cs<sup>+</sup> Ions Intercalated in Vermiculite Clay through Cation Exchange with Mg<sup>2+</sup> Ions2012

    • Author(s)
      Kazuya Morimoto, Toshihiro Kogure, Kenji Tamura, Saki Tomofuji, Akihiko Yamagishi
    • Journal Title

      Chemistry Letters

      Volume: 41 Issue: 12 Pages: 1715-1717

    • DOI

      10.1246/cl.2012.1715

    • NAID

      130004426473

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] セシウムの粘土への吸着2014

    • Author(s)
      森本 和也
    • Organizer
      シンポジウム「放射性物質汚染に関する汚染被災地の現状と課題」
    • Place of Presentation
      九州大学(福岡市)
    • Year and Date
      2014-12-11
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ため池底質におけるCsの分布状態について2014

    • Author(s)
      鈴木 正哉、万福 和子、星野谷 亜衣、森本 和也、平林 恵理、佐藤 卓 見、大和田 朗、横山信吾、伊藤 健一、八田珠郎、万福 裕造、北澤  英明、末原 茂、山田裕久
    • Organizer
      第58回粘土科学討論会
    • Place of Presentation
      福島市
    • Year and Date
      2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 飯館村ため池底土におけるCsの分布と存在状態について2014

    • Author(s)
      鈴木 正哉、万福 和子、星野谷 亜衣、森本 和也、大和田 朗、佐藤 卓見、平林 恵理
    • Organizer
      第57回日本薄片研磨片技術研究会
    • Place of Presentation
      東北大学(仙台市)
    • Year and Date
      2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] バーミキュライトに対するセシウムイオンの吸着と脱離2014

    • Author(s)
      森本 和也
    • Organizer
      学術振興会 鉱物新活用 第111委員会
    • Place of Presentation
      早稲田大学(新宿区)
    • Year and Date
      2014-07-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Study on Desorption of Cesium Ions Fixed in Vermiculite Clay2012

    • Author(s)
      K. Morimoto, S. Tomofuji, K. Tamura, A. Yamagishi, H. Sato
    • Organizer
      The 5th International Symposium on Environmental Economy and Technology
    • Place of Presentation
      Fukuoka
    • Related Report
      2012 Research-status Report
  • [Presentation] 粘土鉱物に吸着したセシウムイオンの脱離法の検討2012

    • Author(s)
      森本 和也、友藤 早紀、田村 堅志、山岸 晧彦、佐藤 久子
    • Organizer
      第1回環境放射能除染研究発表会
    • Place of Presentation
      福島
    • Related Report
      2012 Research-status Report
  • [Presentation] 層状ケイ酸塩に取り込まれたセシウムイオンの吸着構造の観察と脱離の検討2012

    • Author(s)
      森本 和也、小暮 敏博、田村 堅志、山岸 晧彦、佐藤 久子
    • Organizer
      日本化学会「低次元系光機能材料研究会」第1回サマーセミナー
    • Place of Presentation
      福岡
    • Related Report
      2012 Research-status Report
  • [Book] 重金属類汚染対策のための鉱物材料ガイドブック2012

    • Author(s)
      森本 和也(分担)
    • Total Pages
      226
    • Publisher
      ブイツーソリューション
    • Related Report
      2012 Research-status Report
  • [Remarks] 最近の研究:小暮研究室

    • URL

      http://www-gbs.eps.s.u-tokyo.ac.jp/kogure/study/study-index.html

    • Related Report
      2013 Research-status Report
  • [Remarks] 粘土鉱物にとりこまれたセシウムイオンについて

    • URL

      http://www.lab.toho-u.ac.jp/sci/chem/sakutai/research/clay_yamagishi5.html

    • Related Report
      2013 Research-status Report
  • [Remarks] 最近の研究:小暮研究室

    • URL

      http://www-gbs.eps.s.u-tokyo.ac.jp/kogure/study/study-index.html

    • Related Report
      2012 Research-status Report
  • [Remarks] 粘土鉱物にとりこまれたセシウムイオンについて

    • URL

      http://www.lab.toho-u.ac.jp/sci/chem/sakutai/research/clay_yamagishi5.html

    • Related Report
      2012 Research-status Report

URL: 

Published: 2013-05-31   Modified: 2019-07-29  

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