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Development of adsorbent with macro-pore silica beads for lithium isotope separation and separative analyses

Research Project

Project/Area Number 24760697
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nuclear fusion studies
Research InstitutionNagoya University

Principal Investigator

SUGIYAMA Takahiko  名古屋大学, 工学(系)研究科(研究院), 准教授 (90353440)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsリチウム / 同位体分離 / 置換クロマトグラフィー
Research Abstract

The purpose of the present study is to enhance a separative performance of displacement chromatography for enrichment of lithium isotope as a blanket material of a fusion reactor. A simulation code was developed based on a model where the mass transfer processes was consisted of convection and dispersion, transfer through liquid films, intraparticle diffusion and adsorption or desorption. The effects of adsorbent diameter on separative performances were estimated using the simulation code. An adsorbent was prepared by impregnating a macroporous silica beads with xylene solution of benzo-15-crown-5. Height equivalent to a theoretical plate (HETP) was estimated by Fujine's equation with data of breakthrough experiments for the adsorbent-packed column. The HETP value decreased with the adsorbent diameter. It becomes clear that the separative performance can be increased by adopting a small diameter of the adsorbent.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (14 results)

All 2014 2013 2012 Other

All Journal Article (2 results) (of which Peer Reviewed: 1 results) Presentation (12 results) (of which Invited: 2 results)

  • [Journal Article] Separative Analyses of Chromatographic Column Packed widh a Core-Shell Adsorbent for Lithium Isotope Separation2014

    • Author(s)
      T. Sugiyama, K. Sugiura, M. Tanaka, Y. Enokida
    • Journal Title

      Fusion Sci. Technol

      Volume: (in print)

    • Related Report
      2013 Final Research Report
  • [Journal Article] Separative Analyses of Chromatographic Column Packed with a Core-shell Adsorbent for Lithium Isotope Separation2014

    • Author(s)
      T. Sugiyama, K. Sugiura, M. Tanaka, Y. Enokida
    • Journal Title

      Fusion Science and Technology

      Volume: 0000

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 核融合炉ブランケットのためのリチウム同位体分離2013

    • Author(s)
      杉山貴彦
    • Organizer
      第32回溶媒抽出討論会
    • Place of Presentation
      名古屋大学,名古屋
    • Year and Date
      2013-11-22
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] リチウム同位体分離用コアシェル型吸着材の開発2013

    • Author(s)
      杉山貴彦,杉浦圭,榎田洋一,山本一良
    • Organizer
      日本原子力学会「2013年秋の大会」
    • Place of Presentation
      八戸工業大学,青森
    • Year and Date
      2013-09-04
    • Related Report
      2013 Final Research Report
  • [Presentation] 表面多孔質型吸着剤を充填したリチウム同位体分離用クロマトカラム内の物質移動解析2013

    • Author(s)
      杉山貴彦,杉浦圭,榎田洋一,山本一良
    • Organizer
      第11回同位体科学研究会
    • Place of Presentation
      産業技術総合研究所,臨界副都心センター
    • Year and Date
      2013-03-14
    • Related Report
      2013 Final Research Report
  • [Presentation] Separative Analyses of Chromatographic Column Packed widh a Core-Shell Adsorbent for Lithium Isotope Separation2013

    • Author(s)
      T. Sugiyama, K. Sugiura, M. Tanaka, Y. Enokida
    • Organizer
      10^<th> International Conference on Tritium Science and Technology
    • Place of Presentation
      Nice, France
    • Related Report
      2013 Final Research Report
  • [Presentation] Separative Analyses of Chromatographic Column Packed with a Core-shell Adsorbent for Lithium Isotope Separation2013

    • Author(s)
      T. Sugiyama, K. Sugiura, Y. Enokida, I. Yamamoto
    • Organizer
      10th International Conference on Tritium Science and Technology
    • Place of Presentation
      Nice, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] 表面多孔質型吸着剤を充填したリチウム同位体分離用クロマトカラム内の物質移動解析2013

    • Author(s)
      杉山 貴彦,杉浦 圭,榎田 洋一,山本 一良
    • Organizer
      第11回同位体科学研究会
    • Place of Presentation
      産業技術総合研究所 臨海副都心センター
    • Related Report
      2012 Research-status Report
  • [Presentation] 置換クロマトグラフィー法によるリチウム同位体分離における物質移動の解析2012

    • Author(s)
      杉浦圭,杉山貴彦,榎田洋一,山本一良
    • Organizer
      日本原子力学会「2012年秋の大会」
    • Place of Presentation
      広島大学,広島
    • Related Report
      2013 Final Research Report
  • [Presentation] 海水から回収したリチウムの同位体比の測定2012

    • Author(s)
      杉山貴彦,杉浦圭,西浜章平,吉塚和治,今川信作
    • Organizer
      日本原子力学会「2012年秋の大会」
    • Place of Presentation
      広島大学,広島
    • Related Report
      2013 Final Research Report
  • [Presentation] 海水から回収したリチウムの 同位体比の測定2012

    • Author(s)
      杉山貴彦,杉浦圭,西浜章平,吉塚和治,今川信作
    • Organizer
      日本原子力学会「2012年秋の大会」
    • Place of Presentation
      広島大学
    • Related Report
      2012 Research-status Report
  • [Presentation] 置換クロマトグラフィー法によるリチウム同位体分離における物質移動の解析2012

    • Author(s)
      杉浦圭,杉山貴彦,榎田洋一,山本一良
    • Organizer
      日本原子力学会「2012年秋の大会」
    • Place of Presentation
      広島大学
    • Related Report
      2012 Research-status Report
  • [Presentation] リチウム同位体分離用コアシェル型吸着材の開発

    • Author(s)
      杉山貴彦,杉浦圭,榎田洋一,山本一良
    • Organizer
      日本原子力学会「2013年秋の大会」
    • Place of Presentation
      八戸工業大学,青森
    • Related Report
      2013 Annual Research Report
  • [Presentation] 核融合炉ブランケットのためのリチウム同位体分離

    • Author(s)
      杉山貴彦
    • Organizer
      第32回溶媒抽出討論会
    • Place of Presentation
      名古屋大学,名古屋
    • Related Report
      2013 Annual Research Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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