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Radiation effects in processing of radioactive water by inorganic adsorbents

Research Project

Project/Area Number 24760721
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nuclear engineering
Research InstitutionJapan Atomic Energy Agency

Principal Investigator

KUMAGAI Yuta  独立行政法人日本原子力研究開発機構, 原子力科学研究部門 原子力基礎工学研究センター, 研究員 (70455294)

Project Period (FY) 2012-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2014: ¥390,000 (Direct Cost: ¥300,000、Indirect Cost: ¥90,000)
Fiscal Year 2013: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2012: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywords放射線効果 / 水の放射線分解 / 固液混合物 / ゼオライト / 水素 / 過酸化水素 / 酸素
Outline of Final Research Achievements

Zeolite adsorbents are used for removal of radioactive ions from water because of their high radiation resistance and selective ion-exchange property. However, radiation chemistry in solid/liquid systems is not adequately understood in order to estimate radiation effects in the water treatments by zeolite adsorbents. Hence, reactions and products induced by irradiation of the mixtures of zeolites and water were studied. This study revealed that irradiation of zeolites in water produces hydrogen additional to the hydrogen production by direct radiolysis of water. Moreover, the results of this study showed that accumulation of hydrogen peroxide is inhibited due to decomposition of adsorbed hydrogen peroxide on the zeolites by energy deposition on the zeolites. These effects of zeolites were quantitatively formulated and a reaction model for zeolite/water mixture was proposed by incorporating the zeolite effects into the reaction model of water radiolysis.

Report

(4 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • 2012 Research-status Report
  • Research Products

    (16 results)

All 2015 2014 2013 2012 Other

All Journal Article (5 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 2 results) Presentation (11 results) (of which Invited: 1 results)

  • [Journal Article] 水溶液とゼオライトとの混合物中でのγ線照射による2-chlorophenolの分解2015

    • Author(s)
      熊谷 友多
    • Journal Title

      放射線化学

      Volume: 99

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of oxygen on radiolytic hydrogen production from X-type zeolite-water mixtures.2014

    • Author(s)
      Y. Kumagai, A. Kimura, M. Taguchi
    • Journal Title

      Proceedings of 2014 Nuclear Plant Chemistry Conference (NPC2014)

      Volume: 10043 Pages: 1-9

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Decomposition of Hydrogen Peroxide by gamma-ray Irradiation in Mixture of Aqueous solution and Y-Type Zeolite2014

    • Author(s)
      Yuta Kumagai
    • Journal Title

      Radiation Physics and Chemistry

      Volume: 97 Pages: 223-232

    • DOI

      10.1016/j.radphyschem.2013.12.006

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Hydrogen production in gamma radiolysis of the mixture of mordenite and seawater2012

    • Author(s)
      Yuta Kumagai
    • Journal Title

      Journal of Nuclear Science and Technology

      Volume: 50 Issue: 2 Pages: 130-138

    • DOI

      10.1080/00223131.2013.757453

    • NAID

      120006683976

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Journal Article] Effects of alumina powder characteristics on H2 and H2O2 production yield in gamma-radiolysis of water and 0.4 M H2SO4 aqueous solution2012

    • Author(s)
      Reiji Yamada, Yuta Kumagai
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 37 Issue: 18 Pages: 13272-13277

    • DOI

      10.1016/j.ijhydene.2012.06.062

    • Related Report
      2012 Research-status Report
    • Peer Reviewed
  • [Presentation] Hydrogen and hydrogen peroxide productions by γ-irradiation of A-, X-, Y- and mordenite type zeolites in aqueous solution.2015

    • Author(s)
      Y. Kumagai, A. Kimura, M. Taguchi
    • Organizer
      15th International Congress on Radiation Research
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2015-05-25 – 2015-05-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水溶液中でのゼオライト吸着質の放射線誘起反応2015

    • Author(s)
      熊谷友多,木村敦,田口光正
    • Organizer
      先端放射線化学シンポジウム(SARAC2015)
    • Place of Presentation
      東京大学
    • Year and Date
      2015-03-05 – 2015-03-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of a high-silica mordenite-type zeolite on degradation of 2-chlorophenol in aqueous solution by γ-ray irradiation.2014

    • Author(s)
      Y. Kumagai
    • Organizer
      The 5th Asia Pacific Symposium on Radiation Chemistry
    • Place of Presentation
      東京大学
    • Year and Date
      2014-09-08 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水溶液-ゼオライト混合系での照射による過酸化水素分解挙動の反応解析 1.過酸化水素のゼオライトへの吸着と放射線分解2013

    • Author(s)
      熊谷友多
    • Organizer
      第56回放射線化学討論会
    • Place of Presentation
      広島大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 水溶液-ゼオライト混合系での照射による過酸化水素分解挙動の反応解析 2. 水素発生と気泡形成の影響2013

    • Author(s)
      熊谷友多
    • Organizer
      第56回放射線化学討論会
    • Place of Presentation
      広島大学
    • Related Report
      2013 Research-status Report
  • [Presentation] ガンマ線照射による水溶液中のゼオライトからの水素発生2013

    • Author(s)
      熊谷友多
    • Organizer
      日本原子力学会2014年春の年会
    • Place of Presentation
      東京都市大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 水-ゼオライト混合物中での過酸化水素の放射線分解モデルの検討2013

    • Author(s)
      熊谷友多  間柄正明
    • Organizer
      日本原子力学会 2013年春の年会
    • Place of Presentation
      大阪
    • Related Report
      2012 Research-status Report
  • [Presentation] Production of Hydrogen and Hydrogen peroxide by gamma-radiolysis of water in the presence of Y-type zeolite2012

    • Author(s)
      Yuta Kumagai, Atsushi Kimura, Reiji Yamada, Ryuji Nagaishi, Mitsumasa Taguchi
    • Organizer
      The 4th Asia-Pacific Symposium on Radiation Chemistry
    • Place of Presentation
      Huangsha, China
    • Related Report
      2012 Research-status Report
  • [Presentation] 放射性汚染水処理における放射線効果に関する研究 (5)ゼオライトと水との混合物のガンマ線分解による水素発生量の温度依存性2012

    • Author(s)
      熊谷友多 永石隆二 木村敦 田口光正 西原健司 山岸功
    • Organizer
      日本原子力学会 2012年秋の大会
    • Place of Presentation
      広島
    • Related Report
      2012 Research-status Report
  • [Presentation] 水-ゼオライト混合物のγ線照射による過酸化水素の生成と分解2012

    • Author(s)
      熊谷友多 木村敦 永石隆二 田口光正 間柄正明
    • Organizer
      第55回放射線化学討論会
    • Place of Presentation
      宮城
    • Related Report
      2012 Research-status Report
  • [Presentation] 水溶液中のゼオライトへのガンマ線照射により細孔内で誘起される水素発生と過酸化水素分解

    • Author(s)
      熊谷友多
    • Organizer
      第17回弥生研究会 放射線効果の解明と応用
    • Place of Presentation
      東京大学
    • Related Report
      2013 Research-status Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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