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Nano-materials Design for High Performance Metal-Air Batteries

Research Project

Project/Area Number 24760731
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Energy engineering
Research InstitutionKyushu University

Principal Investigator

YUASA Masayoshi  九州大学, 総合理工学研究科(研究院), 助教 (50404075)

Project Period (FY) 2012-04-01 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords電池 / 酸素還元 / 触媒 / ペロブスカイト型酸化物 / ナノ粒子 / 白金代替 / ナノ粒子合成 / 空気電池 / 放電特性
Research Abstract

In order to improve the electrode potential for the oxygen reduction reaction of air electrode, the effect of the composition of La-Mn based perovskite-type oxides on the oxygen reduction activity and the effect of the doubly loading of LaMnO3 and Pt on the carbon-support were investigated. As the result of substituting Ca and Fe for LaMnO3 nanoparticles, the optimum oxygen reduction activity was obtained at Ca=0.4 and Fe=0.1 because the valence state of B-sipe in the perovskite-type oxide was well optimized. The doubly loading of LaMnO3 and Pt on the carbon-support revealed that Pt is effective to improve the on-set potential for the oxygen reduction reaction, and that LaMnO3 is effective to reduce the overpotential for oxygen reduction reaction.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Research-status Report
  • Research Products

    (6 results)

All 2014 2013

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (4 results) (of which Invited: 4 results)

  • [Journal Article] Oxygen reduction activity of carbon-supported La_<1-x>Ca_xMn_1-yFe_yO_3 nanoparticles2013

    • Author(s)
      Masayoshi Yuasa, Naoki Tachibana, Kengo Shimanoe
    • Journal Title

      Chemistry of Materials

      Volume: Vol 25 Pages: 3072-3079

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oxygen reduction activity of carbon-supported La1-xCaxMn1-yFeyO3 nanoparticles2013

    • Author(s)
      Masayoshi Yuasa, Naoki Tachibana, Kengo Shimanoe
    • Journal Title

      Chemistry of Materials

      Volume: 25 Issue: 15 Pages: 3072-3079

    • DOI

      10.1021/cm401276y

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Air electrode using perovskite-type oxides for metal-air batteries2014

    • Author(s)
      Masayoshi Yuasa
    • Organizer
      Collaborative Conference on Materials Research 2014
    • Place of Presentation
      Incheon, Korea
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Air electrode using perovskite-type oxides for metal air batteries2014

    • Author(s)
      Masayoshi Yuasa
    • Organizer
      Collaborative Conference on Materials Research 2014
    • Place of Presentation
      大韓民国, 仁川広域市
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Perovskite-type Oxide as an Electrocatalyst for The Metal-Air Battery2013

    • Author(s)
      Masayoshi Yuasa, Naoki Tachibana, Kengo Shimanoe
    • Organizer
      7^<th> Asian Conference on Electrochemical Power Sources
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2013 Final Research Report
    • Invited
  • [Presentation] Perovskite-type Oxide as an Electrocatalyst for The Metal-Air Battery2013

    • Author(s)
      Masayoshi Yuasa, Naoki Tachubana, Kengo Shimanoe
    • Organizer
      7th Asian Conference on Electrochemical Power Sources
    • Place of Presentation
      大阪市
    • Related Report
      2013 Annual Research Report
    • Invited

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Published: 2013-05-31   Modified: 2019-07-29  

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