| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2012: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
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| Outline of Final Research Achievements |
We have developed the efficient synthetic methods of heterocyclic compounds by means of cascade reactions and multi-component reactions based on each of the following reactions: 1) syntheses of polycyclic isochromane and benzofuran via Au-catalyzed carboalkoxylation reactions, 2) syntheses of oxazoles and imidazoles by metal-free [2+2+1]annulation reactions, and 3) syntheses of fluorinated oxazoles through hypervalent iodine-mediated cycloisomerization-fluorination reaction.
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