| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2015: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2012: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Outline of Final Research Achievements |
I studied the following reactions using unstable chemical species such as aryne and radical for developing rapid and/or efficient reactions. In general, it was difficult to control the reaction using these species. But I succeeded new one-pot synthesis of dihydrobenzofuran, benzofuran, and 4H-chromene via the insertion reaction of aryne into the C=O pai-bond of formamides. I also developed catalytic radical cascade reactions in aqueous media using the photocatalyst under visible light irradiation. I reported the results of experiments to prove the utility of the dye-supported polycrystalline titanium dioxide in the hydrogenation of aromatic ketones.
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