Development of Hydrogen-bonded Purely Organic Single-component Molecular Conductors
| Project/Area Number |
24850006
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional materials chemistry
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| Research Institution | The University of Tokyo |
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Principal Investigator |
UEDA Akira 東京大学, 物性研究所, 助教 (20589585)
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| Project Period (FY) |
2012-08-31 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | 有機伝導体 / 水素結合 / テトラチアフルバレン / カテコール / 単一ユニット伝導体 / 重水素化 / セレン原子導入 |
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| Research Abstract |
Hydrogen-bonded purely organic single-component (unit) molecular conductors based on tetrathiafulvalene (TTF)-type organic pi-electron donor molecules fused with hydrogen-bonding functional groups were synthesized and characterized. Interestingly, the conductivity of the catechol-fused TTF-based single-unit organic conductor system is enhanced by the substitution of its hydrogen-bonded proton with deuteron, although the parent and deuterated systems are isostructural each other at room temperature.
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Report
(3 results)
Research Products
(33 results)
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[Journal Article] Ground State and Pressure-induced Superconductivity of Checkerboard-type Charge-ordered Molecular Conductor beta-(meso-DMBEDT-TTF)_2X (X = PF_6 and AsF_6)2012
Author(s)
T.Shikama, T.Shimokawa, S.Lee, T.Isono, A.Ueda , K.Takahashi, A.Nakao , R.Kumai, H.Nakao, K.Kobayashi, Y.Murakami, M.Kimata, H.Tajima, K.Matsubayashi, Y.Uwatoko, Y.Nishio, K.Kajita, and H.Mori
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Journal Title
Crystals
Volume: 2
Issue: 4
Pages: 1502-1513
DOI
Related Report
Peer Reviewed
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[Journal Article] Charge-order driven proton arrangement in a hydrogen-bonded charge-transfer complex based on a pyridyl-substituted TTF derivative2012
Author(s)
S.Lee, A.Ueda, H.Kamo, K.Takahashi, M.Uruichi, K.Yamamoto, K.Yakushi, A.Nakao, R.Kumai, K.Kobayashi, H.Nakao, Y.Murakami, and H.Mori
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Journal Title
Chem. Commun
Volume: 48
Issue: 69
Pages: 8673-8675
DOI
Related Report
Peer Reviewed
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