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Preparation of Oxide Mesocrystal Films and Their Application to Transparent Conducting Films

Research Project

Project/Area Number 24860031
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Inorganic materials/Physical properties
Research InstitutionShinshu University

Principal Investigator

WAGATA Hajime  信州大学, 工学部, 助教 (40633722)

Project Period (FY) 2012-08-31 – 2014-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords酸化亜鉛 / 水溶液法 / 透明導電膜 / スピンスプレー法 / 溶液法 / スピンスプレー / メソクリスタル / イオン液体
Research Abstract

In this research, we aim low-temperature fabrication of metal oxide crystal films for substitution of tin-doped indium oxide by a new film processing technique which can achieve low environmental load, high deposition rate, and cost effectiveness. ZnO films with visible-light transparency over 70 percents and electrical resistivity about 5X10-3 ohm cm were successfully fabricated by spin-spray method with controlling the flow rate of solution and rotation rate of table. When water-soluble polymer was used as an additive, the crystal shape was changed by different manner with trisodium citrate. The performance of ZnO films prepared by using water-soluble polymer was not improved compared with those prepared with trisodium citrate. The results indicated that the adsorbed organics and film structure strongly affected electrical properties.

Report

(3 results)
  • 2013 Annual Research Report   Final Research Report ( PDF )
  • 2012 Annual Research Report
  • Research Products

    (15 results)

All 2013 2012 Other

All Journal Article (5 results) (of which Peer Reviewed: 4 results) Presentation (10 results) (of which Invited: 3 results)

  • [Journal Article] 低環境負荷溶液プロセスによる透明導電性酸化亜鉛膜の作製2013

    • Author(s)
      我田元,是津信行,手嶋勝弥,大石修治
    • Journal Title

      ケミカルエンジニヤリング

      Volume: 58 Pages: 67-73

    • Related Report
      2013 Annual Research Report 2013 Final Research Report
  • [Journal Article] An aqueous Solution Process and Subsequent UV Treatment for Highly Transparent Conductive ZnO films2012

    • Author(s)
      Hajime Wagata, Naoki Ohashi, Ken-ichi Katsumata, Kiyoshi Okada, Nobuhiro, Matsushita
    • Journal Title

      J. Mater. Chem.

      Volume: 22 Pages: 20706-20712

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Illuminated Light Wavelength on Electric Resistance of Zinc Oxide Films Prepared by Spin-Spray Method2012

    • Author(s)
      H. Wagata, K. Katsumata, N. Ohashi, K. Okada, N. Matsushita, S. Oishi, K. Teshima
    • Journal Title

      J. Flux Growth

      Volume: 7 Pages: 55-59

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] An aqueous solution process and subsequent UV treatment for highly transparent conductive ZnO films2012

    • Author(s)
      Hajime Wagata
    • Journal Title

      Journal of Materials Chemistry

      Volume: 22 Issue: 38 Pages: 20706-20712

    • DOI

      10.1039/c2jm33584k

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Illuminated Light Wavelength on Electric Resistance of Zinc Oxide Films Prepared by Spin-Spray Method2012

    • Author(s)
      Hajime Wagata
    • Journal Title

      Journal of Flux Growth

      Volume: 7 Pages: 55-59

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Presentation] Fabrication of transparent zinc oxide crystal layers by spin-spray method2013

    • Author(s)
      Naoya Harata, Hajime Wagata, Nobuyuki Zettsu, Shuji Oishi, Katsuya Teshima
    • Organizer
      The 1st International Conference on Surface Engineering
    • Place of Presentation
      Korea
    • Year and Date
      2013-11-18
    • Related Report
      2013 Final Research Report
  • [Presentation] スピンスプレー形成された酸化亜鉛結晶層の光触媒活性および表面化学状態の解析2013

    • Author(s)
      我田元,大石修治,手嶋勝弥
    • Organizer
      表面技術協会第127回講演大会
    • Place of Presentation
      埼玉
    • Year and Date
      2013-03-18
    • Related Report
      2013 Final Research Report
  • [Presentation] 塩化コリン-尿素DES フラックス熱分解法による酸化亜鉛結晶の育成2013

    • Author(s)
      我田元
    • Organizer
      日本セラミックス協会2013年年会
    • Place of Presentation
      東京工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] スピンスプレー形成された酸化亜鉛結晶層の光触媒活性および表面化学状態の解析2013

    • Author(s)
      我田元
    • Organizer
      表面技術協会第127回講演大会
    • Place of Presentation
      日本工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] スピンスプレー法による低温水溶液中での酸化物結晶層の直接形成2012

    • Author(s)
      我田元,大石修治,大橋直樹,勝又健一,岡田清,松下伸広,手嶋勝弥
    • Organizer
      日本結晶成長学会第42回結晶成長国内会議(NCG42)
    • Place of Presentation
      福岡
    • Year and Date
      2012-11-09
    • Related Report
      2013 Final Research Report
  • [Presentation] Facile Spin-Spray Method for Low-Temperature Fabrication of Metal Oxide Films2012

    • Author(s)
      Hajime Wagata
    • Organizer
      2012 Collaborative Conference on Crystal Growth
    • Place of Presentation
      Double Tree by Hilton at Orlando (Florida)
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Transparent Conductive ZnO Films Prepared by Spin-Spray Method and Subsequent UV Treatment2012

    • Author(s)
      Hajime Wagata
    • Organizer
      International Union of Materials Research Societies-International Conference on Electronic Materials 2012
    • Place of Presentation
      Pacifico Yokohama
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Fabrication of transparent zinc oxide crystal layers by spin-spray method

    • Author(s)
      Naoya Harata, Hajime Wagata, Nobuyuki Zettsu, Shuji Oishi, Katsuya Teshima
    • Organizer
      The 1st International Conference on Surface Engineering (ICSE2013)
    • Place of Presentation
      Haeundae Grand Hotel, Busan, Korea
    • Related Report
      2013 Annual Research Report
  • [Presentation] Growth of Idiomorphic ZnO Crystals by Thermal Decomposition of an Ionic Liquid Flux

    • Author(s)
      Hajime Wagata, Nobuyuki Zettsu, Shuji Oishi, Katsuya Teshima
    • Organizer
      The 1st International Conference on Surface Engineering (ICSE2013)
    • Place of Presentation
      Haeundae Grand Hotel, Busan, Korea
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水溶液法による透明導電性酸化亜鉛膜の創製

    • Author(s)
      我田元,是津信行,大石修治,手嶋勝弥
    • Organizer
      表面技術協会・ナノテク部会 第52回研究会
    • Place of Presentation
      東京ビッグサイト
    • Related Report
      2013 Annual Research Report
    • Invited

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Published: 2012-11-27   Modified: 2019-07-29  

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