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High Voltage Electron Phase Differential Microscopy of Metal-Ion Conductor Interfaces

Research Project

Project/Area Number 25246001
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanostructural chemistry
Research InstitutionNagoya University

Principal Investigator

Tanji Takayoshi  名古屋大学, 未来社会創造機構, 研究員 (90125609)

Co-Investigator(Renkei-kenkyūsha) 臼倉 治郎  名古屋大学, 理学部, 特任教授 (30143415)
川﨑 忠寛  名古屋大学, 未来材料システム研究所, 客員准教授 (10372533)
石田 高史  名古屋大学, 未来材料システム研究所, 助教 (60766525)
Research Collaborator 富田 正弘  (株)真空デバイス
Project Period (FY) 2013-10-21 – 2017-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥42,770,000 (Direct Cost: ¥32,900,000、Indirect Cost: ¥9,870,000)
Fiscal Year 2016: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2015: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2014: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000)
Fiscal Year 2013: ¥21,060,000 (Direct Cost: ¥16,200,000、Indirect Cost: ¥4,860,000)
Keywords電子線位相微分顕微鏡法 / A-B効果位相板 / 環境電子顕微鏡 / 超高圧走査透過電子顕微鏡 / 固体酸化物形燃料電池 / 非染色生体試料観察 / 電界分布観察 / 透過電子顕微鏡 / 位相板 / 電子線ホログラフィー / 固体酸化物型燃料電池 / 界面 / 細胞脂質二重膜 / 電界観察 / 超高圧電子顕微鏡 / 電子顕微鏡 / 位相微分電子顕微鏡 / 表面・界面 / 生体材料 / 燃料電池
Outline of Final Research Achievements

In order to observe the phenomenon including the property of ions at the triple interface of electrolyte, electrode and gas environment in a solid oxide type fuel cell by means of an ultra high voltage environmental electron microscope equipped with a LaB6 thermionic electron gun, we developed 1) a special phase plate holder placed under the intermediate lens, 2 ) a special specimen holder which can heat and apply external voltage to the specimen in the gas atmosphere, and 3) the specimen preparation technique by a focused ion beam instrument. Using these instruments and technique we observed 1) the behavior of Oxygen ions at the interfaces of Pt/YSZ and Pt/GDC by electron microscopy, electron energy loss spectroscopy and 2) the electric field inside and outside of charged latex sphere and 3) at the p-n junction in a semiconductor of GaAs, and also observed 4) non stained biomaterials.

Report

(5 results)
  • 2017 Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (43 results)

All 2017 2016 2015 2014 2013 Other

All Int'l Joint Research (3 results) Journal Article (7 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results,  Open Access: 4 results) Presentation (30 results) (of which Int'l Joint Research: 14 results,  Invited: 3 results) Book (1 results) Patent(Industrial Property Rights) (2 results)

  • [Int'l Joint Research] 大連工業大学(中国)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] University of Victoria(カナダ)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] ビクトリア大学(カナダ)

    • Related Report
      2014 Annual Research Report
  • [Journal Article] 環状分割検出器を用いたホロコーンSTEMによる位相再生2017

    • Author(s)
      石田高史、川﨑忠寬、丹司敬義、生田孝
    • Journal Title

      顕微鏡

      Volume: 52 Pages: 13-18

    • NAID

      130007689129

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Quantitative evaluation of annular bright-field phase images in STEM2015

    • Author(s)
      T. Ishida, T. Kawasaki, T. Tanji and T. Ikuta
    • Journal Title

      Microscopy

      Volume: 64 Issue: 2 Pages: 121-128

    • DOI

      10.1093/jmicro/dfu113

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Determination of three-dimensional strain state in crystals using self-interfered split HOLZ lines2015

    • Author(s)
      R. Herring, M. Norouzpour, K. Saitoh, N. Tanaka, T. Tanji
    • Journal Title

      Ultramicroscopy

      Volume: 156 Pages: 37-40

    • DOI

      10.1016/j.ultramic.2015.04.013

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Phase reconstruction in annular bright-field scanning transmission electron microscopy2014

    • Author(s)
      T. Ishida, T. Kawasaki, T. Tanji, T. Kodama, T. Matsutani, K. Ogai and T. Ikuta
    • Journal Title

      Microscopy

      Volume: 64 Issue: 2 Pages: 69-76

    • DOI

      10.1093/jmicro/dfu098

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] In situ transmission electron microscopy of ionic conductivity and reaction mechanisms in ultrathin solid oxide fuel cells2014

    • Author(s)
      A. H. Tavabi, S. Arai, S. Muto, T. Tanji, R. E. Dunin-Borkowski
    • Journal Title

      Microscopy and Microanalysis

      Volume: 20 Issue: 6 Pages: 1817-1825

    • DOI

      10.1017/s143192761401349x

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Synthesis of Zirconia Oxide (ZrO2) Nanofibers on Zirconnia Substrates by Ultrasonic Spray Pyrolysis2014

    • Author(s)
      J.-H. Zhang, W. Li, T. Tanji
    • Journal Title

      Materials Sciences and Applications

      Volume: 5 Issue: 04 Pages: 193-198

    • DOI

      10.4236/msa.2014.54024

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Image Processing for Phase Imperfections in Electron Holography2013

    • Author(s)
      W. Li, J.-H. Zhang and T. Tanji
    • Journal Title

      Microscopy

      Volume: 62 Issue: 6 Pages: 583-588

    • DOI

      10.1093/jmicro/dft034

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Electron Differential Microscopy with an A-B Effect Phase Plate2017

    • Author(s)
      T.Tanji,T.Ishida and W. Li
    • Organizer
      Analytix 2017
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Contrast Enhancement of Biological Specimens by Differential Phase Electron Microscopy using the Aharonov-Bohm Effect2017

    • Author(s)
      T. Ishida, W. Li, T. Tanji, Y. Yamamoto and K. Saitoh
    • Organizer
      International Conference on Materials and Systems for Sustainability 2017
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of TEM Specimen Holders with Three Electrodes for In-Situ Observation2017

    • Author(s)
      H. Hiroshima, T. Ishida, T. Tanji, M. Tomita, K. Higuchi and K. Saitoh
    • Organizer
      International Conference on Materials and Systems for Sustainability 2017
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of a voltage applying and heating specimen holder for observation of solid oxide fuel cell’s reactions in environmental TEM2017

    • Author(s)
      T. Ishida, H. Hiroshima, K. Higuchi, T. Tanji, M. Tomita and K. Saitoh
    • Organizer
      11th International Symposium on Atomic Level Characterizations for New Materials and Devices ’17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体酸化物形燃料電池その場観察のための三端子試料ホルダーの開発2017

    • Author(s)
      廣嶋 秀斗、石田 高史、丹司 敬義、富田 正弘、樋口 公孝、齋藤 晃
    • Organizer
      日本顕微鏡学会第73回学術講演会
    • Related Report
      2016 Annual Research Report
  • [Presentation] Electron differetial phase microscopy with an A-B effect phase plate2016

    • Author(s)
      T. Tanji
    • Organizer
      Symposium on Surface and Nano Science
    • Place of Presentation
      Furano, Japan
    • Year and Date
      2016-01-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Visualization of Active Reaction Site on Gold Nanoparticulate Catalyst2016

    • Author(s)
      T. Kawasaki, K. Yoshida, T. Ishida and T. Tanji
    • Organizer
      Asia Pacific Microscopy Conference 11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Development of an In-Situ Specimen Holder for High-Voltage Environmental Electron Microscopy of Fuel Cells2016

    • Author(s)
      T. Ishida, T. Tanji, M. Tomita, K. Higuchi and K. Saitoh
    • Organizer
      The 16th European Microscopy Congress
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] STEM Phase Retrieval Method for Thick Specimen by Using Quasi-Bessel Beam2016

    • Author(s)
      T. Kawasaki, T. Ishida, T. Kodama and T. Tanji, T. Ikuta
    • Organizer
      The 16th European Microscopy Congress
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 金ナノ粒子触媒の活性反応サイトの可視化2016

    • Author(s)
      川﨑忠寛、吉田要、石田高史、丹司敬義
    • Organizer
      日本顕微鏡学会第72回学術講演会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 固体酸化物形燃料電池その場観察のための超高圧電子顕微鏡試料ホルダーの開発2016

    • Author(s)
      石田高史、丹司敬義、富田正弘、樋口公孝 、齋藤晃
    • Organizer
      日本顕微鏡学会第72回学術講演会
    • Related Report
      2016 Annual Research Report
  • [Presentation] 固体酸化物型燃料電池のその場観察のための電圧印加・加熱試料ホルダーの開発2015

    • Author(s)
      石田高史,丹司敬義,富田正弘,樋口公孝
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] Simulation of phase imperfection restoration in electron holography in noisy case2015

    • Author(s)
      W. Li and T. Tanji
    • Organizer
      The 2nd East Asia Microscopy Conference (EAMC2)
    • Place of Presentation
      Himeji, Japan
    • Year and Date
      2015-11-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A-B効果を用いたヒルベルト位相板の開発2015

    • Author(s)
      石田高史,李偉,丹司敬義
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] New quantitative phase reconstruction technique using hollow-cone probe and annularly arrayed detectors in STEM2015

    • Author(s)
      T. Ishida, T. Kawasaki and T. Tanji
    • Organizer
      Microscopy & Microanalysis
    • Place of Presentation
      Portland, USA
    • Year and Date
      2015-08-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electron differential phase microscopy with an A-B effect phase plate2015

    • Author(s)
      T. Tanji, H. Niimi, J. Usukura and Y. Yamamoto
    • Organizer
      Microscopy & Microanalysis
    • Place of Presentation
      Portland, USA
    • Year and Date
      2015-08-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] n situ observation of propene epoxidation by gold nanoparticles supported on anatase TiO22015

    • Author(s)
      T. Kawasaki, H. Murase, K. Yoshida and T. Tanji
    • Organizer
      Microscopy & Microanalysis
    • Place of Presentation
      Portland, USA
    • Year and Date
      2015-08-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A-B効果位相板を用いた電子線微分干渉顕微鏡法の開発Ⅲ2015

    • Author(s)
      丹司敬義, 新美博久, 山本悠太, 臼倉治郎
    • Organizer
      日本顕微鏡学会第71回学術講演会
    • Place of Presentation
      京都
    • Year and Date
      2015-05-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Differential phase contrast electron microscopy with an A-B effect phase plate'2014

    • Author(s)
      H. Niimi, U. Ikeda, T. Tanji and J. Usukura
    • Organizer
      日本顕微鏡学会第58回シンポジウム
    • Place of Presentation
      福岡
    • Year and Date
      2014-11-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] Electron differential phase microscopy with an A-B effect phase plate2014

    • Author(s)
      T. Tanji, U. Ikeda, H. Niimi and J. Usukura
    • Organizer
      18th International Microscopy Congress
    • Place of Presentation
      Prague, Czech Republic
    • Year and Date
      2014-09-07
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Phase Reconstruction in Annular Bright Field STEM2014

    • Author(s)
      T. Ishida, T. Kawasaki, T. Kodama, K. Ogai, T. Ikuta and T. Tanji
    • Organizer
      18th International Microscopy Congress
    • Place of Presentation
      Prague, Czech Republic
    • Year and Date
      2014-09-07
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A-B効果位相板を用いた電子線微分干渉顕微鏡法の開発2014

    • Author(s)
      池田 宇輝,丹司 敬義,臼倉 治郎
    • Organizer
      日本顕微鏡学会
    • Place of Presentation
      千葉
    • Year and Date
      2014-05-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] 環境電子顕微鏡用の液体セルの開発2014

    • Author(s)
      今枝紀裕,村瀬弘樹,川﨑忠寛,山崎佳代,松谷貴臣,丹司敬義
    • Organizer
      第61回応用物理学会春季学術講演会
    • Place of Presentation
      相模原市
    • Related Report
      2013 Annual Research Report
  • [Presentation] A-B効果位相版を用いた電子線微分干渉顕微鏡法の開発2014

    • Author(s)
      池田宇輝、丹司敬義、臼倉治郎
    • Organizer
      日本顕微鏡学会第70回学術講演会
    • Place of Presentation
      幕張
    • Related Report
      2013 Annual Research Report
  • [Presentation] Electron differential phase microscopy with an A-B effect phase plate2014

    • Author(s)
      T. Tanji, U. Ikeda, H. Niimi, J. Usukura
    • Organizer
      International Microscopy Congress2014
    • Place of Presentation
      Prague, Czech
    • Related Report
      2013 Annual Research Report
  • [Presentation] 環境電子顕微鏡用の液体セルの開発2013

    • Author(s)
      今枝紀裕,川﨑忠寛,丹司敬義
    • Organizer
      日本顕微鏡学会第57回シンポジウム
    • Place of Presentation
      名古屋市
    • Related Report
      2013 Annual Research Report
  • [Presentation] 金ナノ粒子の触媒反応による構造変化の原子分解能観察2013

    • Author(s)
      伊藤陽,川﨑忠寛,丹司敬義
    • Organizer
      日本顕微鏡学会第57回シンポジウム
    • Place of Presentation
      名古屋市
    • Related Report
      2013 Annual Research Report
  • [Presentation] Development of C/SiN hybrid E-cell membranes and application to in-situ observations of nano-particulate gold catalyst2013

    • Author(s)
      T. Kawasaki, N. Imaeda, A. Itou and T. Tanji
    • Organizer
      ALC '13
    • Place of Presentation
      Kona, USA
    • Related Report
      2013 Annual Research Report
  • [Presentation] In situ study of Pt/GDC interface by electron holography2013

    • Author(s)
      T. Narushima, A. H. Tavabi, T. Tanji
    • Organizer
      ISETS '13
    • Place of Presentation
      名古屋市
    • Related Report
      2013 Annual Research Report
  • [Presentation] Electron Holography of Interfaces between Metal and Oxide Ionic Conductor2013

    • Author(s)
      T. Tanji
    • Organizer
      IUMRS ICA2013
    • Place of Presentation
      Bangalor, India
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] 環境調和型社会のためのナノ材料科学2015

    • Author(s)
      丹司敬義 他 (名古屋大学エコトピア科学研究所 編)
    • Publisher
      コロナ社
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 電子顕微鏡用試料加熱・印加装置2016

    • Inventor(s)
      富田正弘、丹司敬義、石田高史、浮穴基英、吉田寿治
    • Industrial Property Rights Holder
      株式会社真空デバイス
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-02-05
    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] 荷電粒子ビーム用電磁レンズの球面収差補正装置2015

    • Inventor(s)
      川﨑忠寬、生田孝、丹司敬義
    • Industrial Property Rights Holder
      名古屋大学総長
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-04-27
    • Related Report
      2015 Annual Research Report

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Published: 2013-10-24   Modified: 2019-07-29  

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