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Development of open-cell type nanoporous silicon for long lifetime and high capacity lithium secondary battery electrode

Research Project

Project/Area Number 25246009
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials engineering
Research InstitutionTohoku University

Principal Investigator

Hidemi Kato  東北大学, 金属材料研究所, 教授 (80323096)

Co-Investigator(Kenkyū-buntansha) 和田 武  東北大学, 金属材料研究所, 助教 (10431602)
市坪 哲  京都大学, 工学(系)研究科(研究院), 准教授 (40324826)
Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥45,890,000 (Direct Cost: ¥35,300,000、Indirect Cost: ¥10,590,000)
Fiscal Year 2016: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2015: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2014: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2013: ¥27,690,000 (Direct Cost: ¥21,300,000、Indirect Cost: ¥6,390,000)
Keywordsポーラス材料 / リチウム二次電池 / 負極 / シリコン / デアロイング / リチウムイオン二次電池 / 活物質 / 多孔体 / 多孔質 / 脱成分法 / 負極材料 / ナノ多孔体 / ナノ材料 / 創製プロセス
Outline of Final Research Achievements

A dealloying in metallic melt, a novel top-down process for preparing nanoporous Si powder was developed. By immersing magnesium-silicon alloy precursor in bismuth metal melt, magnesium selectively dissolved into bismuth melt and the remaining silicon atoms self-organized into an open-cell type nanoporous structure. A lithium secondary battery anode made with the developed nanoporous Si exhibited about 3 times higher capacity than that of graphite anode and extremely long lifetime exceeding 1500 cycles.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (48 results)

All 2017 2016 2015 2014 2013 Other

All Int'l Joint Research (5 results) Journal Article (10 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 8 results,  Acknowledgement Compliant: 6 results) Presentation (31 results) (of which Int'l Joint Research: 12 results,  Invited: 9 results) Book (1 results) Remarks (1 results)

  • [Int'l Joint Research] Brookhaven National Laboratory(米国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] INSA deLyon(フランス)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Helmholtz-Zentrum Geesthacht(ドイツ)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Brookhaven National Laboratory(米国)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] INSA de Lyon(フランス)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Cold-rolling influence on microstructure and mechanical properties of NiCr-Ag composites and porous NiCr obtained by liquid metal dealloying2017

    • Author(s)
      Morgane Mokhtari; Christophe Le Bourlot; Jer ome Adrien; Sylvain Dancette; Takeshi Wada; Jannick Duchet-Rumeau; Hidemi Kato; Eric Maire
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 707 Pages: 251-256

    • DOI

      10.1016/j.jallcom.2016.12.105

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Three dimensional analysis of nanoporous silicon particles for Li-ion batteries2016

    • Author(s)
      Roiban, Lucian; Koneti, Siddardha; Wada, Takeshi; Kato, Hidemi; et al
    • Journal Title

      MATERIALS CHARACTERIZATION

      Volume: 124 Pages: 165-170

    • DOI

      10.1016/j.matchar.2016.12.013

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Enlarging the surface area of an electrolytic capacitor of porous niobium by Mg-Ce eutectic liquid dealloying2016

    • Author(s)
      Kim, Joung Wook; Wada, Takeshi; Kim, Sung Gyoo; Kato, Hidemi
    • Journal Title

      SCRIPTA MATERIALIA

      Volume: 122 Pages: 68-71

    • DOI

      10.1016/j.scriptamat.2016.05.014

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Evolution of a bicontinuous nanostructure via a solid-state interfacial dealloying reaction2016

    • Author(s)
      Wada, Takeshi; Yubuta, Kunio ; Kato, Hidemi
    • Journal Title

      SCRIPTA MATERIALIA

      Volume: 118 Pages: 33-36

    • DOI

      10.1016/j.scriptamat.2016.03.008

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Formation of porous layer with low Ni content on NiTi substrate by dealloying in metallic melts2016

    • Author(s)
      Kyosuke UEDA, Ryuma HASHIMOTO, Masahiro HIROHASHI, Takeshi WADA, Hidemi KATO, Takayuki NARUSHIMA
    • Journal Title

      粉体および粉末冶金

      Volume: 63 Pages: 766-770

    • NAID

      130005253114

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of three-dimensional nanoporous Si using dealloying by metallic melt and application as a lithium-ion rechargeable battery negative electrode2016

    • Author(s)
      T. Wada, J. Yamada, H. Kato
    • Journal Title

      Journal of Power Sources

      Volume: 306 Pages: 8-16

    • DOI

      10.1016/j.carbon.2015.09.093

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Optimizing niobium dealloying with metallic melt to fabricate porous structure for electrolytic capacitors2015

    • Author(s)
      J. W. Kim, M. Tsuda, T. Wada, K. Yubuta, S. G. Kim, H. Kato
    • Journal Title

      Acta Materialia

      Volume: 84 Pages: 497-505

    • DOI

      10.1016/j.actamat.2014.11.002

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ひずみ解放機構を有するオープンセル型バルクナノポーラス材料のリチウム蓄電池負極特性2015

    • Author(s)
      市坪 哲、和田 武、加藤 秀実
    • Journal Title

      工業材料

      Volume: 3 Pages: 38-44

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Bulk-nanoporous-silicon negative electrode with extremely high cyclability for lithium-ion batteries prepared using a top-down process2014

    • Author(s)
      T. Wada, T. Ichitsubo, K. Yubuta, H. Segawa, H. Yoshida, H. Kato
    • Journal Title

      Nano Letters

      Volume: 14 Issue: 8 Pages: 4505-4510

    • DOI

      10.1021/nl501500g

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] リチウムイオン蓄電池負極用大比表面積オープンセル型ポーラスシリコン粉末の開発2014

    • Author(s)
      和田 武、市坪 哲、湯葢 邦夫、吉田 浩一、瀬川 春彦、加藤 秀実
    • Journal Title

      化学工業

      Volume: 65 Pages: 25-32

    • Related Report
      2014 Annual Research Report
    • Acknowledgement Compliant
  • [Presentation] Fe-Ni 単結晶前駆合金のMg 溶湯中での脱合金化反応およびポーラス構造発達過程2016

    • Author(s)
      齋藤樹里, 和田武, 湯葢邦夫, 加藤秀実
    • Organizer
      第132回 金属材料研究所 講演会
    • Place of Presentation
      東北大学 金属材料研究所
    • Year and Date
      2016-11-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属溶湯脱成分法を用いた多孔質金属の作製およびリチウム空気電池用バインダーフリー空気極への応用2016

    • Author(s)
      森下史弥, 加藤秀実, 和田武, et al.
    • Organizer
      第132回 金属材料研究所 講演会
    • Place of Presentation
      東北大学 金属材料研究所
    • Year and Date
      2016-11-24
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属溶湯中の脱成分現象を利用した金属ガラス複合材料の作製とポーラス金属への応用2016

    • Author(s)
      加藤秀実
    • Organizer
      日本材料学会金属ガラス部門委員会第39回研究会
    • Place of Presentation
      山口宇部
    • Year and Date
      2016-11-18
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Preparation of nanoporous base metals by dealloying in metallic melt and their application for energy related materials2016

    • Author(s)
      Takeshi WADA, Hidemi KATO
    • Organizer
      2016 Russia-Japan Conference "Advanced Materials: Synthesis, Processing and Properties of Nanostructure
    • Place of Presentation
      ロシア・ノヴォシビリスク
    • Year and Date
      2016-10-30
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Graphitization and Activation of Open-Cell Type Porous Carbon Prepared by Dealloying in Metallic Melt2016

    • Author(s)
      Won Young PARK, Hidemi KATO, Takeshi WADA, Seung-Geun YU
    • Organizer
      2016 Russia-Japan Conference "Advanced Materials: Synthesis, Processing and Properties of Nanostructure
    • Place of Presentation
      ロシア・ノヴォシビリスク
    • Year and Date
      2016-10-30
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of 3D Nanoporous Si by Dealloying in Metallic Melt and its Application of Lithium Ion Rechargeable Battery Negative Electrode2016

    • Author(s)
      Takeshi WADA, Hidemi KATO
    • Organizer
      The 1st International Symposium on Creation of Life Innovation Materials for Interdisciplinary and International Researcher Development (iLIM-1)
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-10-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Graphitization and Activation of Open-Cell Type Porous Carbon Prepared by Dealloying in Metallic Melt2016

    • Author(s)
      Won Young PARK, Hidemi KATO, Takeshi WADA, Seung-Geun YU
    • Organizer
      The 1st International Symposium on Creation of Life Innovation Materials for Interdisciplinary and International Researcher Development (iLIM-1)
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-10-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of Porous Metal by Dealloying in Metallic Melt and its Application to the Binder-Free Cathode for Rechargeable Li-Air Battery2016

    • Author(s)
      Fumiya MORISHITA, Hidemi KATO, Takeshi WADA, et al
    • Organizer
      The 1st International Symposium on Creation of Life Innovation Materials for Interdisciplinary and International Researcher Development (iLIM-1)
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-10-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 金属溶湯中の脱成分現象を用いた金属ガラス複合材料の作製とポーラス金属開発への展開2016

    • Author(s)
      加藤秀実, 和田武
    • Organizer
      日本材料学会第2回材料WEEK
    • Place of Presentation
      京都
    • Year and Date
      2016-10-11
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 金属溶湯脱成分法により作製したドープナノポーラスSiの形態とリチウムイオン電池性能との関係2016

    • Author(s)
      山田純平, 加藤秀実, 和田武
    • Organizer
      日本金属学会2016年秋期大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属溶湯脱成分法を用いたポーラス卑・半金属の作製とそのエネルギーデバイスへの応用2016

    • Author(s)
      加藤秀実, 和田武
    • Organizer
      日本金属学会2016年秋期大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 金属ガラスのナノスケール不均質性と機械的性質2016

    • Author(s)
      加藤秀実, 市坪哲
    • Organizer
      日本金属学会2016年秋期大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 単結晶前駆合金の金属溶湯脱合金化反応およびポーラス構造発達過程2016

    • Author(s)
      齋藤樹里, 加藤秀実, 和田武, 湯葢邦夫
    • Organizer
      日本金属学会2016年秋期大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属溶湯脱成分法を用いて作製したオープンセル型ポーラス炭素と黒鉛化および賦活処理に伴う特性変化2016

    • Author(s)
      朴元永, 兪承根, 加藤秀実, 和田武
    • Organizer
      日本金属学会2016年秋期大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-09-21
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属溶湯脱成分法により作製したドープナノポーラスSi の形態とリチウムイオン電池性能との関係2016

    • Author(s)
      山田純平, 加藤秀実, 和田武
    • Organizer
      早稲田大学ナノ・ライフ創新研究開発機構  連携協定締結記念シンポジウム
    • Place of Presentation
      東北大学 金属材料研究所
    • Year and Date
      2016-09-01
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金属溶湯脱成分法を用いたオープンセル型ポーラス金属の開発2016

    • Author(s)
      和田武, 加藤秀実
    • Organizer
      学際・国際的高度人材育成ライフイノベーションマテリアル創製共同研究プロジェクト平成28 年度キックオフ公開討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2016-07-08
    • Related Report
      2016 Annual Research Report
  • [Presentation] Preparation of nanoporous less noble metals by solid-state interfacial dealloying reaction2016

    • Author(s)
      Takeshi WADA, Kunio YUBUTA, Hidemi KATO
    • Organizer
      23rd International Symposium on Metastable, Amorphous and Nanostructured Materials (ISMANAM2016)
    • Place of Presentation
      奈良
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Microstructure characterization along the process of nanoporous metal made by alloying in metalic melt bath by Xray tomography and SEM-EBSD2016

    • Author(s)
      Morgane MOKHTARI, Hidemi KATO, Takeshi WADA, et al
    • Organizer
      23rd International Symposium on Metastable, Amorphous and Nanostructured Materials (ISMANAM2016)
    • Place of Presentation
      奈良
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Three-Dimensional bicontinuous porous carbon generated in low temperature metallic liquid2016

    • Author(s)
      Seung Geyn YU, Hidemi KATO, Takeshi WADA
    • Organizer
      23rd International Symposium on Metastable, Amorphous and Nanostructured Materials (ISMANAM2016)
    • Place of Presentation
      奈良
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reaction Design for Mg-Based Metallic Glass with In Situ Ti Dispersoids, and Its Development to Macro-Porous Base/Half Metals2016

    • Author(s)
      Hidemi KATO, Takeshi WADA
    • Organizer
      23rd International Symposium on Metastable, Amorphous and Nanostructured Materials (ISMANAM2016)
    • Place of Presentation
      奈良
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Preparation of doped-nanoporous silicon by dealloying in metallic melt and its application to the negative electrode for lithium-ion batteries2016

    • Author(s)
      Junpei YAMADA, Hidemi KATO, Takeshi WADA
    • Organizer
      Summit of Materials Science 2016(SMS2016)
    • Place of Presentation
      東北大学 金属材料研究所
    • Year and Date
      2016-05-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 金属溶湯中での脱成分現象を利用した金属ガラス複合材料の作製とポーラス材料への展開2016

    • Author(s)
      加藤 秀実、和田 武
    • Organizer
      2016 日本金属学会春期講演大会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Nanoporous Metals by Dealloying in Metallic Melt and Their Application for Energy2015

    • Author(s)
      H. Kato
    • Organizer
      ICFMFEI2015
    • Place of Presentation
      ロシア・ノヴォシビリスク
    • Year and Date
      2015-09-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 金属溶湯デアロイングにより作製したナノポーラスシリコンのリチウムイオン電池電極特性と電極体積変化の関係2015

    • Author(s)
      和田 武、山田 純平、加藤 秀実
    • Organizer
      2015 日本金属学会秋期講演大会
    • Place of Presentation
      九州大学
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Preparation of nanoporous silicon by dealloying in metallic melt and its application to the negative electrode for lithium-ion batteries2015

    • Author(s)
      T. Wada, T. Ichitsubo, K. Yubuta, H. Segawa, H. Yoshida, H. Kato
    • Organizer
      ISMANAM2015
    • Place of Presentation
      フランス・パリ
    • Year and Date
      2015-07-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 金属溶湯デアロイングによるナノポーラスシリコンの構造制御とそのリチウムイオン二次電池特性2015

    • Author(s)
      和田武、加藤秀実
    • Organizer
      日本金属学会春期講演大会2015
    • Place of Presentation
      東京大学駒場キャンパス
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属溶湯中脱成分法による三次元ナノポーラスシリコンの作製とそのリチウムイオン電池負極特性2014

    • Author(s)
      和田武、市坪哲、湯葢邦夫、瀬川春彦、吉田浩一、加藤秀実
    • Organizer
      第55回電池討論会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2014-11-19 – 2014-11-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属溶湯デアロイングによるポーラスシリコンの作製とそのリチウムイオン電池負極特性2014

    • Author(s)
      和田武、市坪哲、湯葢邦夫、瀬川春彦、吉田浩一、加藤秀実
    • Organizer
      日本金属学会2014年秋期講演大会(155回)
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属溶湯脱成分法を用いて作製した多孔質Fe-Crの多孔質構造に及ぼす添加元素の効果2014

    • Author(s)
      津田雅史、和田武、加藤秀実
    • Organizer
      日本金属学会2014年秋期講演大会(155回)
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属溶湯脱成分法を用いた3Dバルクポーラス黒鉛の作製2014

    • Author(s)
      兪承根、和田武、加藤秀実
    • Organizer
      日本金属学会2014年秋期講演大会(155回)
    • Place of Presentation
      名古屋大学東山キャンパス
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属溶湯デアロイング法によるナノポーラスシリコンの作製2013

    • Author(s)
      和田 武
    • Organizer
      日本金属学会2013年度秋期講演大会(第153回)
    • Place of Presentation
      金沢大学
    • Related Report
      2013 Annual Research Report
  • [Book] 全固体電池のイオン伝導性向上技術と材料、製造プロセスの開発 第7章1節 251貢-257貢2017

    • Author(s)
      和田武、加藤秀実、市坪哲
    • Total Pages
      475
    • Publisher
      株式会社 技術情報協会
    • Related Report
      2016 Annual Research Report
  • [Remarks] リチウムイオン蓄電池負極用大比表面積オープンセル型ポーラスシリコン粉末の開発

    • URL

      http://www.imr.tohoku.ac.jp/ja/info/results/2014.html

    • Related Report
      2014 Annual Research Report

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Published: 2013-05-15   Modified: 2022-01-28  

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