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Analysis of precise electron density of topological insulator thin films by applying direct methods to surface X-ray diffraction

Research Project

Project/Area Number 25246026
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionTokyo Gakugei University (2015)
The University of Tokyo

Principal Investigator

TAKAHASHI Toshio  東京学芸大学, 教育学部, 研究員 (20107395)

Co-Investigator(Kenkyū-buntansha) AKIMOTO Koichi  日本女子大学, 理学部, 教授 (40262852)
SHIRASAWA Tetsuroh  産業技術総合研究所, 計量標準総合センター, 主任研究員 (80451889)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥46,150,000 (Direct Cost: ¥35,500,000、Indirect Cost: ¥10,650,000)
Fiscal Year 2015: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2014: ¥15,080,000 (Direct Cost: ¥11,600,000、Indirect Cost: ¥3,480,000)
Fiscal Year 2013: ¥27,560,000 (Direct Cost: ¥21,200,000、Indirect Cost: ¥6,360,000)
Keywords表面界面構造 / X線回折 / トポロジカル絶縁体 / 位相問題 / ホログラフィ / 反復位相回復 / 電子密度分布 / 原子分解 / 表面構造
Outline of Final Research Achievements

Surface x-ray diffraction is a powerful method of studying the atomic-scale structure and morphologies of surfaces and interfaces. We have studied the structure of Cu-doped Bi2Se3 ultra-thin films and the Si(111)-5x2-Au surface. We could analyze the structures as electron density with atomic, or atomic-layer resolution, using highly developed analyzing methods such a holographic method and phase retrieval methods.
We showed Cu is intercalated into van der Waals gaps of Bi2Se3 quintuple layers, and determined the dependence of the gap distance on the concentration of Cu as well. Our resistivity measurements at low temperatures never showed superconductivity. This result, casting a question on a previous report indicating superconductivity, is getting a consensus.
We also determined the surface structure of Si(111)-5x2-Au, that has been in dispute for a long time of about a half-century.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (40 results)

All 2016 2015 2014 Other

All Journal Article (7 results) (of which Peer Reviewed: 6 results,  Open Access: 2 results,  Acknowledgement Compliant: 2 results) Presentation (32 results) (of which Int'l Joint Research: 7 results,  Invited: 11 results) Book (1 results)

  • [Journal Article] Atomic structure of “multilayer silicene” grown on Ag(111): Dynamical low energy electron diffraction analysis2016

    • Author(s)
      K. Kawahara, T. Shirasawa, C.-L. Lina, R. Nagao, N. Tsukahara, T. Takahashi, Ryuichi Arafune, M. Kawai, N. Takagi
    • Journal Title

      Surface Science

      Volume: 57 Pages: 70-75

    • DOI

      10.1016/j.susc.2016.03.029

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Recent Progress in Surface X-ray Diffraction2016

    • Author(s)
      白澤徹郎
    • Journal Title

      Journal of the Vacuum Society of Japan

      Volume: 59 Issue: 2 Pages: 26-34

    • DOI

      10.3131/jvsj2.59.26

    • NAID

      130005138322

    • ISSN
      1882-2398, 1882-4749
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Polarity Determination of GaN Thin Films by Anomalous X-Ray Diffraction2015

    • Author(s)
      秋本晃一
    • Journal Title

      Nihon Kessho Gakkaishi

      Volume: 57 Issue: 5 Pages: 263-268

    • DOI

      10.5940/jcrsj.57.263

    • NAID

      130005105680

    • ISSN
      0369-4585, 1884-5576
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Structure and transport properties of Cu doped Bi2Se3 films2014

    • Author(s)
      T. Shirasawa, M. Sugiki, T. Hirahara, M. Aitani, T. Shirai, S. Hasegawa, and T. Takahashi
    • Journal Title

      Physical Review B

      Volume: 89 Issue: 19 Pages: 195311-195311

    • DOI

      10.1103/physrevb.89.195311

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Identification of the Structure Model of the Si(111)-(5×2)-Au Surface2014

    • Author(s)
      T. Shirasawa, W. Voegeli, T. Nojima, Y. Iwasawa, Y. Yamaguchi, T. Takahashi
    • Journal Title

      Physical Review Letters

      Volume: 113 Issue: 16

    • DOI

      10.1103/physrevlett.113.165501

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] X線CTR散乱法による薄膜界面構造の直接的構造決定2014

    • Author(s)
      白澤徹郎, 高橋敏男
    • Journal Title

      日本結晶学会誌

      Volume: 56 Pages: 263-269

    • NAID

      130004688360

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ICSOS-11会議報告2014

    • Author(s)
      白澤徹郎
    • Journal Title

      Journal of Japanese Society for Synchrotron Radiation Research,

      Volume: 27 Pages: 267-268

    • Related Report
      2014 Annual Research Report
  • [Presentation] 表面X線回折によるSi(111)-√21×√21-(Ag+Au)構造2016

    • Author(s)
      高橋敏男、山口雄大、白澤徹郎、田尻寛男
    • Organizer
      第29回日本放射光学会年会
    • Place of Presentation
      柏の葉カンファレンスセンター(千葉県柏市)
    • Year and Date
      2016-01-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Polarity Determination of GaN Thin Films by Anomalous X-Ray Diffraction2015

    • Author(s)
      K. Akimoto
    • Organizer
      Joint Symposium 2015, Ewha Womans University, Japan Women’s University and Ochanomizu University for the promotion and research for women in science
    • Place of Presentation
      ソウル(韓国)
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Interface structures of tuned topological insulator films2015

    • Author(s)
      T. Shirasawa
    • Organizer
      15th International Conference on Formation of Semiconductor Interfaces
    • Place of Presentation
      Hiroshima International Conferenc Center(広島)
    • Year and Date
      2015-11-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Is the silicene a 2D Dirac material?2015

    • Author(s)
      T. Shirasawa
    • Organizer
      228th Electrochemical Society Meeting
    • Place of Presentation
      Phoenix Convention Center(米国)
    • Year and Date
      2015-10-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Si1-xGex上の歪みSi表面のLEEDによる構造解析2015

    • Author(s)
      白澤徹郎、武田さくら、高橋敏男
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Si(111)-√21×√21-(Ag+Au)構造の再考察 II2015

    • Author(s)
      高橋敏男、山口雄大、白澤徹郎、田尻寛男
    • Organizer
      日本物理学会 2015年秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] X線の遠まわり反射による格子ひずみ評価2015

    • Author(s)
      西川史恵、平井知子、秋本晃一
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学千里山キャンパス(大阪)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] A Method of X-ray Reciprocal Space Mapping for Quick Characterization of Thinfilm Structure2015

    • Author(s)
      T. Shirasawa, W. Voegeli, E. Arakawa, T. Takahashi, and T. Matsushita
    • Organizer
      SemiconNano 2015
    • Place of Presentation
      Lakeshore Hotel, Hsinchu(台湾)
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Investigation of superconductivity of CuxBi2Se3 using thinfilm samples2015

    • Author(s)
      T. Shirasawa, M. Sugiki, T. Hirahara, M. Aitani, T. Shirai, S. Hasegawa, and T. Takahashi
    • Organizer
      Synchrotron Radiation Instrumentation 2015
    • Place of Presentation
      ニューヨーク(米国)
    • Year and Date
      2015-07-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A Method of X-ray Reciprocal Space Mapping for Quick Characterization of Thinfilm Structure2015

    • Author(s)
      T. Shirasawa, W. Voegeli, E. Arakawa, T. Takahashi, and T. Matsushita
    • Organizer
      Synchrotron Radiation Instrumentation 2015
    • Place of Presentation
      ニューヨーク(米国)
    • Year and Date
      2015-07-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 表面X線回折法による表面界面構造の研究2015

    • Author(s)
      高橋敏男
    • Organizer
      日本学術振興会第161委員会第91回研究会
    • Place of Presentation
      東北大学片平キャンパス(仙台市)
    • Year and Date
      2015-05-15
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Surface X-ray diffraction as holography to solve the atomic structure of surfaces and interfaces2015

    • Author(s)
      T. Shirasawa and T. Takahashi
    • Organizer
      588. WE-Heraeus-Seminar on 'Element Specific Structure Determination in Materials on Nanometer and Sub-Nanometer'
    • Place of Presentation
      ボン(ドイツ)
    • Year and Date
      2015-04-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 界面の直接的構造解析2015

    • Author(s)
      白澤徹郎
    • Organizer
      物質構造科学研究所 談話会
    • Place of Presentation
      高エネ研つくばキャンパス(つくば市)
    • Year and Date
      2015-04-16
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 実験室X線源を用いた、時分割反射率計、回折計の開発2015

    • Author(s)
      亀沢知夏、Voegeli Wolfgang、荒川悦雄、白澤徹郎、高橋敏男、松下正、矢野陽子
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学(東京都新宿区)
    • Year and Date
      2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] X線トポグラフ法によるGaN結晶の欠陥評価2015

    • Author(s)
      井上絵美子、 野口彩純、大山美咲、渡辺玲那、秋本晃一
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学(東京都新宿区)
    • Year and Date
      2015-03-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] 表面X線回折法によるSi(111)-5x2-Au表面構造モデルの決定2015

    • Author(s)
      白澤徹郎、Voegeli Wolfgang、山口雄大、高橋敏男
    • Organizer
      日本物理学会第70回年次大会
    • Place of Presentation
      早稲田大学(東京都新宿区)
    • Year and Date
      2015-03-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] Quantitative Strain Analysis of Surfaces and Interfaces Using Extremely Asymmetric X-Ray Diffraction2014

    • Author(s)
      K. Akimoto
    • Organizer
      Joint Symposium 2014, Ewha Womans University, Japan Women’s University and Ochanomizu University for the promotion and research for women in science
    • Place of Presentation
      ソウル(韓国)
    • Year and Date
      2014-12-03
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Structural analysis of Si(111)-5x2-Au surface by surface X-ray diffraction2014

    • Author(s)
      Yudai Yamaguchi, Tetsuroh Shirasawa, Wolfgang Voegeli. Toshio Takahashi
    • Organizer
      The 7th International Symposium on Surface Science
    • Place of Presentation
      島根県立産業交流会館(島根県松江市)
    • Year and Date
      2014-11-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Structure and Transport Properties of Cu-doped Bi2Se3 Films2014

    • Author(s)
      Tetsuroh Shirasawa, Masato Sugiki, Toru Hirahara, Masaki Aitani, Terufusa Shirai, Shuji Hasegawa, and Toshio Takahashi
    • Organizer
      The 7th International Symposium on Surface Science
    • Place of Presentation
      島根県立産業交流会館(島根県松江市)
    • Year and Date
      2014-11-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] X線回折における位相問題解決―現状と展望2014

    • Author(s)
      高橋敏男
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] X線CTR散乱における直接的界面構造解析法とトポロジカル絶縁体界面への応用2014

    • Author(s)
      白澤徹郎
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] CuドープBi2Se3薄膜の構造と電子輸送特性2014

    • Author(s)
      白澤徹郎、杉木祐人、平原徹、長谷川修司、高橋敏男
    • Organizer
      日本物理学会2014年秋季大会
    • Place of Presentation
      中部大学(愛知県春日井市)
    • Year and Date
      2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Si(111)-√21×√21-(Ag+Au)構造の再考察2014

    • Author(s)
      山口雄大、白澤徹郎、田尻寛男、高橋敏男
    • Organizer
      日本物理学会2014年秋季大会
    • Place of Presentation
      中部大学(愛知県春日井市)
    • Year and Date
      2014-09-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] Time-resolved X-ray crystal truncation rod measurement in a multi-wavelength dispersive mode2014

    • Author(s)
      Tetsuroh Shirasawa, Etsuo Arakawa, Wolfgang Voegeli, Toshio Takahashi, Tadashi Matsushita
    • Organizer
      11th International Conference on the Structure of Surfaces
    • Place of Presentation
      ワーウィック(英国)
    • Year and Date
      2014-07-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] トポロジカル絶縁体の表面界面構造

    • Author(s)
      白澤 徹郎
    • Organizer
      SPring-8シンポジウム2013のサテライト研究会:表面界面・薄膜ナノ構造研究会
    • Place of Presentation
      京都大学吉田キャンパス(京都府)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 次世代光源による表面構造研究への期待

    • Author(s)
      高橋 敏男
    • Organizer
      SPring-8シンポジウム2013のサテライト研究会:表面界面・薄膜ナノ構造研究会
    • Place of Presentation
      京都大学吉田キャンパス(京都府)
    • Related Report
      2013 Annual Research Report
  • [Presentation] X線回折によるトポロジカル絶縁体Bi2Se3超薄膜構造の膜厚依存性の研究

    • Author(s)
      杉木 祐人
    • Organizer
      日本物理学会2013年秋季大会
    • Place of Presentation
      徳島大学(徳島県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] CTR散乱による界面評価と欠陥

    • Author(s)
      高橋 敏男
    • Organizer
      2013年度東北大学金属材料研究所ワークショップ:格子欠陥が挑戦する新エネルギー・環境材料開発
    • Place of Presentation
      東北大学金属材料研究所(宮城県)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Atomic level structural characterization of topological insulator films with surface x-ray diffraction

    • Author(s)
      白澤 徹郎
    • Organizer
      9th International Symposium on Atomic Level Characterizations for New Materials and Devices '13
    • Place of Presentation
      ハワイ島(アメリカ)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Atomic-layer resolved structure of ultra-thin films studied by X-ray CTR scattering

    • Author(s)
      高橋 敏男
    • Organizer
      3th International Conference on Physics at Surfaces and Interfaces
    • Place of Presentation
      プリ(インド)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Quantitative Strain Analysis of Surfaces and Interfaces Using Extremely Asymmetric X-Ray Diffraction

    • Author(s)
      K. Akimoto
    • Organizer
      3th International Conference on Physics at Surfaces and Interfaces
    • Place of Presentation
      プリ(インド)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 埋もれた界面の原子配列決定による超薄膜構造物性の研究

    • Author(s)
      白澤 徹郎
    • Organizer
      日本物理学会第69回年次大会
    • Place of Presentation
      東海大学湘南キャンパス(神奈川県)
    • Related Report
      2013 Annual Research Report
  • [Book] Reference Module in Chemistry, Molecular Sciences and Chemical Engineering2014

    • Author(s)
      T. Shirasawa, T. Takahashi
    • Total Pages
      6
    • Publisher
      Elsevier
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-15   Modified: 2019-07-29  

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