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Development of innovative technique for determining elemental and isotopic contents by using high intense pulsed neutrons and continuous neutrons

Research Project

Project/Area Number 25246038
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Quantum beam science
Research InstitutionTokyo Metropolitan University

Principal Investigator

Ebihara Mitsuru  首都大学東京, 理工学研究科, 教授 (10152000)

Co-Investigator(Kenkyū-buntansha) 藤 暢輔  国立研究開発法人日本原子力研究開発機構, 原子力科学研究部門・原子力基礎工学研究センター, 研究主幹 (60354734)
松尾 基之  東京大学, 総合文化研究科, 教授 (10167645)
三浦 勉  国立研究開発法人産業技術総合研究所, 物質計測標準研究部門, 研究グループ長 (70371078)
千葉 光一  国立研究開発法人産業技術総合研究所, 計測標準研究部, 部門長 (20281066)
Co-Investigator(Renkei-kenkyūsha) KIMURA Atsushi  日本原子力研究開発機構, 核データ研究グループ, 研究副主幹 (30360423)
KIMURA Atsushi  首都大学東京, 理工学研究科, 准教授 (90291567)
SHOZUGAWA Katsumi  東京大学, 総合文化研究科, 助教 (00507923)
MIURA Tsutomu  産業技術総合研究所, 計測標準研究部門, 研究室長 (70371078)
Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥45,500,000 (Direct Cost: ¥35,000,000、Indirect Cost: ¥10,500,000)
Fiscal Year 2016: ¥11,570,000 (Direct Cost: ¥8,900,000、Indirect Cost: ¥2,670,000)
Fiscal Year 2015: ¥11,830,000 (Direct Cost: ¥9,100,000、Indirect Cost: ¥2,730,000)
Fiscal Year 2014: ¥11,830,000 (Direct Cost: ¥9,100,000、Indirect Cost: ¥2,730,000)
Fiscal Year 2013: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
Keywords非破壊元素分析 / 即発ガンマ線分析 / 中性子共鳴捕獲分析 / TOF-PGA / J-PARC / MIF / ANNRI / 物質・生命科学実験施設 / JRR-3 / MPGA / 即発ガンマ線 / パルス中性子 / 宇宙物質 / 環境試料 / 標準物質 / 元素分析 / ANRRI
Outline of Final Research Achievements

We developed a novel non-destructive analytical technique that combines prompt gamma-ray analysis (PGA) and time-of-flight elemental analysis (TOF) by using an intense pulsed neutron beam at the Materials and Life Science Facility of Japan Proton Accelerator Research Complex. It allows us to obtain analytical results from the both methods at the same time. In addition, it can be used to quantify elemental concentrations in the sample, to which neither of these methods can be applied independently. A simple and accurate correction method for practical use was also developed for data processing in the TOF-PGA analysis. The effectiveness and the usefulness of the developed TOF-PGA method were confirmed by measuring of a composite reference sample. Moreover, its applicability was validated by analyzing of representative materials in several fields, such as cosmochemistry and environmental science.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (37 results)

All 2017 2016 2015 2014 2013

All Journal Article (15 results) (of which Peer Reviewed: 15 results,  Acknowledgement Compliant: 7 results,  Open Access: 1 results) Presentation (20 results) (of which Int'l Joint Research: 3 results,  Invited: 5 results) Book (2 results)

  • [Journal Article] Development of a correction method for the time-of-flight prompt gamma-ray analysis2017

    • Author(s)
      M. Huang, Y. Toh, M. Ebihara, A. Kimura, and S. Nakamura
    • Journal Title

      J. Appl. Phys

      Volume: 121 Issue: 10

    • DOI

      10.1063/1.4978309

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] J-PARC/ANNRIにおける即発ガンマ線分析法開発2016

    • Author(s)
      藤暢輔、海老原充、黄明輝、木村敦、中村詔司、原田秀郞
    • Journal Title

      放射化学

      Volume: 33号 Pages: 1-10

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Precise Determination of Silicon in Ceramic Reference Materials by Prompt Gamma Activation Analysis at JRR-32016

    • Author(s)
      T. Miura, H. Matsue
    • Journal Title

      Nuclear Engineering and Technology

      Volume: 48 Pages: 299-303

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 大強度パルス中性子ビームを用いた新しい非破壊分析法の開発2015

    • Author(s)
      藤暢輔、海老原充、黄明輝、木村敦、中村詔司、原田秀郞
    • Journal Title

      Isotope News

      Volume: No. 736 Pages: 22-26

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Multielemental analysis of Korean geological reference samples by INAA, ICP-AES and ICP-MS2015

    • Author(s)
      N. Shirai, M. Toktaganov, H. Takahashi, Y. Yokotsuka, S. Sekimoto and M. Ebihara
    • Journal Title

      J. Radioanal. Nucl. Chem.

      Volume: 303 Issue: 2 Pages: 1367-1374

    • DOI

      10.1007/s10967-014-3653-5

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Neutron activation analysis of iron meteorites2015

    • Author(s)
      N. Shirai, Y. Hidaka, A. Yamaguchi, S. Sekimoto, M. Ebihara and H. Kojima
    • Journal Title

      J. Radioanal. Nucl. Chem.

      Volume: 303 Pages: 1375-1380

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Accurate determination of Zn in geological and cosmochemical rock samples by isotope dilution inductively coupled plasma mass spectrometry2015

    • Author(s)
      R. Khan, Y. Yokozuka, Saki Terai, N. Shiraia and M. Ebihara
    • Journal Title

      J. Anal. At. Spectrom.

      Volume: 30 Issue: 2 Pages: 506-514

    • DOI

      10.1039/c4ja00344f

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chemical and mineralogical compositions of two grains recovered from asteroid Itokawa2015

    • Author(s)
      Ebihara, M., Shirai, N., Sekimoto, S., Nakamura, T., Tsuchiyama, A., Matsuno, J., Matsumoto, T., Tanaka, M., Abe, M., Fujimura, A., Ishibashi, Y., Karouji, Y., Mukai, T., Okada, T., Uesugi, M. and Yada, T.
    • Journal Title

      Meteoritics & Planetary Science

      Volume: 50 Issue: 2 Pages: 243-254

    • DOI

      10.1111/maps.12418

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synergistic effect of combining two non-destructive analytical methods for multi-elemental analysis2014

    • Author(s)
      Yosuke Toh, Mitsuru Ebihara, Atsushi Kimura, Shoji Nakamura, Hideo Harada, Kaoru Y. Hara, Mitsuo Koizumi, Fumito Kitatani and Kazuyoshi Furutaka
    • Journal Title

      Analytical Chemistry

      Volume: 86 Issue: 24 Pages: 12030-12036

    • DOI

      10.1021/ac502632w

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Quality Assessment of INAA Data for Small-sized Environmental Reference Samples2014

    • Author(s)
      Wanna Wilmolwattannapun, Supamatthree Bunprapob, Mang Dung Ho, Sutisna, Yasuji Oura and Mitsuru Ebihara
    • Journal Title

      Analytical Sciences

      Volume: 30 Issue: 8 Pages: 787-792

    • DOI

      10.2116/analsci.30.787

    • NAID

      130004677852

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Accurate determination of trace amounts of phosphorus in geological samples by inductively coupled plasma atomic emission spectrometry with ion-exchange separation.2013

    • Author(s)
      K. Asoh and M. Ebihara
    • Journal Title

      Anal. Chim. Acta

      Volume: 779 Pages: 8-13

    • DOI

      10.1016/j.aca.2013.04.005

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Accurate determination of chlorine, bromine, and iodine in sedimentary rock reference samples by radiochemical neutron activation analysis and a detailed comparison with ICP-MS literature data.2013

    • Author(s)
      S. Sekimoto and M. Ebihara
    • Journal Title

      Analytical Chemistry

      Volume: 85 Issue: 13 Pages: 6336-6341

    • DOI

      10.1021/ac400637d

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Non-destructive elemental analysis of large meteorite samples by prompt gamma-ray neutron activation analysis with the internal mono-standard method.2013

    • Author(s)
      Sk. Latif, Y. Oura, M. Ebihara and H. Nakahara
    • Journal Title

      Analytical and Bioanalytical Chemistry

      Volume: 405 Issue: 27 Pages: 8749-8759

    • DOI

      10.1007/s00216-013-7331-1

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Geochemistry and mineralogy of a feldspathic lunar meteorite (regolith breccia), Northwest Africa 2200.2013

    • Author(s)
      H. Nagaoka, Y. Karouji, T. Arai, M. Ebihara and N. Hasebe
    • Journal Title

      Polar Sciences

      Volume: 7 Issue: 3-4 Pages: 241-259

    • DOI

      10.1016/j.polar.2013.09.001

    • NAID

      110009647316

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Experimental evidence of fast transport of trace elements in planetary basaltic crusts by high temperature metamorphism.2013

    • Author(s)
      A. Yamaguchi, T. Mikouchi, M. Ito, N. Shirai, J. A. Barrat, S. Messenger and M. Ebihara
    • Journal Title

      Earth Planet. Sci. Lett.

      Volume: 368 Pages: 101-109

    • DOI

      10.1016/j.epsl.2013.02.036

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] ANNRI の現状と即発ガンマ線分析2017

    • Author(s)
      藤 暢輔
    • Organizer
      平成28 年度非破壊検査・可視化・分析技術研究会
    • Place of Presentation
      東京
    • Year and Date
      2017-02-15
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] J-PARC ANNRIにおける放射性核種の非破壊分析2016

    • Author(s)
      藤 暢輔、海老原 充、黄 明輝、木村 敦、中村詔司、瀬川麻里子
    • Organizer
      2016 日本放射化学会年会・第60 回放射化学討論会
    • Place of Presentation
      新潟大学
    • Year and Date
      2016-09-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] Determination of chemical composition of nickel-based super alloy by TOF-PGA technique2016

    • Author(s)
      黄 明輝、藤 暢輔、海老原 充、木村 敦、中村詔司
    • Organizer
      2016 日本放射化学会年会・第60 回放射化学討論会
    • Place of Presentation
      新潟大学
    • Year and Date
      2016-09-10
    • Related Report
      2016 Annual Research Report
  • [Presentation] Nondestructive analysis of difficult-to-measure radionuclides by TOF-PGA2016

    • Author(s)
      Yosuke Toh, Mitsuru Ebihara, Minghui Huang, Atsushi Kimura, Shoji Nakamura and Hideo Harada
    • Organizer
      9th International Conference on Nuclear and Radiochemistry (NRC-9)
    • Place of Presentation
      Helsinki(Finland)
    • Year and Date
      2016-08-29
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] J-PARC ANNRI におけるパルス中性子を用いた多重即発ガンマ線分析法の開発2016

    • Author(s)
      藤 暢輔、海老原充
    • Organizer
      第11 回先進原子力科学技術に関する連携重点研究討論会
    • Place of Presentation
      東京大学(本郷)
    • Year and Date
      2016-08-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 藤暢輔2016

    • Author(s)
      中性子放射化分析
    • Organizer
      H27年度非破壊検査・可視化・分析技術研究会
    • Place of Presentation
      都心・貸しビル
    • Year and Date
      2016-01-20
    • Related Report
      2015 Annual Research Report
  • [Presentation] 飛行時間型即発ガンマ線分析による放射性核種分析の実現可能性2015

    • Author(s)
      藤暢輔、黄明輝、海老原充、瀬川麻里子、木村敦、中村詔司
    • Organizer
      2015日本放射化学会年会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] Prompt gamma-ray analysis using pulsed neutrons at J-PARC2015

    • Author(s)
      Y. Toh, M. Ebihara, M. Huang, A. Kimura, S. Nakamura and H. Harada
    • Organizer
      International Conference on Modern Trends in Activation Analysis
    • Place of Presentation
      Delft, Netherlands
    • Year and Date
      2015-08-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Attempt of application of multiple prompt gamma-ray analysis using pulsed neutrons to geochemical samples2015

    • Author(s)
      Y. Miura, Y. Oura, M. Ebihara, Y. Toh and M. Huang
    • Organizer
      International Conference on Modern Trends in Activation Analysis
    • Place of Presentation
      Delft, Netherlands
    • Year and Date
      2015-08-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] The chemical composition of Australasian tektites collected from Dalat, Vietnam2014

    • Author(s)
      R. Akhter, N. Shirai and M. Ebihara
    • Organizer
      2014年度日本地球化学会年会
    • Place of Presentation
      富山大学
    • Year and Date
      2014-09-16 – 2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] ICP-MS法を用いた地球化学的標準試料中のZn, Cd, In, Tl, Pb, Biの定量(1)―火成岩」2014

    • Author(s)
      横塚佑太、寺井早紀、白井直樹、海老原充
    • Organizer
      2014年度日本地球化学会年会
    • Place of Presentation
      富山大学
    • Year and Date
      2014-09-16 – 2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] ICP-MS法を用いた地球化学的標準試料中のZn, Cd, In, Tl, Pb, Biの定量 (2)―堆積岩, 堆積物2014

    • Author(s)
      寺井 早紀、横塚佑太、白井直樹、海老原充
    • Organizer
      2014年度日本地球化学会年会
    • Place of Presentation
      富山大学
    • Year and Date
      2014-09-16 – 2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Multielement analysis of NIST and IAEA reference materials (NIST-1646a, NIST-1400, IAEA-450 and IAEA-395) by INAA, ICP-AES and ICP-MS2014

    • Author(s)
      カオ・ドン・ブ、スギャン・レイモンド、タン・ワン・ティエン、ホ・バン・ヤン、白井直樹、海老原充
    • Organizer
      2014年日本放射化学会年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-09-11 – 2014-09-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] J-PARC BL04 ANNRIによるTOF-MPGA法を用いた元素分析2014

    • Author(s)
      三浦勉、海老原充、藤暢輔、松尾基之、千葉光一、木村敦、大浦泰嗣、小豆川勝見
    • Organizer
      2014年日本放射化学会年会
    • Place of Presentation
      名古屋大学
    • Year and Date
      2014-09-11 – 2014-09-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Trace amounts of halogens (Cl, Br and I) in 16 U.S. Geological Survey geochemical reference materials2014

    • Author(s)
      S. Sekimoto and M. Ebihara
    • Organizer
      Goldschmidt 2014
    • Place of Presentation
      Sacramento, CA, USA
    • Year and Date
      2014-06-08 – 2014-06-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Development of Prompt Gamma-ray Analysis Using Spallogenic Neutrons at J-PARC2013

    • Author(s)
      Y. Toh, M. Ebihara and H. Harada
    • Organizer
      2013 American Nuclear Society Winter Meeting
    • Place of Presentation
      Washington, D. C., USA
    • Year and Date
      2013-11-10 – 2013-11-14
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Development of Prompt Gamma-ray Analysis Using Guided Neutrons at JRR-32013

    • Author(s)
      M. Ebihara1, M. A. Islam1, Y. Toh and H. Harada
    • Organizer
      2013 American Nuclear Society Winter Meeting
    • Place of Presentation
      Washington, D. C., USA
    • Year and Date
      2013-11-10 – 2013-11-14
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Multielement analysis of KIGAM reference samples by INAA, ICP-AES and ICP-MS2013

    • Author(s)
      N. Shirai, M. Toktaganov, H. Takahashi, Y. Yokozuka, S. Sekimoto and M. Ebihara
    • Organizer
      5th Asia-Pacific Symposium on Radiochemistry
    • Place of Presentation
      金沢市
    • Year and Date
      2013-09-22 – 2013-09-27
    • Related Report
      2013 Annual Research Report
  • [Presentation] ANNRI at J-PARC2013

    • Author(s)
      H. Harada, M. Igashira and M. Ebihara
    • Organizer
      5th Asia-Pacific Symposium on Radiochemistry
    • Place of Presentation
      金沢市
    • Year and Date
      2013-09-22 – 2013-09-27
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Neutron activation analysis of iron meteorite2013

    • Author(s)
      N. Shirai, Y. Hidaka, S. Sekimoto, M. Ebihara and H. Kojima
    • Organizer
      5th Asia-Pacific Symposium on Radiochemistry
    • Place of Presentation
      金沢市
    • Year and Date
      2013-09-22 – 2013-09-27
    • Related Report
      2013 Annual Research Report
  • [Book] 原発事故環境汚染」2014

    • Author(s)
      海老原充(分担執筆)
    • Total Pages
      310
    • Publisher
      東大出版会
    • Related Report
      2014 Annual Research Report
  • [Book] 同位体環境分析2013

    • Author(s)
      海老原充(分担執筆)
    • Total Pages
      331
    • Publisher
      丸善出版
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-15   Modified: 2018-03-22  

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