| Budget Amount *help |
¥45,370,000 (Direct Cost: ¥34,900,000、Indirect Cost: ¥10,470,000)
Fiscal Year 2017: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2016: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2015: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Fiscal Year 2014: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000)
Fiscal Year 2013: ¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
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| Outline of Final Research Achievements |
We elucidated the correlation between the nonlinear optical (NLO) and magnetic response functions, the structure and electronic states of nano-sized molecular substances having open-shell nature and created novel NLO substances by conducting research under the cooperation of the theory-synthesis-measurement fields: (1) theoretical design of various open-shell aggregates with tuning open-shell nature, asymmetric charge and spin states as control factors, and theoretical prediction of their NLO properties; (2) creation of π stacked aggregate systems composed of phenalenyl molecules; (3) measurement of two-photon absorption of diphenalenyl crystals with strong intermolecular interaction caused by open-shell nature and significant NLO. We succeeded in pioneering the field of novel NLO response functions of theoretically-driven nano-sized open-shell molecular substances by discovering the remarkable increase and controllability in their functions and confirming the theoretical prediction.
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