Constructions of multifunctional coordination compounds exhibiting light and electric field switching properties
Project/Area Number |
25248014
|
Research Category |
Grant-in-Aid for Scientific Research (A)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | University of Tsukuba |
Principal Investigator |
OSHIO Hiroki 筑波大学, 数理物質系, 教授 (60176865)
|
Project Period (FY) |
2013-04-01 – 2017-03-31
|
Project Status |
Completed (Fiscal Year 2016)
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Budget Amount *help |
¥47,450,000 (Direct Cost: ¥36,500,000、Indirect Cost: ¥10,950,000)
Fiscal Year 2016: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2015: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2014: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
Fiscal Year 2013: ¥21,970,000 (Direct Cost: ¥16,900,000、Indirect Cost: ¥5,070,000)
|
Keywords | スピン平衡 / 電子移動共役スピン転移 / 双安定性 / シアン化物イオン架橋 / 混合原子価錯体 / 磁性 / 誘電性 / 電気伝導性 / 電子移動を伴うスピン転移 |
Outline of Final Research Achievements |
In this work, coordination compounds with a lot of flexibility of spin, charge, and structure have been designed and their highly assembled coordination archtectures have been constructed by bottom-up methods. It is considered that hierarchical structures of coordination compounds will have amplified electronic properties, and can show controlable optical, magnetic, electronic properties. In this project, the following three systems were investigated. (1) spin-crossover multinuclear systems, (2) cyanide bridged mixed valence self-assembled systems, (3) hybrid-systems of cyanide-bridged multinuclear complexes and proton donors.
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Report
(5 results)
Research Products
(153 results)
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[Journal Article] X-ray Magnetic Circular Dichroism Investigation of the Electron Transfer Phenomena Responsible for Magnetic Switching in a Cyanide-Bridged [CoFe] Chain2013
Author(s)
M. L. Baker, Y. Kitagawa, T. Nakamura, K. Tazoe, Y. Narumi, Y. Kotani, F. Iijima, G. N. Newton, M. Okumura, H. Oshio, H. Noiiri
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Journal Title
Inorg. Chem.
Volume: 52
Issue: 24
Pages: 13956-13962
DOI
Related Report
Peer Reviewed
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[Presentation] Mixed-Valence Metal Complexes2016
Author(s)
大塩 寛紀
Organizer
The 15th International Conference on Molecule-based Magnets (ICMM2016)
Place of Presentation
Sendai International Center (宮城県仙台市)
Year and Date
2016-09-04
Related Report
Int'l Joint Research / Invited
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[Presentation] Switching properties of a [CoFe] chiral 1-D chain complex2013
Author(s)
Fumichika Iijima, Norihisa Hoshino, Norifumi Yoshida, Takuya Shiga, Graham N. Newton, Akiko Nakao, Youichi Murakami, Kou Tazoe, Michael Baker, Hiroyuki Nojiri, Hiroki Oshio
Organizer
4th Asian Conference on Coordination Chemistry
Place of Presentation
International Convention Center, Jeju, Korea
Year and Date
2013-11-04 – 2013-11-07
Related Report
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[Presentation] Multi-step Spin-crossover Iron [2 x 2] Grids2013
Author(s)
Takuto Matsumoto, Graham N. Newton, Takuya Shiga, Hidenobu Kamihata, Shinya Hayami, Yuta Matsui, Hiroshi Okamoto, Reiji Kumai, Youichi Murakami, Hiroki Oshio
Organizer
4th Asian Conference on Coordination Chemistry
Place of Presentation
International Convention Center, Jeju, Korea
Year and Date
2013-11-04 – 2013-11-07
Related Report
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