| Budget Amount *help |
¥47,450,000 (Direct Cost: ¥36,500,000、Indirect Cost: ¥10,950,000)
Fiscal Year 2016: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2015: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2014: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000)
Fiscal Year 2013: ¥21,970,000 (Direct Cost: ¥16,900,000、Indirect Cost: ¥5,070,000)
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| Outline of Final Research Achievements |
In this work, coordination compounds with a lot of flexibility of spin, charge, and structure have been designed and their highly assembled coordination archtectures have been constructed by bottom-up methods. It is considered that hierarchical structures of coordination compounds will have amplified electronic properties, and can show controlable optical, magnetic, electronic properties. In this project, the following three systems were investigated. (1) spin-crossover multinuclear systems, (2) cyanide bridged mixed valence self-assembled systems, (3) hybrid-systems of cyanide-bridged multinuclear complexes and proton donors.
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