| Budget Amount *help |
¥44,720,000 (Direct Cost: ¥34,400,000、Indirect Cost: ¥10,320,000)
Fiscal Year 2015: ¥11,960,000 (Direct Cost: ¥9,200,000、Indirect Cost: ¥2,760,000)
Fiscal Year 2014: ¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2013: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
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| Outline of Final Research Achievements |
“What’ll happen if the multiple metal ions are placed (or dropped) into the conjugated pi-electron pool (or sea)?”
We can expect the birth of new functional multiple metal complex whose properties are totally different from the porphyrin mono-metal because of strong electronic interactions between metal and ligand pi-electrons, could be expected if the two metal ions are wrapped in the conjugated pi-space. We have succeeded to synthesize a variety of bis-metal complexes of double N-confused hexaphyrins having rectangular shapes and investigated their basic properties in detail. As the results, we found the peculiar stable bismetal complexes having emission over 1500 nm.
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