Synthesis, Properties and Reactivity of N-confused hexaphyrin Bis-Metal Complexes
Project/Area Number |
25248039
|
Research Category |
Grant-in-Aid for Scientific Research (A)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Bio-related chemistry
|
Research Institution | Kyushu University |
Principal Investigator |
FURUTA HIROYUKI 九州大学, 工学(系)研究科(研究院), 教授 (40244157)
|
Co-Investigator(Renkei-kenkyūsha) |
TOGANOH Motoki 九州大学, 大学院工学研究院, 助教 (80372754)
|
Project Period (FY) |
2013-10-21 – 2016-03-31
|
Project Status |
Completed (Fiscal Year 2015)
|
Budget Amount *help |
¥44,720,000 (Direct Cost: ¥34,400,000、Indirect Cost: ¥10,320,000)
Fiscal Year 2015: ¥11,960,000 (Direct Cost: ¥9,200,000、Indirect Cost: ¥2,760,000)
Fiscal Year 2014: ¥17,030,000 (Direct Cost: ¥13,100,000、Indirect Cost: ¥3,930,000)
Fiscal Year 2013: ¥15,730,000 (Direct Cost: ¥12,100,000、Indirect Cost: ¥3,630,000)
|
Keywords | ポルフィリン / 金属錯体 / 複核 / 近赤外色素 / ヘキサフィリン / 複核金属錯体 / 拡張ポルフィリン / 近赤外吸収発光 / ヘリックス / 磁性 / 安定ラジカル / 近赤外 |
Outline of Final Research Achievements |
“What’ll happen if the multiple metal ions are placed (or dropped) into the conjugated pi-electron pool (or sea)?” We can expect the birth of new functional multiple metal complex whose properties are totally different from the porphyrin mono-metal because of strong electronic interactions between metal and ligand pi-electrons, could be expected if the two metal ions are wrapped in the conjugated pi-space. We have succeeded to synthesize a variety of bis-metal complexes of double N-confused hexaphyrins having rectangular shapes and investigated their basic properties in detail. As the results, we found the peculiar stable bismetal complexes having emission over 1500 nm.
|
Report
(4 results)
Research Products
(100 results)
-
-
-
-
-
[Journal Article] Macrocyclic Transformations from Norrole to Isonorrole and an N-Confused Corrole with a Fused Hexacyclic Ring System Triggered by a Pyrrole Substituent2016
Author(s)
Li, M.; Wei, P.; Ishida, M.; Li, X.; Savage, M.; Guo, R.; Ou, Z.; Yang, S.; Furuta, H.; Xie, Y.
-
Journal Title
Angew. Chem. Int. Ed.
Volume: 55
Issue: 9
Pages: 3063-3067
DOI
Related Report
Peer Reviewed / Int'l Joint Research
-
-
-
-
-
[Journal Article] Rational syntheses of helical pai-conjugated oligopyrrins with a bipyrrole linkage: geometry control of bis-copper(II) coordination2016
Author(s)
Kai Zhang, Mathew Savage, Xin Li, Yu Jiang, Masatoshi Ishida, Koki Mitsuno, Satoru Karasawa, Tatsuhisa Kato, Weihua Zhu, Sihai Yang, Hiroyuki Furuta and Yongshu Xie
-
Journal Title
Chem. Commun.
Volume: 52
Issue: 29
Pages: 5148-5151
DOI
Related Report
Peer Reviewed / Int'l Joint Research
-
-
-
[Journal Article] Stable π-Radical from a Contracted Doubly N-Confused Hexaphyrin by Bis-Palladium Metallation2015
Author(s)
Y. Hisamune, K. Nishimura, K. Isakari, M. Ishida, S. Mori, Satoru. Karasawa, T. Kato, Sangsu L., D.Kim, and H. Furuta,
-
Journal Title
Angew. Chem., Int. Ed. Engl.
Volume: 54
Issue: 25
Pages: 7323-7327
DOI
Related Report
Peer Reviewed
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-