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Structure and Function of Organic Solar Cells -Polymers with Specific Shapes and Analysis of their Hierarchical Structures-

Research Project

Project/Area Number 25248053
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Device related chemistry
Research InstitutionKyoto University

Principal Investigator

Kaji Hironori  京都大学, 化学研究所, 教授 (30263148)

Co-Investigator(Kenkyū-buntansha) SATOH Toshifumi  北海道大学, 大学院工学研究院, 教授 (80291235)
FUKUSHIMA Tatsuya  京都大学, 化学研究所, 助教 (70705392)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥47,710,000 (Direct Cost: ¥36,700,000、Indirect Cost: ¥11,010,000)
Fiscal Year 2015: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2014: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2013: ¥31,330,000 (Direct Cost: ¥24,100,000、Indirect Cost: ¥7,230,000)
Keywords有機太陽電池 / 有機デバイス / 固体NMR / 特殊形状高分子 / 階層構造解析 / 有機薄膜太陽電池
Outline of Final Research Achievements

In this study, we carried out the following fundamental researches on organic devices. Cyclic- and star-shaped polymers with short-wavelength absorptions were successfully synthesized. Power conversion efficiencies (PCEs) of organic solar cells (OSCs) using cyclic-shaped polymers were higher than those using conventional linear polymers. On the basis of solid-state NMR analysis, short-wavelength absorption type OSCs with high PCEs were successfully fabricated using a new polymer, especially without using halogenated solvents. These results will contribute greatly for the developments of environmentally-friendly tandem-type OSCs. In addition, we carried out device fabrications by a slot-die coater, whose PCEs were almost the same or slightly higher than those by the conventional spin-coating method. We also carried out studies on device degradation analysis, multiscale charge transport calculations, and organic light-emitting diodes. The progress of this study is beyond the expected.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (46 results)

All 2016 2015 2014 2013

All Journal Article (7 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results,  Open Access: 1 results,  Acknowledgement Compliant: 4 results) Presentation (37 results) (of which Int'l Joint Research: 3 results,  Invited: 15 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Highly efficient solution-processed host-free organic light-emitting diodes showing an external quantum efficiency of nearly 18% with a thermally activated delayed fluorescence emitter2016

    • Author(s)
      Yoshimasa Wada, Katsuyuki Shizu, Shosei Kubo, Tatsuya Fukushima, Takuya Miwa, Hiroyuki Tanaka, Chihaya Adachi and Hironori Kaji
    • Journal Title

      Applied Physics Express

      Volume: 9 Issue: 3 Pages: 0321021-3

    • DOI

      10.7567/apex.9.032102

    • NAID

      210000137814

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Donor-Acceptor Poly(3-hexylthiophene)-block-Pendent Poly(isoindigo) with Dual Roles of Charge Transporting and Storage Layer for High-Performance Transistor-Type Memory Applications2016

    • Author(s)
      Jau-Tzeng Wang, Shoichi Takashima, Hung-Chin Wu, Yu-Cheng Chiu, Yougen Chen, Takuya Isono, Toyoji Kakuchi, Toshifumi Satoh and Wen-Chang Chen
    • Journal Title

      Advanced Functional Materials

      Volume: 26 Issue: 16 Pages: 1-11

    • DOI

      10.1002/adfm.201504957

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Multiscale simulation of charge transport in a host material, N,N0-dicarbazole-3,5-benzene (mCP), for organic light-emitting diodes2015

    • Author(s)
      Furitsu Suzuki, Katsuyuki Shizu, Hisafumi Kawaguchi, Shinya Furukawa, Tohru Sato, Kazuyoshi Tanaka, Hironori Kaji
    • Journal Title

      J. Mater. Chem. C

      Volume: 3 Issue: 21 Pages: 5549-5555

    • DOI

      10.1039/c5tc00543d

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Purely organic electroluminescent material realizing 100% conversion from electricity to light2015

    • Author(s)
      Hironori Kaji, Hajime Suzuki, Tatsuya Fukushima, Katsuyuki Shizu, Katsuaki Suzuki, Shosei Kubo, Takeshi Komino, Hajime Oiwa, Furitsu Suzuki, Atsushi Wakamiya, Yasujiro Murata, and Chihaya Adachi
    • Journal Title

      Nature Communications

      Volume: 6 Issue: 1 Pages: 84761-8

    • DOI

      10.1038/ncomms9476

    • NAID

      120005663313

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Highly Efficient Electroluminescence from a Solution-Processable Thermally Activated Delayed Fluorescence Emitter2015

    • Author(s)
      Yoshimasa Wada, Katsuyuki Shizu, Shosei Kubo, Katsuaki Suzuki, Hiroyuki Tanaka, Chihaya Adachi and Hironori Kaji
    • Journal Title

      Applied Physics Letters

      Volume: 107 Issue: 18 Pages: 1833031-4

    • DOI

      10.1063/1.4935237

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Triarylboron-based Fluorescent Organic Light-emitting Diodes with External Quantum Efficiencies Exceeding 20%2015

    • Author(s)
      Katsuaki Suzuki, Shosei Kubo, Katsuyuki Shizu, Tatsuya Fukushima, Atsushi Wakamiya, Yasujiro Murata, Chihaya Adachi, Hironori Kaji
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 54 Issue: 50 Pages: 15231-15235

    • DOI

      10.1002/anie.201508270

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Rod-Coil Type Miktoarm Star Copolymers Consisting of Polyfluorene and Polylactide: Precise Synthesis and Structure-Morphology Relationship2015

    • Author(s)
      Kengo Saito, Takuya Isono, Han-Sheng Sun, Toyoji Kakuchi, Wen-Chang Chen and Toshifumi Satoh
    • Journal Title

      Polymer Chemistry

      Volume: 6 Issue: 39 Pages: 6959-6972

    • DOI

      10.1039/c5py01031d

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 炭素・水素・窒素のみからなる新規緑色発光材料を用いた外部量子効率40%を超える有機ELデバイス2016

    • Author(s)
      福島達也・志津功將・鈴木克明・久保勝誠・鈴木不律・小簑 剛・安達千波矢・梶弘典
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 三配位ホウ素骨格に基づいた熱活性化遅延蛍光材料の開発2016

    • Author(s)
      鈴木克明・久保勝誠・志津功將・福島 達也・若宮淳志・村田靖次郎・安達千波矢・梶弘典
    • Organizer
      第63回応用物理学会春季学術講演会
    • Place of Presentation
      東京工業大学(東京)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Refractive Index Control of Glass Substrate for Enhanced Light Out-coupling of Organic Light-Emitting Diodes2016

    • Author(s)
      Shosei Kubo, Katsuaki Suzuki, Tatsuya Fukushima, Hironori Kaji
    • Organizer
      Institute for Chemical Research International Symposium 2016
    • Place of Presentation
      京都大学 化学研究所(京都)
    • Year and Date
      2016-03-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Triarylboron-based Fluorescent Organic Light-emitting Diodes with External Quantum Efficiencies Exceeding 20%2016

    • Author(s)
      Katsuaki Suzuki, Shosei Kubo, Katsuyuki Shizu, Tatsuya Fukushima, Atsushi Wakamiya, Yasujiro Murata, Chihaya Adachi, Hironori Kaji
    • Organizer
      Institute for Chemical Research International Symposium 2016
    • Place of Presentation
      京都大学 化学研究所(京都)
    • Year and Date
      2016-03-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Organic light-emitting diodes and organic solar cells: NMR analysis toward higher performance2015

    • Author(s)
      Hironori Kaji, Tatsuya Fukushima, Katsuaki Suzuki, Katsuyuki Shizu
    • Organizer
      International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Hawai(米国)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Organic light-emitting diodes exploiting thermally activated delayed fluorescence: Development of a new emitter material and the analysis2015

    • Author(s)
      Hironori Kaji, Hajime Suzuki, Tatsuya Fukushima, Katsuyuki Shizu, Katsuaki Suzuki, Shosei Kubo, Takeshi Komino, Hajime Oiwa, Furitsu Suzuki, Atsushi Wakamiya, Yasujiro Murata, Chihaya Adachi
    • Organizer
      International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Hawai(米国)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] Enhancement of light out-coupling efficiency for organic light-emitting diodes2015

    • Author(s)
      Shosei Kubo, Katsuaki Suzuki, Tatsuya Fukushima, Hironori Kaji
    • Organizer
      International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Hawai(米国)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] 逆項間交差を利用した新規高効率緑色,青色,および塗布型有機EL材料の設計と素子化2015

    • Author(s)
      梶弘典・志津功將・福島達也・鈴木克明・和田啓幹・久保勝誠・鈴木不律・小簑剛・安達千波矢
    • Organizer
      有機EL討論会 第21回例会
    • Place of Presentation
      九州大学(福岡)
    • Year and Date
      2015-11-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] NMR CASTEPによる有機デバイス材料の構造解析・精密化2015

    • Author(s)
      梶 弘典
    • Organizer
      MS FGM Materials Studio フォーカスグループミーティング
    • Place of Presentation
      東京コンファレンスセンター・品川(東京)
    • Year and Date
      2015-11-10
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 有機デバイス:有機ELにおける電荷輸送シミュレーションを中心に2015

    • Author(s)
      梶 弘典
    • Organizer
      九州大学大学院 博士課程教育リーディングプログラム 第81回 分子システム デバイスセミナー
    • Place of Presentation
      九州大学(福岡)
    • Year and Date
      2015-10-23
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 有機ELおよび有機太陽電池の創製と解析:計算、合成、固体NMR解析2015

    • Author(s)
      梶 弘典
    • Organizer
      高分子同友会
    • Place of Presentation
      薬業年金会館(大阪)
    • Year and Date
      2015-10-20
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 大環状ポリ(3-ヘキシルチオフェン)の合成と特性評価2015

    • Author(s)
      蓬田昌伸・高島象一・磯野拓也・田島健次・梶弘典・佐藤敏文
    • Organizer
      第5回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船橋(千葉)
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 触媒移動型縮合重合を介したポリ (3-ヘキシルチオフェン) の定量的末端官能基化2015

    • Author(s)
      高島象一・中村亮介・蓬田昌伸・磯野拓也・田島健次・梶弘典・佐藤敏文
    • Organizer
      第5回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船橋(千葉)
    • Year and Date
      2015-10-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] スリットコート法を用いた有機薄膜太陽電池の塗布プロセス検討と特性評価2015

    • Author(s)
      福島達也・黒田梨紗子・梶弘典
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学(宮城)
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] 有機ELにおける電荷輸送解析:多階層シミュレーションによる取り組み2015

    • Author(s)
      梶 弘典・鈴木 不律・志津 功將・ 川口久文・古川晋也 ・佐藤徹・田中一義
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学(宮城)
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] ポリフルオレンを一成分とするミクトアームスターポリマーの精密合成とミクロ相分離2015

    • Author(s)
      磯野拓也、Wen-Chang Chen、佐藤敏文
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学 川内キャンパス (宮城)
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis of highly pure ethynyl end-functionalized poly(3-hexylthiophene) via Kumada catalyst transfer polycondensation2015

    • Author(s)
      Shoichi Takashima, Ryosuke Nakanura, Masanobu Yomogida, Takuya Isono, Kenji Tajima, Hironori Kaji, and Toshifumi Satoh
    • Organizer
      Japan Taiwan Bilateral Polymer Symposium
    • Place of Presentation
      Hokkaido University (Hokkaido)
    • Year and Date
      2015-09-03
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ポリ (3-ヘキシルチオフェン) (P3HT) の定量的末端エチニル化2015

    • Author(s)
      高島 象一、中村 亮介、蓬田 昌伸、磯野 拓也、田島 健次、梶 弘典、佐藤 敏文
    • Organizer
      2015年度 北海道高分子若手研究会
    • Place of Presentation
      定山渓グランドホテル瑞苑(北海道)
    • Year and Date
      2015-08-28
    • Related Report
      2015 Annual Research Report
  • [Presentation] Organic light-emitting diodes: multiscale charge transport simulation and fabrication of new thermally activated delayed fluorescence (TADF) materials2015

    • Author(s)
      Hironori Kaji, Katsuyuki Shizu, Furitsu Suzuki, Tatsuya Fukushima, Katsuaki Suzuki, Chihaya Adachi
    • Organizer
      SPIE
    • Place of Presentation
      San Diego(米国)
    • Year and Date
      2015-08-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 有機デバイスの本質的理解を目指して:計算および解析の観点から2015

    • Author(s)
      梶 弘典、志津功將、鈴木不律
    • Organizer
      日本化薬講演会
    • Place of Presentation
      日本化薬株式会社(東京)
    • Year and Date
      2015-07-21
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 有機EL・有機太陽電池 特性向上と基礎的知見の構築を目指して2015

    • Author(s)
      梶弘典
    • Organizer
      Ambitious 物質科学セミナー
    • Place of Presentation
      北海道大学(北海道)
    • Year and Date
      2015-01-29
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ロジウム触媒を用いた末端エチニル化ポリ(3-ヘキシルチオフェン)のグラフト重合2015

    • Author(s)
      高島象一・中村亮介・磯野拓也・田島健次・佐藤敏文
    • Organizer
      2014年度高分子学会北海道支部研究発表会
    • Place of Presentation
      北海道大学学術交流会館(北海道)
    • Year and Date
      2015-01-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 分子内薗頭反応による大環状ポリ(3-ヘキシルチオフェン)の合成2015

    • Author(s)
      蓬田昌伸・中村亮介・磯野拓也・田島健次・梶弘典・佐藤敏文
    • Organizer
      2014年度高分子学会北海道支部研究発表会
    • Place of Presentation
      北海道大学学術交流会館(北海道)
    • Year and Date
      2015-01-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Precise synthesis of cyclic- and star-shaped poly(3-hexylthiophene)s2014

    • Author(s)
      Ryosuke Nakamura, Daichi Suemasa, Takuya Isono, Kenji Tajima, Hironori Kaji, and Toshifumi Satoh
    • Organizer
      The 1st Innovation Forum of Engineering Education (SPACC)
    • Place of Presentation
      Kogakuin University (Tokyo)
    • Year and Date
      2014-10-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] NMR of Organic Semiconductors2014

    • Author(s)
      Hironori Kaji
    • Organizer
      ICRIS-NMR '14: Technological Frontiers in Solid-State NMR -A French-Japanese Workshop-
    • Place of Presentation
      Institute for Chemical Research (Kyoto)
    • Year and Date
      2014-10-04 – 2014-10-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 触媒移動型連鎖重縮合による末端エチニル化ポリチオフェンの精密合成2014

    • Author(s)
      蓬田昌伸・末政大地・中村亮介・磯野拓也・田島健次・梶弘典・佐藤敏文
    • Organizer
      2014年度北海道高分子若手研究会
    • Place of Presentation
      定山渓ビューホテル(北海道)
    • Year and Date
      2014-08-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Solid-State NMR Studies on Aggregated Structures in Organic Devices2014

    • Author(s)
      Tatsuya Fukushima, Hironori Kaji
    • Organizer
      TADF International Workshop
    • Place of Presentation
      アクロス福岡 (福岡)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 大環状ポリ(3-ヘキシルチオフェン)の精密合成2014

    • Author(s)
      末政大地・齋藤憲吾・中村亮介・田島健次・梶弘典・佐藤敏文
    • Organizer
      化学系学協会北海道支部 2014年 冬季研究発表会
    • Place of Presentation
      北海道大学学術交流会館 (北海道)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis and characteristics of cyclic- and star-shaped poly(3-hexylthiophene)2014

    • Author(s)
      Toshifumi Satoh, Daichi Suemasa, Ryosuke Nakamura, Hirotaka Ishibashi, Tatsuya Fukushima, Hironori Kaji
    • Organizer
      Institute for Chemical Research International Symposium 2014
    • Place of Presentation
      京都大学化学研究所 (京都)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Solid-state NMR and GIPAW Approach for Organic LEDs and Organic Solar Cells2013

    • Author(s)
      Hironori KAJI, Tatsuya FUKUSHIMA, Masashi Fukuchi, and Furitsu Suzuki
    • Organizer
      2013 Spring National ACS meeting
    • Place of Presentation
      New Orleans (米国)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 有機EL、有機太陽電池の創製と解析2013

    • Author(s)
      梶 弘典
    • Organizer
      電子情報通信学会 OME・SDM(シリコン材料・デバイス/有機エレクトロニクス)研究会
    • Place of Presentation
      屋久島環境文化村センター (鹿児島)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] NMRおよびGIPAW計算を用いた有機EL、有機太陽電池の解析2013

    • Author(s)
      梶 弘典
    • Organizer
      第52回NMR討論会 チュートリアルコース
    • Place of Presentation
      石川県立音楽堂 (金沢)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Solid-State NMR Analysis of Organic LEDs and Organic Solar Cells2013

    • Author(s)
      Hironori KAJI
    • Organizer
      Swiss-Kyoto Symposium 2013
    • Place of Presentation
      ZURICH (Switzerland)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Solid-State NMR Analysis of Organic LEDs and Organic Solar Cells2013

    • Author(s)
      Hironori KAJI
    • Organizer
      ESPCI-KiPS 2013 Meeting
    • Place of Presentation
      ESPCI, Paris (France)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Solid-state NMR Analysis of Donor/Acceptor Structures in Organic Solar Cells2013

    • Author(s)
      Tatsuya Fukushima, Subaru Fujimura, Hironori Kaji
    • Organizer
      The 11th China-Japan Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena
    • Place of Presentation
      Changchun (China)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 有機太陽電池におけるポリチオフェン/フラーレン混合膜の固体 NMR 解析2013

    • Author(s)
      福島達也・藤村昴・梶弘典
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学 (金沢)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 末端エチニル化ポリ(3-ヘキシルチオフェン)の精密合成2013

    • Author(s)
      齋藤憲吾・末政大地・中村亮介・田島健次・佐藤敏文
    • Organizer
      2013年度北海道高分子若手研究会
    • Place of Presentation
      札幌市アイヌ文化交流センター (北海道)
    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] 半導体材料、有機太陽電池、環状共役高分子化合物およびその製造方法2014

    • Inventor(s)
      梶弘典、石橋寛隆、福島達也、佐藤敏文
    • Industrial Property Rights Holder
      梶弘典、石橋寛隆、福島達也、佐藤敏文
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-109558
    • Filing Date
      2014-05-27
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 組成物およびそれを用いた有機半導体素子2014

    • Inventor(s)
      梶弘典、石橋寛隆、福島達也、吉村研、上谷保則
    • Industrial Property Rights Holder
      住友化学株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-254823
    • Filing Date
      2014-12-17
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-15   Modified: 2019-07-29  

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