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Synthesis of homogeneous carbon-onion and application to friction control

Research Project

Project/Area Number 25249010
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Design engineering/Machine functional elements/Tribology
Research InstitutionThe University of Tokyo

Principal Investigator

Kato Takahisa  東京大学, 工学(系)研究科(研究院), 教授 (60152716)

Co-Investigator(Kenkyū-buntansha) CHOI JUNHO  東京大学, 大学院工学系研究科, 准教授 (30392632)
KAWGUCHI MASAHIRO  地方独立行政法人東京都立産業技術研究センター, 主任研究員 (40463054)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥45,500,000 (Direct Cost: ¥35,000,000、Indirect Cost: ¥10,500,000)
Fiscal Year 2015: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2014: ¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2013: ¥21,970,000 (Direct Cost: ¥16,900,000、Indirect Cost: ¥5,070,000)
Keywordsカーボンオニオン / 摩擦制御 / 熱処理 / CNPクラスタ / 水素雰囲気 / イオン注入 / 摩擦特性 / CNP成長 / 超潤滑 / トライボロジー / カーボンンナノパーティクル / 表面力
Outline of Final Research Achievements

Purpose of this project is to produce high density carbon onion films by optimizing the formation process of silver film, injecting process of carbon ions and thermal process. In particular, effects of parameters of injection process are investigated and injection mechanism of carbon ions are clarified. It was found that the carbon onion particles grow to 20 nm in diameter, but do not grow any more, namely homogeneous size of carbon onion particles are produced in large numbers, and that the density of particles can be changed by controlling the thermal process and temperature. It was also found the final thermal process can evaporate the silver atoms and the film made of only carbon particles can be produced. It was shown that the CNP film exhibits superlubricity, i.e. friction coefficient smaller than 0.01, under the hydrogen gas conditions.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (27 results)

All 2015 2014 2013 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 1 results) Presentation (18 results) (of which Int'l Joint Research: 3 results,  Invited: 1 results)

  • [Journal Article] DLC coating on a trench-shaped target by bipolar PBII2015

    • Author(s)
      Y. Hirata, T. Kato, J. Choi
    • Journal Title

      International Journal of Refractory Metals and Hard Materials

      Volume: 49 Pages: 392-399

    • DOI

      10.1016/j.ijrmhm.2014.08.005

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Friction fade out at polymer-like carbon films slid by ZrO2 pins under hydrogen environment2015

    • Author(s)
      M Nosaka, A. Mifune, M. Kawaguchi, T Shiiba, T Kato
    • Journal Title

      Proc IMechE part J, J. Engineering Tribology

      Volume: On line J Issue: 8 Pages: 1-9

    • DOI

      10.1177/1350650115569857

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and characterization of carbon nanoparticle films prepared by plasma-based ion implantation2014

    • Author(s)
      Shu Sawai, Yuya Nakahara, Naohiro Matsumoto, Junho Choi, Takahisa Kato, Masahiro Kawaguchi
    • Journal Title

      Surface and Interface Analysis

      Volume: (印刷中) Issue: 10-11 Pages: 961-965

    • DOI

      10.1002/sia.5457

    • Related Report
      2014 Annual Research Report 2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evolution of transfer layers on steel balls sliding against hydrogenated amorphous carbon coatings in ambient air2014

    • Author(s)
      J Xu, M Kawaguchi and T Kato
    • Journal Title

      Trib. Intl.

      Volume: 70 Pages: 42-51

    • DOI

      10.1016/j.triboint.2013.09.007

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Origin of superlubricity in a-C:H:Si films: a relation to film bonding structure and environmental molecular characteristic2014

    • Author(s)
      X. Chen, T. Kato and M. Nosaka
    • Journal Title

      ACS Appl. Mat. & Interf,

      Volume: 27 Issue: 16 Pages: 13389-13405

    • DOI

      10.1021/am502416w

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural and environmental dependence of superlow friction in ion vapour-depositeda-C:H:Si films for solid lubrication application2013

    • Author(s)
      X. Chen, T. Kato, M. Kawaguchi, M. Nosaka and J. Choi
    • Journal Title

      J. Phys. D: appli.Phys

      Volume: 46 Pages: 1-11

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical properties and thermal stability of SiBCN films prepared by ion beam assisted sputter deposition2013

    • Author(s)
      J Choi, N Hayashi, T Kato, M Kawaguchi
    • Journal Title

      Diamond and Related Materials

      Volume: 34 Pages: 95-99

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ラマン分光法によるDLC膜の機械特性評価および予測(第1報)―トルエン原料ガスを用いたバイポーラPBII&D法により作成したDLC膜―2013

    • Author(s)
      崔埈豪, 石井啓資, 加藤孝久, 川口雅弘
    • Journal Title

      トライボロジスト

      Volume: 58 Pages: 596-602

    • NAID

      10031189151

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] バイポーラPBII法によるトレンチ形状物へのDLC成膜2013

    • Author(s)
      平田祐樹, 朴元淳, 崔埈豪, 加藤孝久
    • Journal Title

      トライボロジスト

      Volume: 58 Pages: 841-847

    • NAID

      130006732295

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 263.The Effect of Tribo Film Formed on ZrO2 Pins on Friction Fade-out When Slid Against Polymer-like Carbon Films under Hydrogen Environment2015

    • Author(s)
      Takahisa Kato, Masataka Nosaka, Mamoru Tohyama, Masahiro Suzuki
    • Organizer
      ITC2015, Tokyo
    • Place of Presentation
      東京理科大学葛飾キャンパス(東京都葛飾区)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 264.Friction Fade-Out of DLC Composite Films at Heavier Loads under Various Hydrogen Environments2015

    • Author(s)
      Ryota Kusaba, Yushi Morisaki, Masataka Nosaka, Takahisa Kato, Masahiro Kawaguchi
    • Organizer
      ITC2015, Tokyo
    • Place of Presentation
      東京理科大学葛飾キャンパス(東京都葛飾区)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 265.Relationship between Surface Force and Friction of Carbon Materials2015

    • Author(s)
      Hhirokazu Arai, Tomoyuki Inoue, Takahisa Kato
    • Organizer
      ITC2015, Tokyo
    • Place of Presentation
      東京理科大学葛飾キャンパス(東京都葛飾区)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 潤滑環境下における炭素膜の摩擦摩耗特性2015

    • Author(s)
      鈴木 雅裕, 新井 大和, 野坂 正隆, 加藤 孝久
    • Organizer
      日本トライボロジー学会トライボロジー会議、姫路
    • Place of Presentation
      姫路商工会議所(兵庫県姫路市)
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高荷重下におけるDLC複合膜の摩擦フェ イドアウトの安定的発現2015

    • Author(s)
      森崎優志, 野坂正隆, 加藤孝久, 川口雅弘
    • Organizer
      日本トライボロジー学会トライボロジー会議、姫路
    • Place of Presentation
      姫路商工会議所(兵庫県姫路市)
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 表面粗さが凝着力分布に及ぼす影響に関する研究2015

    • Author(s)
      井上 知之, 谷 直亮, 加藤 孝久
    • Organizer
      日本トライボロジー学会トライボロジー会議、姫路
    • Place of Presentation
      姫路商工会議所(兵庫県姫路市)
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 薄膜の表面力と摩擦特性の関係2014

    • Author(s)
      鈴木雅裕,新井大和,井上知之,加藤孝久
    • Organizer
      日本トライボロジー学会トライボロジー会議、盛岡
    • Place of Presentation
      国立オリンピック記念青少年総合センター(東京都渋谷区)
    • Year and Date
      2014-11-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] カーボンナノ粒子添加による銀薄膜のトライボロジー特性2014

    • Author(s)
      柳本史教,中原優也,澤井周,崔埈豪,加藤孝久
    • Organizer
      日本トライボロジー学会トライボロジー会議, 東京
    • Place of Presentation
      国立オリンピック記念青少年総合センター(東京都渋谷区)
    • Year and Date
      2014-05-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水素雰囲気下での各種摩擦材料に対するPLC膜の摩擦フリー特性2014

    • Author(s)
      御舩聡,野坂正隆,加藤孝久,川口雅弘
    • Organizer
      日本トライボロジー学会トライボロジー会議、東京
    • Place of Presentation
      国立オリンピック記念青少年総合センター(東京都渋谷区)
    • Year and Date
      2014-05-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] バイポーラPBII法によるマイクロ・ナノスケールトレンチパターンへの三次元DLCコーティング2013

    • Author(s)
      崔埈豪,時岡秀行,朴元淳,平田祐樹,加藤孝久
    • Organizer
      日本トライボロジー学会トライボロジー会議・東京
    • Place of Presentation
      国立オリンピック記念青少年総合センター、東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] カーボンナノ粒子・DLC複合膜のトライボロジー特性評価2013

    • Author(s)
      中原優也,澤井周,加藤孝久
    • Organizer
      日本トライボロジー学会トライボロジー会議・福岡
    • Place of Presentation
      アクロス福岡、福岡
    • Related Report
      2013 Annual Research Report
  • [Presentation] バイポーラPBII法で合成したカーボンナノ粒子の構造の検証2013

    • Author(s)
      澤井周,中原優也,崔埈豪,加藤孝久
    • Organizer
      日本トライボロジー学会トライボロジー会議・福岡
    • Place of Presentation
      アクロス福岡、福岡
    • Related Report
      2013 Annual Research Report
  • [Presentation] プラズマイオン注入法によるナノカーボン粒子膜の形成とトライボロジー特性評価

    • Author(s)
      澤井周,中原優也,松本直浩,崔埈豪,加藤孝久
    • Organizer
      日本トライボロジー学会トライボロジー会議・東京
    • Place of Presentation
      国立オリンピック記念青少年総合センター、東京
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis of nano carbon onion thin film by plasma-based ion implantation method and its tribological properties

    • Author(s)
      Shu Sawai,Yuya Nakahara, Naohiro Matsumoto, Junho Choi, Takahisa Kato
    • Organizer
      5th World Tribology Conference
    • Place of Presentation
      Turin, Italy
    • Related Report
      2013 Annual Research Report
  • [Presentation] Synthesis and Characterization of High-Density Nano Carbon Particle Film by Plasma-Based Ion Implantation Method

    • Author(s)
      Shu Sawai,Yuya Nakahara, Naohiro Matsumoto, Junho Choi, Takahisa Kato
    • Organizer
      15th European Conference on Applications of Surface and Interface Analysis 2013.10.14
    • Place of Presentation
      Cagliari, Italy
    • Related Report
      2013 Annual Research Report
  • [Presentation] プラズマ利用イオン注入法を用いたカーボンナノ粒子膜の合成およびその摩擦・摩耗特性

    • Author(s)
      澤井周,中原優也,崔埈豪,加藤孝久
    • Organizer
      第5回マイクロ・ナノ工学シンポジウム
    • Place of Presentation
      仙台国際センター, 宮城
    • Related Report
      2013 Annual Research Report
  • [Presentation] 銀薄膜構造の変化によるカーボンオニオン膜合成への影響

    • Author(s)
      中原優也,澤井周,崔埈豪,加藤孝久
    • Organizer
      第5回マイクロ・ナノ工学シンポジウム
    • Place of Presentation
      仙台国際センター, 宮城
    • Related Report
      2013 Annual Research Report
  • [Presentation] カーボンナノクラスタの合成,応用およびシミュレーションによる構造分析

    • Author(s)
      澤井周
    • Organizer
      分子シミュレーションのトライボロジーへの応用研究会第16回研究会
    • Place of Presentation
      東京海洋大学越中島キャンパス、東京
    • Related Report
      2013 Annual Research Report
    • Invited

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Published: 2013-05-15   Modified: 2019-07-29  

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