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Selective production of resin material monomers from lignocellulosic biomass via thermochemical conversion

Research Project

Project/Area Number 25249109
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Reaction engineering/Process system
Research InstitutionKyoto University

Principal Investigator

Mae Kazuhiro  京都大学, 工学(系)研究科(研究院), 教授 (70192325)

Co-Investigator(Kenkyū-buntansha) HASEGAWA ISAO  京都大学, 工学研究科, 助教 (20346092)
MURANAKA YOSUKE  京都大学, 工学研究科, 助教 (40756243)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥44,460,000 (Direct Cost: ¥34,200,000、Indirect Cost: ¥10,260,000)
Fiscal Year 2015: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
Fiscal Year 2014: ¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
Fiscal Year 2013: ¥21,060,000 (Direct Cost: ¥16,200,000、Indirect Cost: ¥4,860,000)
Keywords木質バイオマス / バイオマスリファイナリー / 熱化学変換 / 樹脂製造 / バイオマス / ヒドロキシメチルフルフラール / 糖 / 固体酸触媒 / セルロース / 糖化 / HMF
Outline of Final Research Achievements

Xylan was selectively converted into furfural at the yield of 38.3% at 150℃ using 2-sec butylphenol as an extraction agent. Cedar was treated with 25vol% formic acid at 150℃, which resulted in saccharide yield of 46.4%. Then, saccharide was converted into HMF at the yield of 53.2 mol% using prepared reusable solid acid catalyst with an extraction agent. Furthermore, lignin-rich residue via formic acidic saccharification was treated with 30wt% acetone at 295℃, which resulted in 0.8 g/g-lignin yield of high functional lignin resin material.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (9 results)

All 2015 2014 2013 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (6 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Production of depolymerized lignin resin material from lignocellulosic biomass using acetone-water binary solution2015

    • Author(s)
      Yosuke Muranaka, Ryuichi Murata, Isao Hasegawa, Kazuhiro Mae
    • Journal Title

      Chemical Engineering Journal

      Volume: 274 Pages: 265-273

    • DOI

      10.1016/j.cej.2015.04.009

    • NAID

      120005890308

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effective Production of Levulinic Acid from Biomass through Pretreatment Using Phosphoric Acid, Hydrochloric Acid, or Ionic Liquid2014

    • Author(s)
      Y. Muranaka, T. Suzuki, H. Sawanishi, I. Hasegawa, K. Mae
    • Journal Title

      Indusrtial & Engineering Chemistry Research

      Volume: 53 Issue: 29 Pages: 1161111621-1161111621

    • DOI

      10.1021/ie501811x

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Production of Valuable Chemicals from Biomass by Two-step Conversion Combining Pre-oxidation and Hydrothermal Degradation2013

    • Author(s)
      Y. Muranaka, A. Iwai, I. Hasegawa, K. Mae
    • Journal Title

      Chemical Engineering Journal

      Volume: 234 Pages: 189-194

    • DOI

      10.1016/j.cej.2013.08.055

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Production of lignin resin material from lignocellulosic biomass combining acidic saccharification and acetone treatment2015

    • Author(s)
      Yosuke Muranaka, Junji Hosokawa, Junya Ikuta, Ryuichi Murata, Isao Hasegawa, Kazuhiro Mae
    • Organizer
      APCChE 2015 Congress
    • Place of Presentation
      Melbourne, オーストラリア
    • Year and Date
      2015-09-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体酸触媒を利用した糖類からのレブリン酸メチルの合成2015

    • Author(s)
      村中陽介、信太祐介、長谷川功、牧泰輔、前一廣
    • Organizer
      化学工学会 第47回秋季大会
    • Place of Presentation
      札幌
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] アルカリ条件下におけるバイオマスからの有機酸生成2015

    • Author(s)
      村中陽介、藤井裕大、長谷川功、前 一廣
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工大、東京
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] Catalytic conversion of saccharide into 5-hydroxymethylfurfural using cation exchanged resin2014

    • Author(s)
      Y. Muranaka, Y. Kubota, Y. Nobuta, I. Hasegawa and K. Mae
    • Organizer
      248th American Chemical Society National Meeting & Exposition
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2014-08-10 – 2014-08-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effective Acidic Hydrothermal Degradation of Cellulose to Levulinic Acid through Pretreatment2014

    • Author(s)
      Y. Muranaka, T. Suzuki, I. Hasegawa and K. Mae
    • Organizer
      2014 AIChE Spring Meeting and 10th Global Congress on Process Safety
    • Place of Presentation
      New Orleans, USA
    • Year and Date
      2014-04-01 – 2014-04-03
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属担持イオン交換樹脂を触媒とした糖類からのHMF製造

    • Author(s)
      窪田圭剛、信太佑介、村中陽介、長谷川功、前一廣
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-15   Modified: 2019-07-29  

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