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Development of nuclide confinement cement barrier undergoing a self-repair function under a condition saturated with groundwater

Research Project

Project/Area Number 25249136
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nuclear engineering
Research InstitutionTohoku University

Principal Investigator

Niibori Yuichi  東北大学, 工学研究科, 教授 (90180562)

Co-Investigator(Kenkyū-buntansha) 桐島 陽  東北大学, 多元物質科学研究所, 准教授 (00400424)
千田 太詩  東北大学, 工学(系)研究科(研究院), 助教 (30415880)
三村 均  東北大学, 工学(系)研究科(研究院), 教授 (10091753)
Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥42,510,000 (Direct Cost: ¥32,700,000、Indirect Cost: ¥9,810,000)
Fiscal Year 2016: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Fiscal Year 2015: ¥7,280,000 (Direct Cost: ¥5,600,000、Indirect Cost: ¥1,680,000)
Fiscal Year 2014: ¥10,920,000 (Direct Cost: ¥8,400,000、Indirect Cost: ¥2,520,000)
Fiscal Year 2013: ¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Keywords原子力エネルギー / バックエンド / 放射性廃棄物 / 管理・処分システム / セメント系材料 / カルシウムシリケート水和物 / ヨウ素 / 冠水環境 / 処分システム / 核種閉じ込め / セメント材料
Outline of Final Research Achievements

In consideration of embedding radioactive waste in the subsurface where the liquid-solid ratio is small and saturated by groundwater, the confinement function of calcium silicate hydrate (hereinafter referred to as CSH) was examined by using mainly iodide ions.
While CSH is the main component of cement, it is known that Ca gradually leaches due to alteration. However, even if the Ca/Si molar ratio 1.6 of ordinary cement decreases to 0.4, the results in this study showed that the CSH confines iodine undergoing a form dissolved in the hydration water. Furthermore, such a confinement function also appeared in the flow field of groundwater. This means that in a geological disposal system CSH itself repairs the barrier damaged by crustal deformation and so on.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (27 results)

All 2017 2016 2015 2014 2013 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results,  Open Access: 8 results,  Acknowledgement Compliant: 9 results) Presentation (16 results)

  • [Journal Article] Sorption Behavior of Iodide Ions on Calcium Silicate Hydrate Formed under the Condition Saturated with Saline Water2017

    • Author(s)
      Hirotaka Tago, Taiji Chida, Yuichi Niibori
    • Journal Title

      Proceedings of WM2017 (HLW, TRU, LLW/ILW, Mixed, Hazardous Wastes & Environmental Management)

      Volume: Paper No. 17069 Pages: 1-10

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Sorption Behavior of Cesium Ions on Calcium Aluminosilicate Hydrate under the Condition Saturated with Saline Water2017

    • Author(s)
      Hisatoshi Kasahara, Taiji Chida, Yuichi Niibori
    • Journal Title

      Proceedings of WM2017 (HLW, TRU, LLW/ILW, Mixed, Hazardous Wastes & Environmental Management)

      Volume: Paper No. 17096 Pages: 1-10

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Influence of Calcium Concentration on Permeability Changes in Flow-paths Altered by Highly Alkaline Groundwater2017

    • Author(s)
      Ryo Tashiro, Daiki Kurata, Yuichi Niibori, Taiji Chida
    • Journal Title

      Proceedings of WM2017 (HLW, TRU, LLW/ILW, Mixed, Hazardous Wastes & Environmental Management)

      Volume: Paper No. 17129 Pages: 1-10

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Effect of Temperature on Deposition Rate of Supersaturated Silicic Acid on Ca-Type Bentonite2016

    • Author(s)
      Tsuyoshi Sasagawa, Taiji Chida, Yuichi Niibori
    • Journal Title

      Proceedings of the 2016 24th International Conference on Nuclear Engineering (ICONE24)

      Volume: Paper No. 60468 Pages: 1-8

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Alteration Behavior of Granite Minerals Forming Calcium Silicate Hydrate under a Ca-Rich Highly Akaline Condition2016

    • Author(s)
      Hiten Fujita, Ryo Tashiro, Taiji Chida, Yuichi Niibori
    • Journal Title

      Proceedings of WM2016 (HLW, TRU, LLW/ILW, Mixed, Hazardous Wastes & Environmental Management)

      Volume: Paper No.16160 Pages: 1-8

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Deposition Behavior of Supersaturated Silicic Acid on Ca-type Bentonite in Geological Disposal System2016

    • Author(s)
      Tsuyoshi Sasagawa, Taiji Chida, Yuichi Niibori
    • Journal Title

      Proceedings of WM2016 (HLW, TRU, LLW/ILW, Mixed, Hazardous Wastes & Environmental Management)

      Volume: Paper No.16033 Pages: 1-8

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Evaluation of sorption behavior of iodide ions on calcium sificate hydrate and hydrotalcite2015

    • Author(s)
      Chida, T., Furuya, J., Niibori, Y., Mimura, H.
    • Journal Title

      Scientific Basis for Nuclear Waste Management XXXVIII (Material Research Society Proceedings)

      Volume: 1744 Pages: 29-34

    • DOI

      10.1557/opl.2015.336

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Effects of pH on Deposition Rate of Supersaturated Silicic Acid around Geological Disposal System2015

    • Author(s)
      Tsuyoshi Sasagawa, Taiji Chida, Yuichi Niibori, Hitoshi Mimura
    • Journal Title

      Proceedings of WM2015 (HLW, TRU, LLW/ILW, Mixed, Hazardous Wastes & Environmental Management)

      Volume: Paper No.15245 Pages: 1-9

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Deposition Behavior of Supersaturated Silicic Acid in the Condition of Relatively High Ca or Na Concentration2014

    • Author(s)
      Taiji Chida, Yuichi Niibori, Hayata Shinmura and Hitoshi Mimura
    • Journal Title

      Scientific Basis for Nuclear Waste Management XXXVII (Material Research Society Proceedings)

      Volume: 1665 Pages: 55-60

    • DOI

      10.1557/opl.2014.628

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Raman Spectra of Calcium Silicate Hydrates Sorbing Iodine Ions in Saline Groundwater2014

    • Author(s)
      Jun Furuya, Taiji Chida, Yuichi Niibori, Hitoshi Mimura
    • Journal Title

      Proceedings of WM2014 (HLW, TRU, LLW/ILW, Mixed, Hazardous Wastes & Environmental Management)

      Volume: Paper No, 14077 Pages: 1-12

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Influence of Calcium Ions on Migration of Colloidal Silicic Acid in the Presence of Solid Phase2014

    • Author(s)
      Taiji Chida, Yuichi Niibori, Hitoshi Mimura
    • Journal Title

      Proceedings of WM2014 (HLW, TRU, LLW/ILW, Mixed, Hazardous Wastes & Environmental Management)

      Volume: Paper No. 14123 Pages: 1-10

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 塩化物イオン共存下におけるカルシウムシリケート水和物へのヨウ化物イオンの収着挙動2016

    • Author(s)
      小野寺駿斗,田児啓貴,千田太詩,新堀雄一
    • Organizer
      日本原子力学会
    • Place of Presentation
      福岡県久留米市(久留米シティプラザ)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] カルシウムシリケート水和物の形成およびセシウム収着挙動に及ぼすホウ酸塩の影響2016

    • Author(s)
      原 直哉,千田太詩,新堀雄一
    • Organizer
      日本原子力学会
    • Place of Presentation
      福岡県久留米市(久留米シティプラザ)
    • Year and Date
      2016-09-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] 地層処分場周辺の温度条件におけるCa型ベントナイトに対する過飽和ケイ酸析出挙動の評価2016

    • Author(s)
      笹川 剛,千田太詩,新堀雄一
    • Organizer
      日本原子力学会春の年会
    • Place of Presentation
      宮城県仙台市(東北大学)
    • Year and Date
      2016-03-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] マイクロフローセルを用いた高アルカリ地下水による透水性変化の評価2015

    • Author(s)
      田代 龍,千田太詩,新堀雄一
    • Organizer
      日本原子力学会秋の大会
    • Place of Presentation
      静岡県静岡市(静岡大学)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 埋め戻しによって形成されるCa型ベントナイトへの過飽和ケイ酸の析出挙動2015

    • Author(s)
      笹川 剛,千田太詩,新堀雄一
    • Organizer
      日本原子力学会秋の大会
    • Place of Presentation
      静岡県静岡市(静岡大学)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高塩水環境下におけるヨウ化物イオンのカルシウムシリケート水和物への収着挙動2015

    • Author(s)
      田児啓貴,千田太詩,新堀雄一
    • Organizer
      日本原子力学会秋の大会
    • Place of Presentation
      静岡県静岡市(静岡大学)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ca型ベントナイトへの過飽和ケイ酸析出による流路閉塞の可能性2015

    • Author(s)
      笹川 剛,千田太詩,新堀雄一
    • Organizer
      日本原子力学会第31回「バックエンド」夏季セミナー
    • Place of Presentation
      北海道旭川市(道北経済センタービル)
    • Year and Date
      2015-08-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Caイオン含有高アルカリ環境における花崗岩構成鉱物の変質挙動2015

    • Author(s)
      藤田飛天,田代 龍,千田太詩,新堀雄一
    • Organizer
      日本原子力学会第31回「バックエンド」夏季セミナー
    • Place of Presentation
      北海道旭川市(道北経済センタービル)
    • Year and Date
      2015-08-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] 処分場近傍におけるケイ酸析出挙動による流路閉塞効果の評価2014

    • Author(s)
      笹川剛, 千田太詩, 新堀雄一, 三村均
    • Organizer
      日本原子力学会東北支部第36回研究交流会
    • Place of Presentation
      宮城県仙台市(東北大学)
    • Year and Date
      2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] 蛍光スペクトルおよびTOF-SIMSによる薄片状黒雲母に対するユウロピウム(III)の収着および拡散挙動2014

    • Author(s)
      杉山翔一, 佐々木剛, 千田太詩, 新堀雄一, 三村均
    • Organizer
      日本原子力学会秋の大会
    • Place of Presentation
      京都府京都市(京都大学)
    • Year and Date
      2014-09-08 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Caイオン含有高アルカリ地下水による花崗岩変質に伴うCSHの生成挙動2014

    • Author(s)
      藤田飛天, 新堀雄一, 三村均, 千田太詩, 倉田大輝
    • Organizer
      日本原子力学会秋の大会
    • Place of Presentation
      京都府京都市(京都大学)
    • Year and Date
      2014-09-08 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] 処分場周辺におけるケイ酸析出速度のpH依存性2014

    • Author(s)
      笹川剛, 千田太詩, 新堀雄一, 三村均
    • Organizer
      日本原子力学会バックエンド部会第30回「バックエンド」夏期セミナー
    • Place of Presentation
      福島県郡山市(ビッグパレットふくしま)
    • Year and Date
      2014-08-06 – 2014-08-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] ラマン分光分析法を用いたCSHゲル及びハイドロタルサイトへのヨウ素の収着挙動の評価2014

    • Author(s)
      古谷 純,千田太詩,新堀雄一,三村 均
    • Organizer
      日本原子力学会春の年会
    • Place of Presentation
      東京都市大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] アルカリフロントにおける流路幅および流量変化を考慮したケイ酸析出挙動の評価2013

    • Author(s)
      笹川 剛,千田太詩,新堀雄一,三村 均
    • Organizer
      日本原子力学会バックエンド部会第29回「バックエンド」夏季セミナー
    • Place of Presentation
      福島市
    • Related Report
      2013 Annual Research Report
  • [Presentation] 蛍光発光スペクトルによる乾燥過程を経ないCSHとEu(III)との相互作用の評価2013

    • Author(s)
      斎藤雄太,千田太詩,新堀雄一,三村 均
    • Organizer
      日本原子力学会バックエンド部会第29回「バックエンド」夏季セミナー
    • Place of Presentation
      福島市
    • Related Report
      2013 Annual Research Report
  • [Presentation] 冠水セメント系材料へのヨウ化物イオン収着挙動に及ぼす液固比の影響

    • Author(s)
      古谷 純,千田太詩,新堀雄一,三村 均,桐島 陽
    • Organizer
      日本原子力学会東北支部第37回研究交流会
    • Place of Presentation
      東北大学
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-15   Modified: 2019-07-29  

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