• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Separation and recovery process for rare earth metals using molten salt electrolysis and liquid metals

Research Project

Project/Area Number 25281047
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Environmental conscious materials and recycle
Research InstitutionOsaka University

Principal Investigator

Konishi Hirokazu  大阪大学, 工学(系)研究科(研究院), 助教 (60379120)

Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥19,500,000 (Direct Cost: ¥15,000,000、Indirect Cost: ¥4,500,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2014: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2013: ¥13,910,000 (Direct Cost: ¥10,700,000、Indirect Cost: ¥3,210,000)
Keywordsリサイクル / 希土類金属 / 溶融塩 / 液体金属 / 電解プロセス / 電気化学 / レアアース / 有価物回収
Outline of Final Research Achievements

We proposed new separation and recovery process for rare earth metals using molten salt electrolysis and liquid metals. The alloy samples were prepared by potentiostatic electrolysis using liquid Bi, Sn and Zn electrodes in molten LiCl-KCl added DyCl3 and NdCl3 at 723 K. The formation of Dy-Nd-Zn, Dy-Nd-Sn, Dy-Nd-Bi alloys were confirmed. The atomic ratios of Dy/Nd in Bi, Zn alloy samples were about 2. Rare earth and Fe could be separated by controlling the area of liquid electrodes or applied potential. Dy and Nd of Nd-Fe-B magnets in liquid Sn electrodes could be dissolved into the molten salt as RE ions.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (13 results)

All 2016 2015 2014

All Journal Article (5 results) (of which Peer Reviewed: 4 results,  Open Access: 2 results,  Acknowledgement Compliant: 4 results) Presentation (7 results) (of which Int'l Joint Research: 4 results,  Invited: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Dy Permeation through an Alloy Diaphragm Using Electrochemical Implantation and Displantation2016

    • Author(s)
      H. Konishi, T. Oishi, T. Nohira, H. Ono and E. Takeuchi
    • Journal Title

      ECS Transactions

      Volume: 75 Pages: 105-111

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Electrochemical Formation of RE-Sn (RE=Dy, Nd) Alloys Using Liquid Sn Electrodes in a Molten LiCl-KCl System2016

    • Author(s)
      A. Kuriyama, K Hosokawa, H. Konishi, H. Ono, E. Takeuchi, T. Nohira and T. Oishi
    • Journal Title

      ECS Transactions

      Volume: 75 Pages: 341-348

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] 希土類磁石スクラップからの希土類金属分離・回収プロセス2015

    • Author(s)
      小西宏和、野平俊之、大石哲雄
    • Journal Title

      化学工業

      Volume: 66 Pages: 703-707

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Separation of Dy from Nd-Fe-B Magnet Scraps Using Molten Salt Electrolysis2014

    • Author(s)
      Hirokazu Konishi, Hideki Ono, Eiichi Takeuchi, Toshiyuki Nohira and Tetsuo Oishi
    • Journal Title

      ECS Transactions

      Volume: 64 Pages: 593-600

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical Formation of RE-Zn (RE=Dy, Nd) Alloys in a Molten LiCl-KCl System2014

    • Author(s)
      Hirokazu Konishi, Hideki Ono, Eiichi Takeuchi, Toshiyuki Nohira and Tetsuo Oishi
    • Journal Title

      ECS Transactions

      Volume: 61 Pages: 19-26

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Dy Permeation through an Alloy Diaphragm Using Electrochemical Implantation and Displantation2016

    • Author(s)
      H. Konishi, T. Oishi, T. Nohira, H. Ono and E. Takeuchi
    • Organizer
      PRiME2016
    • Place of Presentation
      ホノルル
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrochemical Formation of RE-Sn (RE=Dy, Nd) Alloys Using Liquid Sn Electrodes in a Molten LiCl-KCl System2016

    • Author(s)
      A. Kuriyama, K Hosokawa, H. Konishi, H. Ono, E. Takeuchi, T. Nohira and T. Oishi
    • Organizer
      PRiME2016
    • Place of Presentation
      ホノルル
    • Year and Date
      2016-10-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Growth rate of DyNi2 Film by Molten Salt Electrolysis2015

    • Author(s)
      H. Konishi, T. Nohira, Y. Ito, H. Ono, E. Takeuchi
    • Organizer
      11th International Conference on Diffusion in Solids and Liquids - DSL 2015
    • Place of Presentation
      ミュンヘン(ドイツ)
    • Year and Date
      2015-06-22
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Investigation of Dy Permeation through Dy Alloy Diaphragm Using Molten Salt Electrolysis2015

    • Author(s)
      H. Konishi, T. Oishi, T. Nohira, H. Ono, and E. Takeuchi
    • Organizer
      227th ECS Meeting
    • Place of Presentation
      シカゴ(アメリカ)
    • Year and Date
      2015-05-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ELECTROCHEMICAL SEPARATION OF Dy AND Nd FROM Nd MAGNET SCRAP IN A MOLTEN LiCl-KCl2015

    • Author(s)
      Hirokazu Konishi, Hideki Ono, Eiichi Takeuchi, Toshiyuki Nohira and Tetsuo Oishi
    • Organizer
      TMS 2015 Annual Meeting
    • Place of Presentation
      オーランド
    • Year and Date
      2015-03-15 – 2015-03-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 塩化物系溶融塩を用いた希土類元素の電解分離2014

    • Author(s)
      小西宏和
    • Organizer
      第25回電解プロセス研究会
    • Place of Presentation
      京都市(京都大学)
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Electrochemical Separation of Dy from Nd Magnet Scrap in a Molten LiCl-KCl2014

    • Author(s)
      Hirokazu Konishi, Hideki Ono, Eiichi Takeuchi, Toshiyuki Nohira, Tetsuo Oishi
    • Organizer
      SHECHTMAN INTERNATIONAL SYMPOSIUM
    • Place of Presentation
      カンクン
    • Year and Date
      2014-06-29 – 2014-07-04
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 希土類金属の製造方法2015

    • Inventor(s)
      1) 小西宏和, 粟津知之, 坪倉光隆, 真嶋正利
    • Industrial Property Rights Holder
      1) 小西宏和, 粟津知之, 坪倉光隆, 真嶋正利
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-09-11
    • Related Report
      2015 Annual Research Report

URL: 

Published: 2013-05-21   Modified: 2018-03-22  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi