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Development of fast hydrogen production/storage system using interfacial ionic transport

Research Project

Project/Area Number 25281061
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Design and evaluation of sustainable and environmental conscious system
Research InstitutionThe University of Tokyo

Principal Investigator

OTOMO Junichiro  東京大学, 新領域創成科学研究科, 准教授 (90322065)

Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥14,950,000 (Direct Cost: ¥11,500,000、Indirect Cost: ¥3,450,000)
Fiscal Year 2016: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Keywords低炭素社会 / 化学エネルギー貯蔵 / イオン伝導体 / 水素生成
Outline of Final Research Achievements

Fast hydrogen energy conversion systems were developed in combination with solid state ionics and chemical-looping technology. For chemical energy conversion cycles: (1) reduction reaction (i.e., chemical energy storage) (2) hydrogen production (3) total oxidation (heat recovery and regeneration of oxygen carriers), we developed a thermochemical-looping system and an electrochemical-looping system. Composite oxygen carriers consisting of an oxide ion electron mixed conductor and a metal oxide were synthesized successfully. Thus we obtained oxygen carriers with good performance on reduction reaction in hydrogen and reoxidation in steam. In addition, we developed a novel proton-conducting fuel cell for an electrochemical-looping system, and examined the feasibility of the proposed system.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (39 results)

All 2017 2016 2015 2014 2013 Other

All Journal Article (7 results) (of which Peer Reviewed: 7 results,  Acknowledgement Compliant: 4 results,  Open Access: 1 results) Presentation (30 results) (of which Int'l Joint Research: 7 results,  Invited: 2 results) Remarks (2 results)

  • [Journal Article] Structural and transport properties of lanthanum tungstate with high La/W ratio: availability of lanthanum tungstate for proton-conducting solid oxide fuel cells operating at intermediate temperature2017

    • Author(s)
      Gen Kojo, Reina Tsukimura, Junichiro Otomo
    • Journal Title

      Solid State Ionics

      Volume: 印刷中 Pages: 89-96

    • DOI

      10.1016/j.ssi.2017.04.009

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Influence of La/W ratio on electrical conductivity of lanthanum tungstate with high La/W ratio2017

    • Author(s)
      Gen Kojo, Yohei Shono, Hiroshi Ushiyama, Yoshito Oshima and Junichiro Otomo
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 248 Pages: 1-8

    • DOI

      10.1016/j.jssc.2017.01.011

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Redox Reaction Kinetics of Fe2O3 by Hydrogen and Water with Oxide Ion Conducting Supports and Oxygen Transport Modeling for Fe2O3 Reduction Process2016

    • Author(s)
      Fumihiko Kosaka, Hiroyuki Hatano, Yoshito Oshima, Junichiro Otomo
    • Journal Title

      Journal of Chemical Engineering of Japan

      Volume: 49 Pages: 243-250

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Iron oxide redox reaction with oxide ion conducting supports for hydrogen production and storage systems2015

    • Author(s)
      Fumihiko Kosaka, Hiroyuki Hatano, Yoshito Oshima and Junichiro Otomo
    • Journal Title

      Chemical Engineering Science

      Volume: 123 Pages: 380-387

    • DOI

      10.1016/j.ces.2014.11.012

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Acceleration of Fe2O3 Reduction Kinetics by Wet Methane using Calcium Titanate as a Support2013

    • Author(s)
      Syunsuke Isogai, Fumihiko Kosaka, Isao Takimoto, Hiroyuki Hatano, Yoshito Oshima, Junichiro Otomo
    • Journal Title

      Chemistry Letters

      Volume: 42 Issue: 11 Pages: 1438-1440

    • DOI

      10.1246/cl.130624

    • NAID

      130004426839

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microstructure Observation and Electrical Conductivities of Proton-Conducting TiO2-P2O5 Glass-Ceramic Solid Electrolytes2013

    • Author(s)
      Ryoto Kawamura, Ryosuke Sakamoto, Yoshito Oshima, Junichiro Otomo
    • Journal Title

      Phosphorus Research Bulletin

      Volume: 28 Pages: 24-19

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Gadolinia-Doped Ceria as Support Material on Redox of Iron Oxide for Energy Conversion System2013

    • Author(s)
      Fumihiko Kosaka, Noriaki Kikuchi, Hiroyuki Hatano, Yoshito Oshima, Junichiro Otomo
    • Journal Title

      Proceedings of International symposium on Innovative Materials for Processes in Energy Systems (IMPRES) Chemical Science & Engineering

      Volume: 3 Pages: 582-586

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 高La/W比領域におけるタングステン酸ランタンの合成とプロトン伝導特性2017

    • Author(s)
      小城 元・大友 順一郎
    • Organizer
      電気化学会第84回大会
    • Place of Presentation
      首都大学東京 南大沢キャンパス
    • Year and Date
      2017-03-25
    • Related Report
      2016 Annual Research Report
  • [Presentation] プロトン伝導性固体電解質形燃料電池の開発と電解合成への応用2017

    • Author(s)
      大友 順一郎
    • Organizer
      日本化学会 第97春季年会
    • Place of Presentation
      慶應義塾大学 日吉・矢上キャンパス
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] タングステン酸ランタンの輸送物性に基づくプロトン伝導性固体酸化物形燃料電池のセル設計2017

    • Author(s)
      月村 玲菜・小城 元・松崎 良雄・大友 順一郎
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学 豊洲キャンパス
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Enhancement of oxygen release in CuO oxygen carriers supported on perovskite oxides in chemical looping with oxygen uncoupling for solid fuel combustion2017

    • Author(s)
      Ochieng James Ochieng, Fumihiko Kosaka, Yoshito Oshima, Junichiro Otomo
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学 豊洲キャンパス
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] タングステン酸ランタンの構造解析とイオン伝導特性評価2016

    • Author(s)
      小城元・月村玲奈・松岡修平・大友順一郎
    • Organizer
      第25回SOFC研究発表会
    • Place of Presentation
      科学技術館サイエンスホール
    • Year and Date
      2016-12-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Redox cycle behavior and stability of metal oxides on perovskite oxide supports in chemical looping systems2016

    • Author(s)
      Ochieng James Ochieng, Fumihiko Kosaka, Junichiro Otomo
    • Organizer
      4th International Conference on Chemical Looping
    • Place of Presentation
      International Conference Hotel Nanjing, China
    • Year and Date
      2016-09-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reaction kinetics and morphological variation of Fe-based oxygen carriers in redox cycles of chemical looping systems2016

    • Author(s)
      Junichiro Otomo, Yuya Saito, Kazuyuki Miya, Noriaki Kikuchi, Fumihiko Kosaka
    • Organizer
      4th International Conference on Chemical Looping
    • Place of Presentation
      International Conference Hotel Nanjing, China
    • Year and Date
      2016-09-26
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrical properties of lanthanum tungstate with high La/W ratio2016

    • Author(s)
      Gen Kojo, Junichiro Otomo
    • Organizer
      The 18th International Conference on Solid State Protonic Conductors (SSPC-18)
    • Place of Presentation
      Sori Moria Coference Center, Oslo, Norway
    • Year and Date
      2016-09-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水素生成・貯蔵を指向したケミカルループ法におけるイルメナイト系酸素キャリアの開発2016

    • Author(s)
      味谷 和之・大友 順一郎
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学 常三島キャンパス
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] Synthesis of lanthanum tungstate and application to proton conducting solid oxide fuel cells2016

    • Author(s)
      Gen Kojo, Shuhei Matsuoka, Yoshito Oshima, Junichiro Otomo
    • Organizer
      2016 Asian SOFC Symposium
    • Place of Presentation
      東京大学 駒場IIキャンパス
    • Year and Date
      2016-09-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高La/W比領域におけるタングステン酸ランタンの合成とプロトン伝導特性2016

    • Author(s)
      小城 元・大友 順一郎
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学吹田キャンパス
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] Redox cycle behavior and stability of metal oxides on perovskite oxides supports in chemical looping systems2016

    • Author(s)
      Ochieng James Ochieng, Fumihiko Kosaka, Hiroyuki Hatano, Yoshito Oshima, Junichiro Otomo
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学千里山キャンパス
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] タングステン酸ランタンを用いたプロトン伝導性固体電解質の合成と燃料電池への適用2016

    • Author(s)
      小城 元・松岡 修平・大島 義人・大友 順一郎
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学千里山キャンパス
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Redox reaction kinetics of metal oxides in chemical-looping processes for hydrogen production/storage systems using oxide ion conducting materials2015

    • Author(s)
      Junichiro Otomo, Fumihiko Kosaka, Yoshito Oshima, Hiroyuki Hatano
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem 2015)
    • Place of Presentation
      Makai Bllrm (Hyatt Regency Waikiki), Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Application of Ion Conducting Materials to Electrical Energy Conversion and Storage Systems2015

    • Author(s)
      Junichiro Otomo
    • Organizer
      The 7th China-Japan Symposium on Chemical Engineering
    • Place of Presentation
      Beijing Conference Center
    • Year and Date
      2015-10-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] タングステン酸ランタンのプロトン伝導率に対するLa/W比の影響評価2015

    • Author(s)
      小城 元・大友 順一郎
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学札幌キャンパス
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Role of Oxide Ion Transport on Promoting Iron Oxide Redox Reaction with Oxide Ion Conductors as Supports for Energy Storage and Conversion2015

    • Author(s)
      Fumihiko Kosaka, Hiroyuki Hatano, Yoshito Oshima, Junichiro Otomo
    • Organizer
      20th International Conference on Solid State Ionics
    • Place of Presentation
      Keystone Resort & Conference Center, Keystone, Colorado USA
    • Year and Date
      2015-06-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] CaTi0.8Fe0.2O3混合伝導帯を用いた異相界面の作製と電子・イオン伝導特性の評価2015

    • Author(s)
      岩永愛季・大友順一郎
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 酸化物イオン伝導体の水素生成・エネルギー変換システムへの応用2015

    • Author(s)
      大友順一郎・高坂文彦
    • Organizer
      化学工学会第80年会
    • Place of Presentation
      芝浦工業大学豊洲キャンパス
    • Year and Date
      2015-03-19 – 2015-03-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] 無機イオン伝導体における局所イオン伝導特性の観測2014

    • Author(s)
      岩永愛季・大友順一郎
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学伊都キャンパス
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属酸化物の酸化還元反応を利用した水素貯蔵技術における反応解析2014

    • Author(s)
      高坂文彦・幡野 博之・大島義人・大友順一郎
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学伊都キャンパス
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Reduction kinetics and stability of CuO and NiO on perovskite supports in chemical looping systems2014

    • Author(s)
      Ochieng James Ochieng, Fumihiko Kosaka, Pooya Azadi, Hiroyuki Hatano, Yoshito Oshima, Junichiro Otomo
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学伊都キャンパス
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of Oxide Ion and Mixed conductors as Supports on Metal Oxide Redox Kinetics in Chemical Looping Systems2014

    • Author(s)
      Junichiro Otomo, Syunsuke Isogai, Fumihiko Kosaka, Yoshito Oshima, and Hiroyuki Hatano
    • Organizer
      3rd International Conference on Chemical Looping
    • Place of Presentation
      Chalmers University of Technology, Gothenburg, Sweden
    • Year and Date
      2014-09-09 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高速水素生成を目指したケミカルループ法における酸化鉄複合粒子の開発と反応解析2014

    • Author(s)
      高坂 文彦・幡野 博之・大島 義人・大友 順一郎
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学柳戸キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] ケミカルループ燃焼におけるCa-Ti-O系担体を用いた金属酸化物の還元反応特性2014

    • Author(s)
      磯貝 俊介・大友 順一郎・大島 義人・幡野 博之
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学柳戸キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] Acceleration of Redox Reaction of Metal Oxide with Oxide Ion Conducting Support Materials and Application to Hydrogen Production2014

    • Author(s)
      Junichiro Otomo, Syunsuke Isogai, Fumihiko Kosaka, Hiroyuki Hatano
    • Organizer
      European Hydrogen Energy Conference (EHEC) 2014
    • Place of Presentation
      Seville, Spain
    • Related Report
      2013 Annual Research Report
  • [Presentation] 酸化鉄の酸化還元反応を利用した水素貯蔵技術における担体効果の検討2013

    • Author(s)
      高坂 文彦・幡野 博之・大島 義人・大友 順一郎
    • Organizer
      化学工学会 第45回 秋季大会
    • Place of Presentation
      岡山大学 津島(東)キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] ケミカルループ燃焼における酸化物イオン伝導体を用いた酸素キャリア金属酸化物の還元反応特性2013

    • Author(s)
      磯貝 俊介・大友 順一郎・幡野 博之
    • Organizer
      化学工学会 第45回 秋季大会
    • Place of Presentation
      岡山大学 津島(東)キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] プロトン伝導性リン酸ガラス-セラミックスの微構造観察とイオン伝導特性2013

    • Author(s)
      門田 稔・大島 義人・大友 順一郎
    • Organizer
      化学工学会 第45回 秋季大会
    • Place of Presentation
      岡山大学 津島(東)キャンパス
    • Related Report
      2013 Annual Research Report
  • [Presentation] Effect of Gadolinia-Doped Ceria as Support Material on Redox of Iron Oxide for Energy Conversion System2013

    • Author(s)
      Fumihiko Kosaka, Noriaki Kikuchi, Hiroyuki Hatano, Yoshito Oshima, Junichiro Otomo
    • Organizer
      International Symposium on Innovative Materials for Processes in Energy Systems 2013 (IMPRES2013)
    • Place of Presentation
      九州大学伊都キャンパス
    • Related Report
      2013 Annual Research Report
  • [Remarks] 大友研究室ホームページ

    • URL

      http://www.otomolab.k.u-tokyo.ac.jp/index.html

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report 2014 Annual Research Report
  • [Remarks] 大友研究室ホームページ

    • URL

      http://www.otomolab.k.u-tokyo.ac.jp/index.html

    • Related Report
      2013 Annual Research Report

URL: 

Published: 2013-05-21   Modified: 2019-07-29  

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