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Preparation of high-performance oxide photovoltaic devices with electrochemical reactions

Research Project

Project/Area Number 25281062
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Design and evaluation of sustainable and environmental conscious system
Research InstitutionToyohashi University of Technology

Principal Investigator

Izaki Masanobu  豊橋技術科学大学, 工学(系)研究科(研究院), 教授 (30416325)

Co-Investigator(Kenkyū-buntansha) 笹野 順司  豊橋技術科学大学, 工学(系)研究科(研究院), 助教 (40398938)
Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000)
Fiscal Year 2015: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2013: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
Keywords酸化銅 / 太陽電池 / 熱力学 / 銅酸化物 / CuO / Cu2O / ZnO / 電気化学 / 水溶液 / 超高効率化 / p型半導体
Outline of Final Research Achievements

The technique for controlling the characteristics and optimization of the structure has been investing to develop the 1.4-eV-CuO-photovoltaic devices with high theoretical conversion efficiency and the preparation process with electrochemical process. The internally stacked CuO/Cu2O bilayer structure has been prepared by electrodeosition of the Cu2O layer followed by heating in air, and both the 2.1-eV-Cu2O and 1.4-eV-CuO layers act as photovoltaic layers, resulting in the expansion of the absorption band.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (39 results)

All 2017 2016 2015 2014 2013 Other

All Int'l Joint Research (4 results) Journal Article (6 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 6 results,  Acknowledgement Compliant: 5 results,  Open Access: 2 results) Presentation (27 results) (of which Int'l Joint Research: 5 results,  Invited: 3 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] Chime Paristech(フランス)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] University Malaysia Perils/University Tun Hussein One Malaysia(マレーシア)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Chime ParisTech(ENSCP)(フランス)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] Universiti Malaysia Perlis/Universiti Tun hussein Onn Malaysia(マレーシア)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Room temperature ultraviolet-light-emitting ZnO vertical nanowires prepared by electrochemical growth2017

    • Author(s)
      Masanobu Izaki, Jun Komori, Kairi Shimidzu, Takayuki Koyama, Tsutomu Shinagawa,
    • Journal Title

      physica status solidi a

      Volume: 214 Pages: 1600473-1600473

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photon-assisted electrodeosition of <0001>-n-ZnO/<111>-p-Cu2O photovoltaic devices with TiO2 intermediate layer2015

    • Author(s)
      Mohd Zamzuri, Junji Sasano, Fariza Binti Mohamad, Masanobu Izaki
    • Journal Title

      Applied Mechanics and Materials

      Volume: 773-774 Pages: 622-625

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Electrodeposited <111>-oriented Cu2O photovoltaic devices with Al:ZnO2015

    • Author(s)
      Mohd Zamzuri, Fariza Binti Mohamad, Masanobu Izaki
    • Journal Title

      Journal of Surface Finishing Society of Japan

      Volume: 66 Pages: 544-545

    • NAID

      110001972654

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Substrate-type <111>--Cu2O/<0001>-ZnO photovoltaic device prepared by photo-assisted electrodeosition2015

    • Author(s)
      Mohd Zamzuri, Junji Sasano, Fariza Binti Mohamad, Masanobu Izaki
    • Journal Title

      Thin Solid Films

      Volume: 595 Pages: 136-141

    • DOI

      10.1016/j.tsf.2015.10.054

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Electrodeposited ZnO-Nanowire/Cu2O Photovoltaic Device with Highly Resistive ZnO Intermediate Layer2014

    • Author(s)
      Masanobu Izaki, Takayuki Ohta, Misaki Kondo, Toshiaki Takahashi, Fariza Binti Mohamad, Mohd Zamzuri, Junji Sasano, Tsutomu Shinagawa, Thierry Pauporte
    • Journal Title

      American Chemical Society, Appl. Mater. & Interfaces

      Volume: 6 Issue: 16 Pages: 13461-13469

    • DOI

      10.1021/am502246j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Photon-Assisted Electrochemical Construction of <0001>-n-ZnO/<111>-p-Cu2O Photovoltaic Devices with Intermediate TiO2 Layer2014

    • Author(s)
      Mohammad Zain Mohd Zamzuri, Junji Sasano, Fariza Binti Mohamad, Masanobu Izaki
    • Journal Title

      ECS Transactions

      Volume: 64 Issue: 15 Pages: 21-26

    • DOI

      10.1149/06415.0021ecst

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Presentation] Internally stacked Cu2O/CuO photovoltaic layer with expanded absorption band2017

    • Author(s)
      Pei Loon Khoo, Kazuma Fukasawa, Naoki Yamashiro, Masakazu Kobayashi, Masanobu Izaki
    • Organizer
      E-MRS 2017 Spring Meeting
    • Place of Presentation
      Strasburg Convention Center
    • Year and Date
      2017-05-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 熱力学に立脚した酸化物半導体形成技術と半導体素子への展開2017

    • Author(s)
      伊﨑昌伸
    • Organizer
      資源・素材学会春季大会
    • Place of Presentation
      千葉
    • Year and Date
      2017-03-29
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 熱力学に立脚した酸化物半導体形成技術と太陽電池への展開2016

    • Author(s)
      伊﨑昌伸
    • Organizer
      日本セラミックス協会2016年秋季シンポジウム
    • Place of Presentation
      広島大学、広島
    • Year and Date
      2016-09-07
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Internally stacked Cu2O/CuO photovoltaic layer with expanded absorption band2016

    • Author(s)
      M. izaki, K. Fukazawa, N. yamashiro
    • Organizer
      NANO 2016
    • Place of Presentation
      Quebec City, canada
    • Year and Date
      2016-08-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrodeposited High Spatial Resolution Vertical ZnO-Nanowires Scintillator2016

    • Author(s)
      Masanobu Izaki,
    • Organizer
      E-MRS 2016 Spring Meeting
    • Place of Presentation
      Lille Convention Center
    • Year and Date
      2016-05-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Electrodeposited high spatial resolution vertical ZnO-nanowires scintillator2016

    • Author(s)
      M.Izaki, K. Shimizu, T. Toyama, M. Kobayashi
    • Organizer
      2016 Spring Meeting of European-MRS
    • Place of Presentation
      Lille, France
    • Year and Date
      2016-05-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Effects of post-annealing on the performance of the electrodeposited Cu2O/ZnO photovoltaic device2016

    • Author(s)
      P.L. Khoo, Mohd. Zamzuri, T. Shinagawa, M. Izaki
    • Organizer
      表面技術協会第133回講演大会
    • Place of Presentation
      早稲田大学
    • Year and Date
      2016-03-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] 溶液化学法による酸化物半導体層の形成と太陽電池への応用2016

    • Author(s)
      伊﨑昌伸
    • Organizer
      表面技術協会第133回講演大会
    • Place of Presentation
      早稲田大学、東京
    • Year and Date
      2016-03-22
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Effects on external quantum efficiency of electrochemically constructed n-ZnO/p-Cu2O photovoltaic device by annealing2016

    • Author(s)
      P.L. Khoo, Y. Kikkawa. T. Shinagawa, M. Izaki
    • Organizer
      3rd International Conference of Global Network For Innovative Technology 2016 (IGNITE 2016)
    • Place of Presentation
      Penang, Malaysia
    • Year and Date
      2016-01-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 電気化学的に形成したCu2O/ZnO太陽電池の量子効率に及ぼす加熱処理の効果2015

    • Author(s)
      P.L. Khoo, Y. Kikkawa. T. Shinagawa, M. Izaki
    • Organizer
      第46回中部科学連合講演会
    • Place of Presentation
      三重大学、三重
    • Year and Date
      2015-11-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] ポスト加熱による電析Cu2O太陽電池の量子効率向上2015

    • Author(s)
      吉川裕貴/Khoo Pei Loon/高橋俊明/品川勉/伊﨑昌伸
    • Organizer
      電気化学会第82回大会
    • Place of Presentation
      横浜国立大学(神奈川県横浜市)
    • Year and Date
      2015-03-15 – 2015-03-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 界面ミスマッチ制御による室温紫外 発光 ZnO の電気化学的形成2015

    • Author(s)
      伊﨑昌伸/甲盛諄/ 清水開史/小林正和
    • Organizer
      表面技術協会第131回講演大会
    • Place of Presentation
      関東学院大学 横浜・金沢八景キャンパス(神奈川県横浜市)
    • Year and Date
      2015-03-04 – 2015-03-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] 直立単配向ZnOナノワイヤー(nw) /Cu2O太陽電池の電気化学的形成と高効率化2014

    • Author(s)
      高橋俊明/太田貴之/近藤美紗紀/笹野順司/伊﨑昌伸
    • Organizer
      第4回高専-TUT太陽電池合同シンポジウム
    • Place of Presentation
      神戸市立工業高等専門学校(兵庫県神戸市)
    • Year and Date
      2014-12-22 – 2014-12-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Photon-Assisted Electrodeposition of <0001>-n-ZnO/<111>-p-Cu2O Photovoltaic Devices with TiO2 Intermediate Layer2014

    • Author(s)
      Mohammad Zain Mohd Zamzuri, Junji Sasano, Fariza Binti Mohamad, Masanobu Izaki
    • Organizer
      International Integrated Engineering Summit 2014
    • Place of Presentation
      Universiti Tun Hussein Onn Malaysia (UTHM) (Johor. Malaysia)
    • Year and Date
      2014-12-01 – 2014-12-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] Photon-Assisted Electrochemical Construction of <0001>-n-ZnO/<111>-p-Cu2O Photovoltaic Devices with Intermediate TiO2 Layer2014

    • Author(s)
      Mohammad Zain Mohd Zamzuri, Junji Sasano, Fariza Binti Mohamad, Masanobu Izaki
    • Organizer
      2014 ECS and SMEQ Joint International Meeting
    • Place of Presentation
      Moon Palace Resort (Cancun, Mexico)
    • Year and Date
      2014-10-05 – 2014-10-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] 直立単配向ZnOナノワイヤー(nw)/Cu2O太陽電池の電気化学的形成と高効率化2014

    • Author(s)
      高橋俊明/太田貴之/近藤美紗紀/笹野順司/伊﨑昌伸
    • Organizer
      2014年電気化学秋季大会
    • Place of Presentation
      2014年電気化学秋季大会(北海道札幌市)
    • Year and Date
      2014-09-27 – 2014-09-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノピラーZnO/Cu2O 太陽電池の電気化学的形成2014

    • Author(s)
      高橋俊明/太田貴之/近藤美沙紀/品川 勉/Thierry Pauporte/伊崎昌伸
    • Organizer
      2014年東海地区ヤングエレクトロケミスト研究会
    • Place of Presentation
      信州大学工学部内長野市ものづくり支援センター(長野県長野市)
    • Year and Date
      2014-09-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノ構造導入によるCu2O/ZnO系太陽電池の高効率化2014

    • Author(s)
      高橋俊明/太田貴之/近藤美沙紀/品川 勉/Thierry Pauporté/伊﨑昌伸
    • Organizer
      日本機会学会東海支部 第63期総会・講演会
    • Place of Presentation
      大同大学滝春校舎(愛知県名古屋市南区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ナノピラーZnO/Cu2O太陽電池の電気化学的形成2013

    • Author(s)
      高橋俊明/太田貴之/近藤美沙紀/品川勉/Thierry Pauporte/伊﨑昌伸
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] O半導体層の電気化学的形成とバンドギャップ制御2013

    • Author(s)
      山尾宜道/笹野順司/伊崎昌伸
    • Organizer
      2013年電気化学秋季大会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Cu2O/Ag積層体のアニーリング処理による構造変化2013

    • Author(s)
      山本雄太/笹野順司/伊崎昌伸
    • Organizer
      2013年電気化学秋季大会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ナノ構造導入によるCu2O/ZnO系太陽電池の高効率化2013

    • Author(s)
      高橋俊明/太田貴之/近藤美沙紀/品川 勉/Thierry Pauporté/伊﨑昌伸
    • Organizer
      第44回 中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      静岡大学浜松キャンパス (静岡県浜松市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] O半導体層の電気化学的形成とバンドギャップ制御2013

    • Author(s)
      山尾宜道/笹野順司/伊崎昌伸
    • Organizer
      第44回 中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      静岡大学浜松キャンパス (静岡県浜松市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Cu2O/Ag積層体のアニーリング処理による構造変化2013

    • Author(s)
      山本雄太/笹野順司/伊崎昌伸
    • Organizer
      第44回 中部化学関係学協会支部連合秋季大会
    • Place of Presentation
      静岡大学浜松キャンパス (静岡県浜松市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] ナノ構造導入によるCu2O/ZnO系太陽電池の高効率化2013

    • Author(s)
      高橋俊明/太田貴之/近藤美沙紀/品川 勉/Thierry Pauporté/伊﨑昌伸
    • Organizer
      第3回高専-TUT太陽電池合同シンポジウム
    • Place of Presentation
      木更津工業高等専門学校(千葉県木更津市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] O半導体層の電気化学的形成とバンドギャップ制御2013

    • Author(s)
      山尾宜道/笹野順司/伊崎昌伸
    • Organizer
      第3回高専-TUT太陽電池合同シンポジウム
    • Place of Presentation
      木更津工業高等専門学校(千葉県木更津市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Cu2O/Ag積層体のアニーリング処理による構造変化2013

    • Author(s)
      山本雄太/笹野順司/伊崎昌伸
    • Organizer
      第3回高専-TUT太陽電池合同シンポジウム
    • Place of Presentation
      木更津工業高等専門学校(千葉県木更津市)
    • Related Report
      2013 Annual Research Report
  • [Book] 水溶液電気化学製膜法による酸化物半導体膜の形成と太陽電池への展開 書籍:「ウエットプロセスによる精密薄膜コーティング技術」2014

    • Author(s)
      伊﨑昌伸(共著)
    • Total Pages
      9
    • Publisher
      株式会社技術情報協会
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 光電変換層及び光電変換層の製造方法2015

    • Inventor(s)
      伊﨑昌伸、深澤和馬
    • Industrial Property Rights Holder
      伊﨑昌伸、深澤和馬
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2015-177515
    • Filing Date
      2015-09-09
    • Related Report
      2015 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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