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Design of device for electric generation and energy saving which can contribute to the decreasing dependency on atomic power generation

Research Project

Project/Area Number 25281066
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Design and evaluation of sustainable and environmental conscious system
Research InstitutionNational Institute for Materials Science

Principal Investigator

MORI Toshiyuki  国立研究開発法人物質・材料研究機構, エネルギー・環境材料研究拠点, 上席研究員 (80343854)

Co-Investigator(Kenkyū-buntansha) YAN Pengfei  国立研究開発法人物質・材料研究機構, ナノ材料科学環境拠点(GREEN)固体酸化物形燃料電池材料設計グループ, ポスドク研究員 (20596556)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2015: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2014: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2013: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Keywords燃料電池 / 水蒸気電解 / 中温作動 / ステンレス・スティール / 高効率 / 固体酸化物形燃料電池 / サーメットアノード / 中温域動作 / ヘテロ界面 / 燃料電池デバイス / 高温水蒸気電解デバイス / 中温動作 / 白金-酸化物ヘテロ界面 / 3層界面 / セリア / ジルコニア / 微量白金 / 低炭素社会 / グリーンエネルギー / ガドリウムドープドセリアナノワイヤー / 欠陥界面 / 電極性能 / 燃料電池デバイス / 高温水蒸気電界デバイス
Outline of Final Research Achievements

The important results which were obtained by the present work are summarized as follows; It was clarified that oxygen defect structure with C type rare earth structure was formed in the anodic condition, although the formation of aforementioned oxygen defect structure was not so important for development of high temperature operation solid oxide fuel cells. In the present work, a development of high quality electrode which includes active metal/ defect fluorite interface was performed in order to design the functional interface which can promote the fuel cell reaction below 100 degree C. This challenge tells us that Pt-defect fluorite interface with C type rare earth structure has promotion effect in the fuel cell reaction. On the basis of all experimental results, we successfully fabricated the functional interface by doping small amount Pt cation in the anode layer of solid oxide fuel cells and hydrogen electrode of solid oxide electrolysis cells.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (38 results)

All 2016 2015 2014 2013 Other

All Int'l Joint Research (2 results) Journal Article (12 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 12 results,  Acknowledgement Compliant: 2 results,  Open Access: 1 results) Presentation (20 results) (of which Int'l Joint Research: 2 results,  Invited: 13 results) Book (3 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] クイーンズランド大学/電子顕微鏡センター(オーストラリア)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] チャールズ大学/数理物理学科(チェコ)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Defect structure analysis of hetero-interface between Pt and CeOx promoter on Pt electro-catalyst2015

    • Author(s)
      Fugane K, Mori T, Yan P F, Masuda T, Yamamoto S, Ye F, Yoshikawa H, Auchterlonie G and Drennan J
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 7 Issue: 4 Pages: 2698-2707

    • DOI

      10.1021/am507754w

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Breaking aggregation in a tetrathiafulvalene-fused zinc porphyrin by metal-ligand coodination to form a donor-acceptor hybrid for ultrafast charge separation and charge stabilization2015

    • Author(s)
      Atanu Jana, Habtom B. Gobeze, Masatoshi Ishida, Toshiyuki Mori, Katsuhiko Ariga, Jonathan P. Hill and Francis D’Souza
    • Journal Title

      Dalton Trans

      Volume: 44 Issue: 1 Pages: 359-367

    • DOI

      10.1039/c4dt03157a

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Study of the character of gold nanoparticles deposited onto sputtered cerium oxide layers by deposition-precipitation method: influence of the preparation parameters2015

    • Author(s)
      Tatiana Zahoranova, Toshiyuki Mori, Peng Fei Yan, Klára Ševčíková, Michal Václavů, Vladimir Matolin, Václav Nehasil
    • Journal Title

      Vacuum

      Volume: 114 Pages: 86-92

    • DOI

      10.1016/j.vacuum.2015.01.005

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Design of Pt-CeOx hetero-interface on electrodes in polymer electrolyte membrane fuel cells2014

    • Author(s)
      Mori T, Fugane K, Chauhan S, Ito M, Masuda T, Noguchi H, and Uosaki K,
    • Journal Title

      IOP Conf. Series: Materials Science and Engineering

      Volume: 54 Pages: 012010-012010

    • DOI

      10.1088/1757-899x/54/1/012010

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Reduction of thermal conductivity in dually doped ZnO by design of three-dimensional stacking faults2014

    • Author(s)
      Takemoto H, Fugane K, Yan P F, Drennan J, Saito M, Mori T, and Yamamura H,
    • Journal Title

      RSC advances

      Volume: 4 Issue: 6 Pages: 2661-2672

    • DOI

      10.1039/c3ra44223c

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relationship between lattice mismatch and ionic conduction of grain boundary in YSZ2014

    • Author(s)
      4.Ye F, Yin C C, Ou D R, and Mori T
    • Journal Title

      Progress in Natural Science Materials International

      Volume: 24 Issue: 1 Pages: 84-86

    • DOI

      10.1016/j.pnsc.2014.01.007

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An assessment of interatomic potentials for yittria-stablized zirconia2014

    • Author(s)
      Yin C, Ye F, Yin C Y, Ou D R, and Mori T
    • Journal Title

      Applied Mechanics and Materials

      Volume: 492 Pages: 239-247

    • DOI

      10.4028/www.scientific.net/amm.492.239

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] HAXPES study of CeOx thin film - silicon oxide interface2014

    • Author(s)
      Vorokhta M, Matolinova I, Dubau M, Haviar S, Khalakhan I, Sevcikova K, Mori T, Yoshikawa H, and Matolin V
    • Journal Title

      Applied Surface Science

      Volume: 303 Pages: 46-53

    • DOI

      10.1016/j.apsusc.2014.02.048

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microstructure evolution of yttria-doped ceria in reducing atmosphere2013

    • Author(s)
      Li Z P, Mori T, Auchterlonie G J, Zou J, and Drennan J
    • Journal Title

      Renewable Energy -an international journal-

      Volume: 50 Pages: 494-497

    • DOI

      10.1016/j.renene.2012.07.019

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Defects clustering and ordering in di- and trivalently doped ceria2013

    • Author(s)
      Li Z P, Mori T, Zou J, and Drennan J
    • Journal Title

      Materials Research Bulletin

      Volume: 48 Issue: 2 Pages: 807-812

    • DOI

      10.1016/j.materresbull.2012.11.073

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microstructural and chemical characterization of ordered structure in yttrium doped ceria2013

    • Author(s)
      Yan P F. Mori T, Wu Y Y, Li Z M, Auchterlonie G J, Zou J, and Drennan J
    • Journal Title

      Micrscopy and Microanalysis

      Volume: 19 Pages: 102-110

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of a nano-structured Pt-loaded cerium oxide nanowire and its anode performance in the methanol electro-oxidation reaction2013

    • Author(s)
      Chauhan S, Richards G J, Mori T, Yan P F, Hill J P, Ariga K, Zou J and Drennan J
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 1 Issue: 20 Pages: 6262-6270

    • DOI

      10.1039/c3ta10652g

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 白金-セリア電極界面への異種異質クラスター活性サイトの設計と その燃料電池用電極への応用2016

    • Author(s)
      森利之
    • Organizer
      第2回 CiRfSEワークショップ
    • Place of Presentation
      筑波大学 数理物質融合科学センター
    • Year and Date
      2016-01-18
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Design of active sites in the interface of anode layer of solid oxide fuel cell byy ultra-low amount PtOx sputtering2015

    • Author(s)
      森利之, Andrii REDNYK, 鈴木彰, 山本春也, Shipra CHAUHAN, 伊坂紀子
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      神奈川県民ホール会議室
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Interface design of ultra-low amount Pt loaded ceria nanowire/C with high ORR activity by proton beam irradiation at solid-liquid interface2015

    • Author(s)
      Shipra CHAUHAN, 森利之, 小林知洋, 山本春也, 伊坂紀子
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      神奈川県民ホール会議室
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] Designing of hetero-interface between Pt and ceria nanowire for development of Pt less cathode with high ORR activity2015

    • Author(s)
      Shipra CHAUHAN, 森利之, 伊坂紀子, John DRENNAN
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      情報文化センター
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] Effect of gamma-ray irradiation on enhancemnt of charge transfer in th einterface between less Pt loaded CeOx nanowire/C and Nafion ionomer in membrane electrode assembly of PEMFC2015

    • Author(s)
      高橋研一, 森利之, 鈴木彰, Shipra CHAUHAN, 前川康成, 廣木章博, 吉村公男, 山本春也
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      情報文化センター
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] Design of Pt-CeOx nanowire interface in less Pt electrode with high performance for fuel cell applications2015

    • Author(s)
      Toshiyuki MORI, Shipra CHAUHAN, Keisuke FUGANE, Tomohiro KOBAYASHI, Shunya YAMAMOTO
    • Organizer
      International conference of advanced materials 2015
    • Place of Presentation
      Jeju International Convention Center, Korea
    • Year and Date
      2015-10-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication and characterization of Pt loaded ceria nanowire/C for improvement of MOR and ORR activities2015

    • Author(s)
      Shipra CHAUHAN, Toshiyuki MORI
    • Organizer
      Conference sponsorInternational conference FiMPART’ 15
    • Place of Presentation
      Hyderabad International Convention Centre (India)
    • Year and Date
      2015-06-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of high quality less Pt electrode for development of high quality compact fuel cells2015

    • Author(s)
      Toshiyuki MORI
    • Organizer
      Europe - Japan Symposium
    • Place of Presentation
      Delegation of the European Union,Tokyo,日本(Japan)
    • Year and Date
      2015-03-26 – 2015-03-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] プロトンビームを用いたPt-CeOx/C電極界面の高性能化2015

    • Author(s)
      森 利之, 小林知洋, 山本春也
    • Organizer
      第7回 量子ビームを利用した燃料電池システム用キーマテリアルの開発
    • Place of Presentation
      物質・材料研究機構, つくば, 日本
    • Year and Date
      2015-02-02
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 活性金属-酸化セリウムヘテロ界面機能を活用した燃料電池用電極材料設計研究2014

    • Author(s)
      森 利之
    • Organizer
      日本希土類学会第32回講演会
    • Place of Presentation
      アイビーホール青学会館,東京,日本
    • Year and Date
      2014-11-14
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Improvement of ORR activity and CO tolerance on Pt by formation of Pt-CeOx hetero-interfaces2014

    • Author(s)
      Toshiyuki MORI, Keisuke FUGANE, Ding Rong OU, John DRENNAN
    • Organizer
      The 15th IUMRS-International Conference in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      福岡大学,福岡,日本
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Design of Pt and ceria nanowire interface with the help of atomistic simulation method for improvement of anode and cathode property on Pt2014

    • Author(s)
      Shipra CHAUHAN, Toshiyuki MORI, Jin ZOU, John DRENNAN
    • Organizer
      The 15th IUMRS-International Conference in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      福岡大学,福岡市,日本
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Fabrication and characterization of Pt and ceria nanowire interface for improvement of CO tolerance and ORR on Pt2014

    • Author(s)
      Shipra CHAUHAN, Toshiyuki MORI, Pengfei YAN, Jin ZOU, John DRENNAN
    • Organizer
      The 15th IUMRS-International Conference in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      福岡大学,福岡市,日本
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Development of Pt loaded ceria electrodes in fuel cells based on the results of microanalysis2014

    • Author(s)
      Toshiyuki MORI, Keisuke FUGANE, Shipra CHAUHAN, Takuya MASUDA, Pengfei YAN, Jin ZOU, Graeme AUHTERLONIE, John DRENNAN
    • Organizer
      8th international conference on advanced materials processing
    • Place of Presentation
      Hotel Grand Chancellor Surfers Paradise,Gold Coast, Queensland,Australia
    • Year and Date
      2014-07-27 – 2014-07-30
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Design of Pt-CeOx Hetero-interface on Cathodes for Improvement of Oxygen Reduction Reaction2014

    • Author(s)
      Toshiyuki MORI, Keisuke FUGANE, Shipra CHAUHAN, Takuya MASUDA, Kohei UOSAKI
    • Organizer
      International Union Materials Research Society and MRS- Taiwan
    • Place of Presentation
      TWTC Nangan Exhibition Hall, ,Taipei,Taiwan
    • Year and Date
      2014-06-10 – 2014-06-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Interface design of Pt-CeOx electrodes for polymer type fuel cells

    • Author(s)
      森 利之
    • Organizer
      IUMRS-ICAM2013
    • Place of Presentation
      青島(中国)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Design of bulk and interface of doped ceria based materials for development of intermediate temperature operating SOFC

    • Author(s)
      Toshiyuki MORI
    • Organizer
      Seminar at Dalian Institute of Chemical Physics,Chinese Academy of Sciences
    • Place of Presentation
      大連(中国)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Design of Pt-CeOx hetero-interface structure on electrodes in fuel cells

    • Author(s)
      Toshiyuki MORI
    • Organizer
      The 3rd German - Japan Nano-workshop
    • Place of Presentation
      つくば市(日本)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 金属ー酸化物ヘテロ界面機能を活用した燃料電池用電極材料設計

    • Author(s)
      森 利之
    • Organizer
      第一回日本MRS講演会
    • Place of Presentation
      横浜(日本)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 燃料電池用Pt電極上のPt-CeOx界面の設計

    • Author(s)
      森 利之
    • Organizer
      第23回日本MRS年次大会
    • Place of Presentation
      横浜(日本)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] XAFS/EELSによる局所構造解析, 第4章4節, EELSによる燃料電池材料の解析2014

    • Author(s)
      1.森 利之
    • Total Pages
      11
    • Publisher
      (株)情報機構, 東京都
    • Related Report
      2014 Annual Research Report
  • [Book] Rare Earths: New Research, 分担執筆題目: Chapter 10, Defect clusters in rare earth doped ceria2013

    • Author(s)
      Li Z P, and Mori T
    • Total Pages
      11
    • Publisher
      Nova Science Publishers, Inc., (New York, NY), ISBN: 978-1-62618-996-6, editor:Prof. Zhosen Liu
    • Related Report
      2013 Annual Research Report
  • [Book] Handbook of Sustainable Engineering Section, 分担執筆題目:No.60, Advanced materials for fuel cells2013

    • Author(s)
      Mori T, and Drennan J
    • Total Pages
      12
    • Publisher
      Spriger Publishing Company, editors in chief: Prof. Kauffman Joanne, Prof. Lee Kun-Mo,
    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] 固体酸化物形燃料電池のアノード材料及びその製造方法、並びに固体酸化物形燃料電池2015

    • Inventor(s)
      森 利之、Andrii Rednyk, 鈴木 彰
    • Industrial Property Rights Holder
      森 利之、Andrii Rednyk, 鈴木 彰
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-06-15
    • Related Report
      2015 Annual Research Report

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Published: 2013-05-21   Modified: 2022-02-01  

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