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Study of 3D local structures around magnetic elements in room temperature ferromagnetic semiconductors

Research Project

Project/Area Number 25286040
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Applied materials
Research InstitutionNagoya Institute of Technology (2016)
Tohoku University (2013-2015)

Principal Investigator

Hayashi Koichi  名古屋工業大学, 工学(系)研究科(研究院), 教授 (20283632)

Co-Investigator(Kenkyū-buntansha) 細川 伸也  熊本大学, 自然科学研究科, 教授 (30183601)
田中 義人  兵庫県立大学, その他の研究科, 教授 (80260222)
Co-Investigator(Renkei-kenkyūsha) Fukumura Tomoteru  東北大学, 大学院理学研究科, 教授 (90333880)
Uchitomi Naotaka  長岡技術科学大学, 大学院工学研究科, 教授 (20313562)
Akagi Kazuto  東北大学, WPI, 准教授 (50313119)
Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2015: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2013: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
Keywords蛍光X線ホログラフィー / 強磁性半導体 / 局所構造 / 3D原子イメージ / 希薄磁性半導体 / 磁性元素 / 亜酸化物 / 蛍光X線ホログラフィー / スピントロニクス
Outline of Final Research Achievements

To understand local structures around magnetic elements, we measured X-ray fluorescence holograms of Co:TiO2 thin film, Mn:ZnSnAs2 thin film and GeMnTe thin film. In Co:TiO2 thin film, we discovered suboxide clusters around Co. The crystal structure of ZnSnAs2 thin film was sphalerite-type, and the As sublattice was largely distorted. Moreover, the local structure around Ge in GeMnTe thin film, reflecting rhombohedral GeTe structure, had lower symmetry than that around Mn.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (33 results)

All 2016 2015 2014 2013 Other

All Journal Article (16 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 16 results,  Open Access: 8 results,  Acknowledgement Compliant: 2 results) Presentation (12 results) (of which Int'l Joint Research: 3 results,  Invited: 9 results) Remarks (5 results)

  • [Journal Article] A divalent rare earth oxide semiconductor: Yttrium monoxide2016

    • Author(s)
      K. Kaminaga, R. Sei, K. Hayashi, N. Happo, H. Tajiri, D. Oka, T. Fukumura, T. Hasegawa
    • Journal Title

      Appl. Phys. Lett.

      Volume: 108 Issue: 12 Pages: 122102-122102

    • DOI

      10.1063/1.4944330

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Large As sublattice distortion in sphalerite ZnSnAs2 thin films revealed by x-ray fluorescence holography2016

    • Author(s)
      K. Hayashi, N. Uchitomi, K. Yamagami, A. Suzuki, H. Yoshizawa, J. T. Asubar, N. Happo, S. Hosokawa
    • Journal Title

      J. Appl. Phys

      Volume: 119 Issue: 12 Pages: 125703-125703

    • DOI

      10.1063/1.4945004

    • NAID

      120006697251

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Chemical and orbital fluctuations in Ba3CuSb2O92016

    • Author(s)
      Y. Wakabayashi, D. Nakajima, Y. Ishiguro, K. Kimura, T. Kimura, S. Tsutsui, A. Q. R. Baron, K. Hayashi, N. Happo, S. Hosokawa, K. Ohwada, and S. Nakatsuji
    • Journal Title

      Physical Review B

      Volume: 93 Issue: 24 Pages: 245117-245117

    • DOI

      10.1103/physrevb.93.245117

    • NAID

      120006697262

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Structural studies on TlInSe2 thermoelectric material by X-ray fluorescence holography, XAFS, and X-ray diffraction2015

    • Author(s)
      Shinya Hosokawa, Kenji Kamimura, Hiroyuki Ikemoto, Naohisa Happo, Kojiro Mimura, Kouichi Hayashi, Kohki Takahashi, Kazuki Wakita, and Nazim Mamedov
    • Journal Title

      physica status solidi (b)

      Volume: 252 Issue: 6 Pages: 1225-1229

    • DOI

      10.1002/pssb.201400247

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Local Structure Analysis of Incommensurate Phase in Ti-42Ni-8Fe(at.%) Alloy by X-ray Fluorescence Holography2015

    • Author(s)
      W. Hu, K. Hayashi, T. Fukumura, K. Akagi, M. Tsukada, N. Happo, S. Hosokawa, K. Ohwada, M. Takahasi, M. Suzuki, M. Kawasaki
    • Journal Title

      Appl. Phys. Lett.

      Volume: 106 Issue: 22 Pages: 222403-222403

    • DOI

      10.1063/1.4921847

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Local structure analysis of incommensurate phase in Ti-42Ni8Fe(at.%) alloy by X-ray fluorescence holography2015

    • Author(s)
      T, Terai, A. Toriyama, T. Fukuda, T. Kakeshita, K. Hayashi, N. Happo and S. Hosokawa
    • Journal Title

      Materials Today: Proceedings

      Volume: 2s

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ペロブスカイト型RRh3B(R=希土類元素)の合成および性質2015

    • Author(s)
      宍戸統悦、湯蓋邦夫、森 孝雄、田中雅彦、岡田 繁、野村明子、菅原孝昌、林 好一、澤田 豊、手嶋勝弥、大石修治、川添良幸、吉川 彰
    • Journal Title

      Journal of Flux Growth

      Volume: Vol.10 Pages: 2-9

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Local structure analysis of lanthanum-doped strontium titanate by means of X-ray fluorescence holography2015

    • Author(s)
      Yoshihiro Ebisu, Kouichi Hayashi, Naohisa Happo, Shinya Hosokawa, and Toru Ozaki
    • Journal Title

      Transactions of Materials Research Society Japan

      Volume: 40 Pages: 355-358

    • NAID

      130005113362

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A metallic glass grating for X-ray grating interferometers fabricated by imprinting2014

    • Author(s)
      W. Yashiro, D. Noda, T. Hattori, K. Hayashi, A. Momose, and H. Kato
    • Journal Title

      Appl. Phys. Exp.

      Volume: 7 Issue: 3 Pages: 32501-32501

    • DOI

      10.7567/apex.7.032501

    • NAID

      210000137015

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Detection of structural change of Pd-Cu-Ge metallic glass thin films upon heat treatment by using X-ray reflectivity2014

    • Author(s)
      Tokujiro Yamamoto, Kouichi Hayashi, Kosuke Suzuki, and Masahisa Ito
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 5S1 Pages: 05FH03-05FH03

    • DOI

      10.7567/jjap.53.05fh03

    • NAID

      210000143841

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Acute and obtuse rhombohedrons in the local structures of relaxor ferroelectric Pb(Mg1/3Nb2/3)O32014

    • Author(s)
      W. Hu, K. Hayashi, K. Ohwada, J. Chen, N. Happo, S. Hosokawa, M. Takahasi, A. A. Bokov, and Z. G. Ye
    • Journal Title

      Phys. Rev. B

      Volume: 89 Issue: 14

    • DOI

      10.1103/physrevb.89.140103

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Applications of x-ray fluorescence holography to determine local lattice distortions in materials2014

    • Author(s)
      K. Hayashi, N. Happo, and S. Hosokawa
    • Journal Title

      Journal of Electron Spectroscopy and Related Phenomena

      Volume: 195 Pages: 337-346

    • DOI

      10.1016/j.elspec.2014.07.008

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Pd-based metallic glass with a low glass transition temperature2013

    • Author(s)
      T. Yamamoto, K. Hayashi, I. Seki, K. Suzuki, and M. Ito
    • Journal Title

      J. Non-cryst. Solids

      Volume: 359 Pages: 46-50

    • DOI

      10.1016/j.jnoncrysol.2012.09.029

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 原子分解能ホログラフィー2013

    • Author(s)
      林 好一
    • Journal Title

      日本物理学会誌

      Volume: 68 Pages: 217-225

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Extent and feature of lattice distortions around Ga impurity atoms in InSb single crystal2013

    • Author(s)
      S. Hosokawa, N. Happo, T. Ozaki, H. Ikemoto, T. Shishido, and K. Hayashi
    • Journal Title

      Phys. Rev. B

      Volume: 87 Issue: 9 Pages: 94104-94104

    • DOI

      10.1103/physrevb.87.094104

    • NAID

      120005368324

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 蛍光X線ホログラフィーによる局所格子歪みの評価2013

    • Author(s)
      林 好一、八方直久、細川伸也
    • Journal Title

      放射光

      Volume: 26 Pages: 195-205

    • NAID

      10031178721

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 蛍光X線ホログラフィーの最近の応用と原子層観測への可能性2016

    • Author(s)
      林 好一
    • Organizer
      物性研究所短期研究会
    • Place of Presentation
      東京大学物性研、柏市
    • Year and Date
      2016-12-20
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] X-ray fluorescence holographic study on high-temperature superconductor FeSe0.4Te0.62016

    • Author(s)
      Kouichi Hayashi
    • Organizer
      International Workshop on Superconductivity and Related Functional Materials 2016
    • Place of Presentation
      NIMS, Tsukuba, Japan
    • Year and Date
      2016-12-20
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] X-ray fluorescence holography study of ZnSnAs2 thin films - Evaluation of large As sublattice distortion-2016

    • Author(s)
      Kouichi Hayashi
    • Organizer
      39th International conference on Vacuum Ultraviolet and X-ray Physics
    • Place of Presentation
      ETH, Zurich, Switzerland
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 蛍光X線ホログラフィーによる特異な3D構造の可視化2016

    • Author(s)
      林 好一
    • Organizer
      第29回日本放射光学会・放射光科学合同シンポジウム 企画公演「機能発現サイトの三次元可視化最前線」
    • Place of Presentation
      柏市 柏の葉カンファレンスセンター
    • Year and Date
      2016-01-09
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Applications of X-ray fluorescence holography -Lattice distortions and dopants-2016

    • Author(s)
      Kouichi Hayashi
    • Organizer
      Local 3D atomic and electronic structure imaging of functionally active sites
    • Place of Presentation
      University of Zurich, Zurich, Switzerland
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 酸化物高温強磁性半導体に潜む特異な原子配列の3D原子像化2015

    • Author(s)
      林 好一
    • Organizer
      Spring-8シンポジウム2015
    • Place of Presentation
      九州大学 伊都キャンパス
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 生体試料に向けた蛍光X線ホログラフィーの挑戦2015

    • Author(s)
      林 好一
    • Organizer
      第53回日本生物物理学会年会シンポジウム 「べん毛・繊毛が織りなす多様な生命現象に挑む ~分子から個体まで~」
    • Place of Presentation
      金沢市 金沢大学
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 蛍光X線ホログラフィーによるMg85Zn6Y9の濃縮層の構造評価2015

    • Author(s)
      林 好一、萩原幸司、伊豆野仁史、八方直久、細川伸也、鈴木基寛
    • Organizer
      日本金属学会春季講演会
    • Place of Presentation
      東京大学
    • Year and Date
      2015-03-18 – 2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] 蛍光X線ホログラフィーによるLPSO構造Mg合金における濃縮層の構造評価2015

    • Author(s)
      林 好一、萩原幸司、伊豆野仁史、八方直久、細川伸也、鈴木基寛
    • Organizer
      第28回日本放射光学会年会・放射光科学合同シンポジウム
    • Place of Presentation
      立命館大学
    • Year and Date
      2015-01-10 – 2015-01-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] X線・中性子線・電子線を用いる原子分解能ホログラフィー2013

    • Author(s)
      林 好一
    • Organizer
      物性研シリーズセミナー 極限コヒーレント科学
    • Place of Presentation
      柏市
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 中性子線ホログラフィー -軽元素及びスピンイメージングの可能性-2013

    • Author(s)
      林 好一
    • Organizer
      第5回 中性子応用専門委員会
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 原子分解能逆光電子ホログラフィーによる3D局所構造解析2013

    • Author(s)
      林 好一
    • Organizer
      日本顕微鏡学会 第57回シンポジウム
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Remarks] 構造物性科学研究室

    • URL

      http://structure.web.nitech.ac.jp/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 3D活性サイト科学

    • URL

      http://www.3d-activesite.jp/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 原子分解能ホログラフィー

    • URL

      https://sites.google.com/site/atomicholography/home

    • Related Report
      2015 Annual Research Report
  • [Remarks] 原子分解能ホログラフィー

    • URL

      https://sites.google.com/site/atomicholography/

    • Related Report
      2014 Annual Research Report
  • [Remarks] 原子分解能ホログラフィー研究会

    • URL

      https://sites.google.com/site/atomicholography/

    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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