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Development of organic tandem solar cells showing 15% efficiency by the pn-control of co-deposited films

Research Project

Project/Area Number 25286044
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Applied materials
Research InstitutionInstitute for Molecular Science

Principal Investigator

HIRAMOTO MASAHIRO  分子科学研究所, 物質分子科学研究領域, 教授 (20208854)

Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000)
Fiscal Year 2015: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2014: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2013: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Keywords有機太陽電池 / キャリアハイウェー / 超バルクヘテロ接合 / ドーピング有機単結晶 / ホール効果 / 有機半導体単結晶 / 超高速移動度 / 横取り出し / pn制御 / キャリア濃度 / ドーピング効率 / 有機半導体 / 単結晶 / エピタキシャル成長 / ドーピング / pnホモ接合 / 多数キャリア / 内蔵電界 / 少数キャリア拡散距離 / イオン化アクセプター散乱 / セル抵抗 / pn制御 / 内蔵電界設計 / 共蒸着膜 / バンドマッピング / ケルビン法 / 抵抗低減
Outline of Final Research Achievements

Carrier highway films, i.e., single crystalline films of high hole-mobility organic semiconductor and a high electron-mobility organic semiconductor were fabricated. Lateral extraction of photogenerated holes and electrons of the order of 1 mm was demonstrated in the hole and electron highway. Operation of super-bulkheterojunction cells combining the hole and electron highway, which can be regarded as a new type of organic tandem solar cell, was demonstrated. Hall effect measurements of the doped organic single crystals were succeeded for the first time. The present results have the meaning of dawn of organic single crystal electronics such as high performance organic single crystal solar cells.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (38 results)

All 2017 2016 2015 2014 2013 Other

All Journal Article (9 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 9 results) Presentation (25 results) (of which Int'l Joint Research: 7 results,  Invited: 11 results) Book (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Single crystal organic photovoltaic cells using lateral electron transport2017

    • Author(s)
      M. Kikuchi, K. Takagi, H. Naito, M. Hiramoto
    • Journal Title

      Organic Electronics

      Volume: 41 Pages: 118-121

    • DOI

      10.1016/j.orgel.2016.12.001

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hall Effect in Bulk-Doped Organic Single Crystals2017

    • Author(s)
      C. Ohashi, S. Izawa, Y. Shinmura, M. Kikuchi, S. Watase, M. Izaki, H. Naito, and M. Hiramoto
    • Journal Title

      Adv. Mater.

      Volume: 29 Issue: 23 Pages: 1605619-1605619

    • DOI

      10.1002/adma.201605619

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Enhancing the photocurrent in high-photovoltage organic solar cells by doping2015

    • Author(s)
      M. Kikuchi, Y. Shinmura, T. Kaji, T. Kono, Y. Yoshida, and M. Hiramoto
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 54 Issue: 11 Pages: 111601-111601

    • DOI

      10.7567/jjap.54.111601

    • NAID

      210000145818

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ppm-Doping Effects in the Simplest n+p-Homojunction Organic Photovoltaic Cells2015

    • Author(s)
      C. Ohashi, Y. Shinmura, M. Kubo, and M. Hiramoto
    • Journal Title

      Organic Electronics

      Volume: 27 Pages: 151-4

    • DOI

      10.1016/j.orgel.2015.09.001

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mapping of Band-bending for Organic pn-Homojunctions2015

    • Author(s)
      Y. Yamashina, Y. Shinmura, N. Ishiyama, T. Kaji, and M. Hiramoto
    • Journal Title

      Journal of Applied Physics

      Volume: 117 Issue: 12 Pages: 125501-125501

    • DOI

      10.1063/1.4915506

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mapping of Band-Bending for Doped C60 Films2014

    • Author(s)
      Y. Shinmura, T. Yoshioka, T. Kaji, and M. Hiramoto
    • Journal Title

      Applied Physics Express

      Volume: 7 Issue: 7 Pages: 071601-071601

    • DOI

      10.7567/apex.7.071601

    • NAID

      210000137158

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Y. Shinmura, Y. Yamashina, T. Kaji, and M. Hiramoto2014

    • Author(s)
      Y. Shinmura, Y. Yamashina, T. Kaji, and M. Hiramoto
    • Journal Title

      Applied Physics Letters

      Volume: 105

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tandem Organic Solar Cells Formed in Co-deposited Films by Doping2013

    • Author(s)
      Norihiro Ishiyama, Masayuki Kubo, Toshihiko Kaji, and Masahiro Hiramoto
    • Journal Title

      Org. Electron.

      Volume: 14 Issue: 7 Pages: 1793-1793

    • DOI

      10.1016/j.orgel.2013.04.003

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] pn-Homojunction Organic Solar Cells Formed in the Thick Phase-separated Co-deposited Films by Doping2013

    • Author(s)
      M. Kubo, T. Kaji, and M. Hiramoto
    • Journal Title

      Appl. Phys. Lett.

      Volume: 103 Issue: 26 Pages: 263303-14

    • DOI

      10.1063/1.4847296

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] ドーピングしたホモエピ-ルブレン単結晶のFET移動度2017

    • Author(s)
      大橋知佳
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] MoO3ドーピングしたルブレン-ホモエピ単結晶におけるHall効果2017

    • Author(s)
      菊地 満
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜(神奈川県横浜市)
    • Year and Date
      2017-03-17
    • Related Report
      2016 Annual Research Report
  • [Presentation] 有機半導体におけるドーピングによるpn制御と太陽電池応用2017

    • Author(s)
      平本昌宏
    • Organizer
      日本学術振興会 情報科学用有機材料第142委員会C部会(有機光エレクトロニクス)第74回合同研究会
    • Place of Presentation
      東京理科大学(東京都新宿区)
    • Year and Date
      2017-03-09
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Bandgap Science for Organic Solar Cells2016

    • Author(s)
      M. Hiramoto
    • Organizer
      2nd World Congress on Materials Science, Polymer Engineering, MIcrotechnologies, Oil, Gas and Petrochemistry
    • Place of Presentation
      Abu Dhabi, UAE
    • Year and Date
      2016-11-30
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 有機半導体のpn制御と有機太陽電池への応用2016

    • Author(s)
      平本昌宏
    • Organizer
      有機エレクトロニクスデバイス・材料に関する研究討論会
    • Place of Presentation
      大阪大学吹田キャンパス(大阪府吹田市)
    • Year and Date
      2016-09-30
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 高移動度有機単結晶薄膜によるミリメーターホール横取り出し光起電力セル2016

    • Author(s)
      菊地 満
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] 高移動度有機単結晶膜における横方向キャリア輸送を利用したD/A超格子型有機太陽電池2016

    • Author(s)
      菊地 満
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟県新潟市)
    • Year and Date
      2016-09-15
    • Related Report
      2016 Annual Research Report
  • [Presentation] Bandgap Science for Organic Solar Cells2016

    • Author(s)
      M. Hiramoto
    • Organizer
      KJF-ICOMEP 2016 (KJF International Conference on Organic Materials for Electronics and Photonics 2016)
    • Place of Presentation
      ACROS FUKUOKA, Fukuoka city, Fukuoka, Japan
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機単結晶薄膜太陽電池2016

    • Author(s)
      平本昌宏
    • Organizer
      第12回有機太陽電池シンポジウム-ペロブスカイト太陽電池の研究展開と有機薄膜太陽電池のポテンシャル-
    • Place of Presentation
      京都大学宇治キャンパス(京都府宇治市)
    • Year and Date
      2016-07-14
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Bandgap Science for Organic Solar Cells2016

    • Author(s)
      M. Hiramoto
    • Organizer
      IUMRS-ICEM2016 (International Union of Materials research Societies - International Conference on Electronic Materials 2016)
    • Place of Presentation
      SUNTEC Singapore Convention & Exhibition Centre, Singapore
    • Year and Date
      2016-07-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機半導体のpn制御と有機太陽電池への応用2016

    • Author(s)
      平本昌宏(招待)
    • Organizer
      第63回応用物理学会春季学術講演会シンポジウム「有機薄膜太陽電池の現状と今後の展望」
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Recent Progress and Future of Organic Photovoltaic Cells2016

    • Author(s)
      M. Hiramoto (Invited)
    • Organizer
      第63回応用物理学会春季学術講演会シンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Bandgap Science for Organic Solar cells2015

    • Author(s)
      M. Hiramoto
    • Organizer
      2015 MRS (Materials Research Society) Fall Meeting
    • Place of Presentation
      Hynes Convention Center, Boston, MA, USA
    • Year and Date
      2015-12-02
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Bandgap Science for Organic Solar Cells2015

    • Author(s)
      M. Hiramoto (Invited)
    • Organizer
      2015 International Conference on Solid State Devices and Materials
    • Place of Presentation
      Sapporo Convention Center, Sapporo, Japan
    • Year and Date
      2015-09-28
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Bandgap Science for Organic Solar Cells2015

    • Author(s)
      M. Hiramoto
    • Organizer
      E-MRS (Europe Materials Research Society) 2015 Spring Meeting
    • Place of Presentation
      Lille Grand Palais, Lille, France
    • Year and Date
      2015-05-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 100 ppm Doping Induced Photocurrent Enhancement in Photoactive Organic Co-deposited Layer2015

    • Author(s)
      C. Ohashi
    • Organizer
      E-MRS (Europe Materials Research Society) 2015 Spring Meeting
    • Place of Presentation
      Lille Grand Palais, Lille, France
    • Year and Date
      2015-05-11
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機共蒸着光電変換層への100 ppmドーピングによる光電流増大2015

    • Author(s)
      大橋知佳
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス(神奈川県 平塚市)
    • Year and Date
      2015-03-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Bandgap Science for Organic Solar Cells2015

    • Author(s)
      M. Hiramoto
    • Organizer
      JSPS-DST, Asian Academic Seminar and School 2015, “Spectroscopy, Theoretical Chemistry and Chemistry of Materials”
    • Place of Presentation
      Kolkata, India
    • Year and Date
      2015-03-06
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Bandgap Science for Organic Solar Cells2015

    • Author(s)
      M. Hiramoto
    • Organizer
      EMN (Energy Materials Nanotechnology) Meeting on Photovoltaics
    • Place of Presentation
      Orlando, FL, USA
    • Year and Date
      2015-01-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 1-10 ppm極微量ドーピングの有機太陽電池特性に与える影響2014

    • Author(s)
      久保雅之
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス(北海道 札幌市)
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機半導体のドーピングイオン化率増感2014

    • Author(s)
      新村祐介
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学札幌キャンパス(北海道 札幌市)
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Bandgap Science for Organic Solar Cells2014

    • Author(s)
      M. Hiramoto
    • Organizer
      MANA (International Center for Materials NanoArchitectonics) Symposium 2014
    • Place of Presentation
      つくば国際会議場(茨城県つくば市)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 共蒸着ドーピングにおけるイオン化率の増感2013

    • Author(s)
      新村祐介
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] 相分離共蒸着膜pnホモ接合セル2013

    • Author(s)
      久保雅之
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      同志社大学京田辺キャンパス(京都府京田辺市)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Bandgap Science for Organic Thin-Film Solar Cells” The 8th Aseanian Conference on Dye-sensitized & Organic Solar Cells

    • Author(s)
      M. Hiramoto
    • Organizer
      Global Photovoltaic Conference 2013 (GPVC 2013)
    • Place of Presentation
      Haeundae Grand Hotel(韓国 釜山)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] 機能性色素の新規合成・実用化動向(ppmドーピングによる有機半導体のpn制御と有機太陽電池応用)2016

    • Author(s)
      平本昌宏
    • Total Pages
      230
    • Publisher
      シーエムシー出版(株)
    • Related Report
      2016 Annual Research Report
  • [Book] 有機半導体のpn制御と有機薄膜太陽電池2014

    • Author(s)
      平本昌宏、新村祐介
    • Publisher
      日本真空学会
    • Related Report
      2014 Annual Research Report
  • [Book] 有機太陽電池のためのバンドギャップサイエンス2013

    • Author(s)
      平本昌宏
    • Total Pages
      7
    • Publisher
      応用物理
    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] 横方向キャリア収集型有機太陽電池2016

    • Inventor(s)
      平本、菊地、新村、廣田、阿部、貞光、内藤
    • Industrial Property Rights Holder
      日本化薬株式会社、自然科学研究機構、大阪府立大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2016-02-29
    • Related Report
      2015 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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