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Electron-spin-resonance study on SiC-MOSFETs and their MOS interface defects related to channel-mobility degradation

Research Project

Project/Area Number 25286054
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionUniversity of Tsukuba

Principal Investigator

Fujinoki Takahide  筑波大学, 数理物質系, 准教授 (10361354)

Co-Investigator(Kenkyū-buntansha) KOSUGI Ryouji  国立研究開発法人産業技術総合研究所, 先進パワーエレクトロニクス研究センター, 主任研究員 (10356991)
OKAMOTO Mitsuo  国立研究開発法人産業技術総合研究所, 先進パワーエレクトロニクス研究センター, 主任研究員 (60450665)
HARADA Shinsuke  国立研究開発法人産業技術総合研究所, 先進パワーエレクトロニクス研究センター, 研究チーム長 (20392649)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2015: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2014: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2013: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Keywordsパワーエレクトロニクス / 4H-SiC / MOSFET / 界面準位 / 電子スピン共鳴分光 / チャネル移動度 / 閾値変動 / 炭化ケイ素 / 酸化膜界面 / 界面欠陥 / 電界効果トランジスタ / ESR法 / 電流検出ESR法 / MOS界面 / しきい値電圧 / ESR / EDMR / 界面窒素 / チャネルドーピング / 界面水素 / しきい値シフト / 移動度劣化
Outline of Final Research Achievements

We studied electrically-active defects in 4H-SiC MOSFETs (metal-oxide-semiconductor field-effect transistors) using electrically-detected magnetic resonance (EDMR) spectroscopy. The EDMR observations revealed that "channel doping" of nitrogen donors or phosphorous donors has a crucial role on the improvement of channel mobility in Si-face SiC-MOSFETs. On the other hand, in C-face SiC-MOSFETs, a different type of interface defect is dominantly formed, which we named "C-face defects." They have a crucial role on the threshold-voltage instability in C-face MOSFETs. The control of "channel doping" and "C-face defects" is key for commercializing high-performance and high-reliability SiC-MOSFETs.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (26 results)

All 2016 2015 2014 2013 Other

All Journal Article (5 results) (of which Peer Reviewed: 4 results) Presentation (20 results) (of which Int'l Joint Research: 4 results,  Invited: 2 results) Remarks (1 results)

  • [Journal Article] C-face interface defects in 4H-SiC MOSFETs studied by electrically detected magnetic resonance2014

    • Author(s)
      T. Umeda, M. Okamoto, R. Arai, Y. Satoh, R. Kosugi, S. Harada, H. Okumura, T. Makino, T. Ohshima
    • Journal Title

      Materials Science Forum

      Volume: 778-780 Pages: 414-417

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improvement of channel mobility in 4H-SiC C-face MOSFETs by H2 rich wet re-oxidation2014

    • Author(s)
      M. Okamoto, Y. Makibuchi, M. Araoka, M. Miyazato, N. Sugahara, T. Tsutsumi, Y. Ohnishi, H. Kimura, S. Harada, K. Fukuda, A. Ohtsuki, H. Okumura
    • Journal Title

      Materials Science Forum

      Volume: 778-780 Pages: 975-978

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of SiC super-junction (SJ) devices by multi-epitaxial growth2014

    • Author(s)
      R. Kosugi, Y. Sakuma, K. Kojima, S. Itoh, A. Nagata, T. Yatsuo, Y. Tanaka, H. Okumura
    • Journal Title

      Materials Science Forum

      Volume: 778-780 Pages: 845-850

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] SiC MOS interface states: difference between Si face and C face2013

    • Author(s)
      T. Umeda, M. Okamoto, R. Kosugi, R. Arai, Y. Sato, S. Harada, T. Makino, T. Ohshima
    • Journal Title

      ECS Transactions

      Volume: 58 Pages: 55-60

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 4H-SiC MOS界面の電子スピン共鳴分光評価2013

    • Author(s)
      梅田享英, 岡本光央, 小杉亮治, 原田信介, 荒井亮, 佐藤嘉洋, 牧野高紘, 大島武, 奥村元
    • Journal Title

      シリコンテクノロジー(応用物理学会分科会)

      Volume: 161 Pages: 98-102

    • Related Report
      2013 Annual Research Report
  • [Presentation] 4H-SiC MOSFET中の単一表面欠陥の共焦点顕微鏡観察2016

    • Author(s)
      梅田享英、阿部裕太、Y.-W. Zhu、岡本光央、小杉亮治、原田信介、春山盛善、小野田忍、大島武
    • Organizer
      第63回応用物理学学術講演会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] エピタキシャル基板を使用した4H-SiC MOS窒化界面のESR評価2016

    • Author(s)
      梅田享英、鹿児山陽平、奥田貴史、須田淳、木本暢恒、小杉亮治、岡本光央、原田信介
    • Organizer
      第63回応用物理学学術講演会
    • Place of Presentation
      東京工業大学(東京都目黒区)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Electrically Detected Magnetic Resonance Study on Interface Defects Responsible forThreshold‐Voltage Shift in C‐face 4H‐SiC MOSFETs2015

    • Author(s)
      T. Umeda, R. Arai, S.J. Ma, G.W. Kim, M. Okamoto, H. Yoshioka, S. Harada, T. Makino, T. Ohshima
    • Organizer
      International Conference on Silicon Carbide and Related Materials 2016
    • Place of Presentation
      Sicily, Italy
    • Year and Date
      2015-10-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] An interfacial defect complex (the P8/9 centers) in C-face 4H-SiC MOSFET studied by electrically detected magnetic resonance2015

    • Author(s)
      T. Umeda, R. Arai, M. Okamoto, R. Kosugi, S. Harada
    • Organizer
      International Conference on Silicon Carbide and Related Materials 2016
    • Place of Presentation
      Sicily, Italy
    • Year and Date
      2015-10-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ESR study on hydrogen passivation of intrinsic defects in p-type and semi-insulating 4H-SiC2015

    • Author(s)
      K. Murakami, S. Tanai, T. Okuda, J. Suda, T. Kimoto, T. Umeda
    • Organizer
      International Conference on Silicon Carbide and Related Materials 2016
    • Place of Presentation
      Sicily, Italy
    • Year and Date
      2015-10-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Microscopic difference between dry and wet oxidations of C-face 4H-SiC MOSFFETs studied by electrically detected magnetic resonance2015

    • Author(s)
      Y. Kagoyama, M. Okamoto, S. Harada, R. Arai, T. Umeda
    • Organizer
      International Conference on Silicon Carbide and Related Materials 2016
    • Place of Presentation
      Sicily, Italy
    • Year and Date
      2015-10-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 容量検出型電子スピン共鳴分光法による4H-SiC MOSFETの結晶欠陥の測定2015

    • Author(s)
      鹿児山陽平、岡本光央、小杉亮治、原田信介、牧野高紘、大島武、梅田享英
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] Electrically Detected Magnetic Resonance (EDMR) Study on Interface Defects in C-face 4H-SiC Metal-Oxide-Semi-conductor Field Effect Transistors2015

    • Author(s)
      G.W. Kim, S.J. Ma, R. Arai, M. Okamoto, S. Harada, T. Makino, T. Ohshima, T. Umeda
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] 4H-SiC中の空孔欠陥と水素の反応と、水素複合欠陥のESR評価2015

    • Author(s)
      棚井創基、村上功樹、奥田貴史、須田淳、木本恒暢、小杉亮治、大島武、梅田享英
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス
    • Year and Date
      2015-03-11 – 2015-03-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] 4H‐SiC中の点欠陥はどこまで分かっているか? :バルク結晶とMOS界面2014

    • Author(s)
      梅田享英
    • Organizer
      第2回筑波大学パワーエレクトロニクス未来技術研究会
    • Place of Presentation
      筑波大学東京キャンパス
    • Year and Date
      2014-12-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] Nitrogen doping to channel regions of 4H-SiC MOSFETs characterized by electron spin resonance2014

    • Author(s)
      T. Umeda, Y. Sato, R. Kosugi, M. Okamoto), S. Harada, H. Okumura
    • Organizer
      European Conference on Silicon Carbide and Related Materials (ECSCRM) 2014
    • Place of Presentation
      Grenoble, France
    • Year and Date
      2014-09-21 – 2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Defects in 4H-SiC MOSFETs studied by Capacitively Detected Magnetic Resonance2014

    • Author(s)
      Y. Kagoyama, T. Umeda, M. Okamoto, R. Kosugi, S. Harada, T. Makino, T. Ohshima
    • Organizer
      European Conference on Silicon Carbide and Related Materials (ECSCRM) 2014
    • Place of Presentation
      Grenoble, France
    • Year and Date
      2014-09-21 – 2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 4H-SiC MOS界面窒化処理における窒素ドーピングのESR定量2014

    • Author(s)
      梅田享英、佐藤嘉洋、佐久間由貴、小杉亮治
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] シリコンカーバイド(4H-SiC)中の格子欠陥の評価: 電子スピン共鳴(ESR)法と、 第一原理計算の対応2014

    • Author(s)
      梅田享英
    • Organizer
      第24回格子欠陥フォーラム
    • Place of Presentation
      かんぽの宿恵那(恵那市)
    • Year and Date
      2014-09-11 – 2014-09-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] Development of SiC super-junction (SJ) devices by multi-epitaxial growth2013

    • Author(s)
      R. Kosugi, Y. Sakuma, K. Kojima, S. Itoh, A. Nagata, T. Yatsuo, Y. Tanaka, H. Okumura
    • Organizer
      International Conference on Silicon Carbide and Related Materials 2013
    • Place of Presentation
      Phoenix Seagaia Resort, Miyazaki, Japan
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] SiC MOS interface states: difference between Si face and C face

    • Author(s)
      T. Umeda, M. Okamoto, R. Kosugi, R. Arai, Y. Sato, S. Harada, T. Makino, T. Ohshima
    • Organizer
      224th Electrochemical Society Meeting
    • Place of Presentation
      The Hilton San Francisco Hotel, San Francisco, USA
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] C-face interface defects in 4H-SiC MOSFETs studied by electrically detected magnetic resonance

    • Author(s)
      T. Umeda, M. Okamoto, R. Arai, Y. Satoh, R. Kosugi, S. Harada, H. Okumura, T. Makino, T. Ohshima
    • Organizer
      International Conference on Silicon Carbide and Related Materials 2013
    • Place of Presentation
      Miyazaki, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] 電流検出ESRによる C面4H-SiC MOSFET界面欠陥からの水素脱離の観察

    • Author(s)
      荒井亮、梅田享英、佐藤嘉洋、岡本光央、原田信介、小杉亮治、奥村元、牧野高紘、大島武
    • Organizer
      第74回応用物理学会学術講演会
    • Place of Presentation
      同志社大学、京都府
    • Related Report
      2013 Annual Research Report
  • [Presentation] Improvement of channel mobility in 4H-SiC C-face MOSFETs by H2 rich wet re-oxidation

    • Author(s)
      M. Okamoto, Y. Makibuchi, M. Araoka, M. Miyazato, N. Sugahara, T. Tsutsumi, Y. Ohnishi, H. Kimura, S. Harada, K. Fukuda, A. Ohtsuki, H. Okumura
    • Organizer
      International Conference on Silicon Carbide and Related Materials 2013
    • Place of Presentation
      Phoenix Seagaia Resort, Miyazaki, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水素リッチウェット再酸化によって作製された4H-SiC(000-1)面上MOSFET

    • Author(s)
      岡本光央、巻渕陽一、荒岡幹、宮里真樹、須ケ原紀之 、堤岳志、大西泰彦、木村浩、原田信介、福田憲司、大月章弘、奥村元
    • Organizer
      SiC及び関連半導体研究第22回講演会
    • Place of Presentation
      埼玉会館、埼玉県
    • Related Report
      2013 Annual Research Report
  • [Remarks] ESR Spectroscopy Laboratory, University of Tsukuba

    • URL

      http://esrlab.bk.tsukuba.ac.jp/index.php?id=6

    • Related Report
      2013 Annual Research Report

URL: 

Published: 2013-05-21   Modified: 2019-07-29  

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