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Work function modulation in the heterostructures of semiconducting and insulating oxides

Research Project

Project/Area Number 25286056
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionTokyo Institute of Technology

Principal Investigator

SUSAKI Tomofumi  東京工業大学, 応用セラミックス研究所, 准教授 (20332265)

Co-Investigator(Kenkyū-buntansha) YANAGI Hiroshi  山梨大学, 大学院総合研究部, 教授 (30361794)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2015: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
Fiscal Year 2013: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Keywords仕事関数 / 表面 / 界面 / 電子デバイス / 酸化物エレクトロニクス / 荷電欠陥 / 薄膜成長 / デバイス / 触媒 / パルスレーザー堆積
Outline of Final Research Achievements

Work function plays a key role in any types of surface and interface functionalities which involve an electron transfer across the solid surface or interface. Surface work function is one of the most important parameters in catalytic functionalities and in efficient electron emitters. In addition, work function is fundamental to design diode junctions and metal-oxide-insulator (MOS) field-effect transistors (FETs). We have controlled work function in the form of heterostructures by using chemically stable oxides and nitrides. Specifically, by introducing charged defects in magnesium oxide thin films we have realized the work function as low as 2 eV.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (26 results)

All 2016 2015 2014 2013 Other

All Int'l Joint Research (1 results) Journal Article (8 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 7 results,  Open Access: 1 results,  Acknowledgement Compliant: 3 results) Presentation (14 results) (of which Int'l Joint Research: 5 results,  Invited: 3 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] ヨーク大学(英国)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Atomic and electronic structure of twin growth defects in magnetite2016

    • Author(s)
      Daniel Gilks, Zlatko Nedelkoski, Leonardo Lari, Balati Kuerbanjiang, Kosuke Matsuzaki, Tomofumi Susaki, Demie Kepaptsoglou, Quentin Ramasse, Richard Evans, Keith McKenna, Vlado K. Lazarov
    • Journal Title

      Scientific Reports

      Volume: 6:20943 Issue: 1 Pages: 20943-20943

    • DOI

      10.1038/srep20943

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] N-type conduction in SnS by anion substitution with Cl2015

    • Author(s)
      H. Yanagi, Y. Iguchi, T. Sugiyama, T. Kamiya and H. Hosono
    • Journal Title

      Appl. Phys. Express

      Volume: 9 Issue: 5 Pages: 051201-051201

    • DOI

      10.7567/apex.9.051201

    • NAID

      210000137871

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atomic study of Fe3O4/SrTiO3 Interface2015

    • Author(s)
      D. Gilks, D.M. Kepaptsoglou, K. McKenna, L. Lari, Q.M. Ramasse, K. Matsuzaki, T. Susaki, V.K. Lazarov
    • Journal Title

      Microsc. Microanal.

      Volume: 21 (Suppl 3) Issue: S3 Pages: 1299-1300

    • DOI

      10.1017/s143192761500728x

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Examination of interfacial charge transfer in photocatalysis using patterned CuO thin film deposited on TiO22015

    • Author(s)
      K. Osako, K. Matsuzaki, H. Hosono, G. Yin, D. Atarashi, E. Sakai, T. Susaki, and M. Miyauchi
    • Journal Title

      APL Materials

      Volume: 3 Issue: 10 Pages: 104409-104409

    • DOI

      10.1063/1.4926934

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Work function modulation in MgO/Nb:SrTiO3 by utilizing highly nonequilibrium thin film growth2014

    • Author(s)
      T. Susaki, N. Shigaki, K. Matsuzaki, and H. Hosono,
    • Journal Title

      Phys. Rev. B

      Volume: 90 Issue: 3

    • DOI

      10.1103/physrevb.90.035453

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Controlled bipolar doping in Cu3N (100) thin films2014

    • Author(s)
      K. Matsuzaki, T. Okazaki, Y.-S. Lee, H. Hosono, and T. Susaki
    • Journal Title

      Appl. Phys. Lett.

      Volume: 105 Issue: 22

    • DOI

      10.1063/1.4903069

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 安定な酸化物で作製した低仕事関数平坦表面2014

    • Author(s)
      須崎友文
    • Journal Title

      工業材料

      Volume: 62 Pages: 40-41

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Control of Surface Work Function by Depositing Insulating Oxide Capping Layers2013

    • Author(s)
      T. Susaki and H. Hosono
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 52 Issue: 11R Pages: 110125-110125

    • DOI

      10.7567/jjap.52.110125

    • NAID

      210000143045

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Post-annealing atmosphere and temperature effects on amorphous Cd-Ga-O thin films2016

    • Author(s)
      C. Sato, Y. Kimura, H. Yanagi
    • Organizer
      E-MRS 2016 Spring Meeting
    • Place of Presentation
      Lille, France
    • Year and Date
      2016-05-03
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アモルファスCd-Ga-Oの電気特性に及ぼすポストアニール効果2016

    • Author(s)
      佐藤千友紀,木村洋太,柳 博
    • Organizer
      日本セラミックス協会 2016年年会
    • Place of Presentation
      早稲田大、東京
    • Year and Date
      2016-03-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] Epitaxial growth of bipolar conducting Cu3N (100) thin films2015

    • Author(s)
      K. Matsuzaki, H. Hosono, T. Susaki
    • Organizer
      EMN 3CG 2015
    • Place of Presentation
      Hong Kong
    • Year and Date
      2015-12-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Hard X-Ray Photoemission Study of LaAlO3/(Nb:)SrTiO32015

    • Author(s)
      T. Susaki, S. Ueda, K. Matsuzaki, T. Kobayashi, Y. Toda, H. Hosono
    • Organizer
      The 9th International Conference on the Science and Technology for Advanced Ceramics (STAC-9)
    • Place of Presentation
      つくば国際会議場、つくば、茨城
    • Year and Date
      2015-10-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Cu3N(100) epitaxial films on SrTiO3(100)2015

    • Author(s)
      A. Maeda, K. Matsuzaki, D. Gilks, B. Kurbanjan, L. Lari, V. K. Lazarov, H. Hosono, T. Susaki
    • Organizer
      The 9th International Conference on the Science and Technology for Advanced Ceramics (STAC-9)
    • Place of Presentation
      つくば国際会議場、つくば、茨城
    • Year and Date
      2015-10-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] LaAlO3/(Nb:)SrTiO3 の硬X線光電子分光:導電性基板 vs 絶縁性基板2015

    • Author(s)
      須崎 友文、上田 茂典、松崎 功佑、小林 敏洋、戸田 喜丈、細野 秀雄
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場・名古屋・愛知
    • Year and Date
      2015-09-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] Controlled bipolar doping in Cu3N (100) films grown by plasma assisted molecular beam epitaxy2015

    • Author(s)
      K. Matsuzaki, T. Okazaki, Y.-S. Lee, D. Gilks, B. Kurbanjan, L. Lari, V. K. Lazarov, H. Hosono, T. Susaki
    • Organizer
      The 2015 E-MRS Spring Meeting
    • Place of Presentation
      Lille, France
    • Year and Date
      2015-05-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 酸化物ヘテロ構造を用いた仕事関数制御2015

    • Author(s)
      須崎友文
    • Organizer
      機能薄膜部会 ナノ構造機能創成専門部会 第 2 回研究会
    • Place of Presentation
      オミクロン ナノテクノロジー ジャパン株式会社 セミナールーム(東京・品川)
    • Year and Date
      2015-01-30
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 窒化銅エピタキシャル薄膜のp/n型伝導制御2014

    • Author(s)
      松崎功佑,細野秀雄,須崎友文
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(北海道・札幌)
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] 室温PLD堆積による MgO/Nb:SrTiO3 の仕事関数変調2014

    • Author(s)
      須崎友文, 紫垣延洋, 松崎功佑,細野秀雄
    • Organizer
      第74回応用物理学会秋季学術講演会
    • Place of Presentation
      北海道大学(北海道・札幌)
    • Year and Date
      2014-09-17
    • Related Report
      2014 Annual Research Report
  • [Presentation] Bipolar conduction in Cu3N epitaxial films grown by molecular beam epitaxy2014

    • Author(s)
      松崎功佑,細野秀雄,須崎友文
    • Organizer
      The Eighth International Conference on the Science and Technology for Advanced Ceramics (STAC8)
    • Place of Presentation
      メルパルク横浜(神奈川・横浜)
    • Year and Date
      2014-06-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Work function control in LaAlO3/SrTiO3 and in MgO/SrTiO32013

    • Author(s)
      Tomofumi Susaki
    • Organizer
      Collaborative Conference on 3D & Materials Research (CC3DMR) 2013
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Controlled work function in MgO films grown by pulsed laser deposition2013

    • Author(s)
      Tomofumi Susaki, Nobuhiro Shigaki, Yasumasa Hamana, Kimitsugu Nakamura, and Hideo Hosono
    • Organizer
      The 7th International Conference on the Science and Technology for Advance Ceramics (STAC-7)
    • Place of Presentation
      Yokohama, Japan
    • Related Report
      2013 Annual Research Report
  • [Presentation] Work function control in oxide thin films2013

    • Author(s)
      Tomofumi Susaki, Nobuhiro Shigaki, Yasumasa Hamana, Kimitsugu Nakamura, and Hideo Hosono
    • Organizer
      The 12th Asia Pacific Physics Conference (APPC12)
    • Place of Presentation
      Makuhari, Japan
    • Related Report
      2013 Annual Research Report
  • [Book] ポストシリコン半導体 - ナノ成膜ダイナミクスと基板・界面効果 -2013

    • Author(s)
      財満鎭明、須崎友文、他
    • Total Pages
      510
    • Publisher
      エヌ・ティー・エス出版
    • Related Report
      2013 Annual Research Report
  • [Remarks] 須崎研究室ページ

    • URL

      http://www.msl.titech.ac.jp/~susaki/

    • Related Report
      2015 Annual Research Report
  • [Patent(Industrial Property Rights)] p型窒化銅半導体薄膜2014

    • Inventor(s)
      松崎功佑,須崎友文,細野秀雄
    • Industrial Property Rights Holder
      松崎功佑,須崎友文,細野秀雄
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-129607
    • Filing Date
      2014-06-24
    • Related Report
      2014 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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