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Fabrication of ZnO Micro-Sphere Whispering-Gallery-Mode Ultraviolet Laser and Their Applications

Research Project

Project/Area Number 25286071
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Optical engineering, Photon science
Research InstitutionKyushu University

Principal Investigator

OKADA TATSUO  九州大学, システム情報科学研究科(研究院, 教授 (90127994)

Co-Investigator(Kenkyū-buntansha) Nakamura Daisuke  九州大学, 大学院システム情報科学研究院, 准教授 (40444864)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥16,120,000 (Direct Cost: ¥12,400,000、Indirect Cost: ¥3,720,000)
Fiscal Year 2015: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2014: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Fiscal Year 2013: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Keywords酸化亜鉛 / ZnO / 微小球 / WGM / p-n接合 / レーザーアブレーション / ドーピング / マイクロキャビティ / ヘテロ接合 / 微小光共振器 / 屈折率センサ / ホトルミネッセンス / ウィスパリングギャラリーモード / 微小共振器
Outline of Final Research Achievements

ZnO micro-spheres were synthesized by laser ablation in air using a Q-switched Nd:YAG laser and a normal-mode Nd:YAG laser, and their optical properties were characterized.
In order to realize p-type ZnO micro-spheres, P-doped ZnO micro-spheres were synthesized. When a heterojunction was made with P-doped ZnO micro-sphere and Al-doped n-type ZnO thin film, apparent rectifying I-V characteristics was observed. In order to control the lasing wavelength of ZnO micro-sphere, Mg doped ZnO micro-spheres were synthesized. When 5 wt% of Mg was doped, the lasing wavelength was 370 nm, which was shorter by 25 nm, compared with 395 nm for non-doped micro-spheres. We have obtained the UV EL emission from p-n junction consisting of Mg-doped ZnO micro-sphere and p-type GaN thin film.
In order to apply ZnO micro-spheres to sensor system, we have investigated the dependence of the lasing wavelength of ZnO WGM laser on the refractive index of the surrounding material experimentally and theoretically.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (33 results)

All 2016 2015 2014 2013

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (25 results)

  • [Journal Article] Optical characterization of ZnO microsphere produced by laser ablation in air2015

    • Author(s)
      D. Nakamura, N. Tetsuyama, T. Shimogaki, Y. Sato, Y. Mizokami, M. Higashihata, T. Okada
    • Journal Title

      Journal of Laser Micro Nanoengineering

      Volume: 10 Pages: 162-165

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultraviolet lasing action in aligned ZnO nanowall2015

    • Author(s)
      K. Harada, S. Nakao, M. Takahashi, M. Higashihata, H. Ikenoue, D. Nakamura, Y. Nakata, T. Okada
    • Journal Title

      Applied Physics B

      Volume: 119 Pages: 469-473

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Laser doping of Sb into ZnO nanowire in the Sb nanoparticle-dispersed liquid2015

    • Author(s)
      H. Kawahara, T. Shimogaki, M. Higashihata, H. Ikenoue, D. Nakamura, T. Okada
    • Journal Title

      Applied Physics B

      Volume: 119 Pages: 463-467

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of potassium permanganate on the anisotropic growth and enhanced UV emission of ZnO nanostructures using hydrothermal process for optoelectronic applications2015

    • Author(s)
      T. Dixit, A. Bilgaiyan, I. A. Palani, D. Nakamura, T. Okada, C. Singh
    • Journal Title

      J. of Sol-Gel Sciences and Technology

      Volume: 75 Pages: 693-702

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of laser irradiation on the properties of ZnO buffer layers and its application to selective growth of ZnO nano/microcrystals2015

    • Author(s)
      T. Shimogaki, H. Kawahara, S. Nakao, K. Harada, M. Higashihata, H. Ikenoue, Y. Nakata, D. Nakamura, T. Okada
    • Journal Title

      Journal of Laser Micro Nanoengineering

      Volume: 10 Pages: 259-262

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 大気中レーザアブレーションによるZnO マイクロ結晶球の作製2015

    • Author(s)
      中村 大輔, 田中 稔伸, 池渕 達也, 植山 健史, 東畠 三洋, 岡田 龍雄
    • Journal Title

      電気学会論文誌C

      Volume: 135 Pages: 1085-1089

    • NAID

      130005096939

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ultraviolet electroluminescence from hetero p-n junction between a single ZnO microsphere and p-GaN thin film2014

    • Author(s)
      Norihiro Tetsuyama, Koshi Fusazaki, Yasuaki Mizokami, Tetsuya Shimogaki, Mitsuhiro Higashihata, Daisuke Nakamura, Tatsuo Okada
    • Journal Title

      Optics Express

      Volume: 22 Issue: 8 Pages: 10026-10031

    • DOI

      10.1364/oe.22.010026

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Various Sized ZnO Microspheres by Laser Ablation and Their Lasing Characteristics2013

    • Author(s)
      D. Nakamura, T. Shimogaki, K. Okazaki, M. Higashihata, H. Ikenoue, T. Okada
    • Journal Title

      JOURNAL OF LASER MICRO NANOENGINEERING

      Volume: 8 Pages: 296-299

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 大気中レーザーアブレーションで作製したSbドープZnOマイクロスフィアの特性評価2016

    • Author(s)
      永嵜 史明, 下垣 哲也, 池渕 達也, 植山 健史, 田中 稔伸, 藤原 優輝, 東畠 三洋, 中村 大輔, 岡田 龍雄
    • Organizer
      応用物理学会春季学術講演会
    • Place of Presentation
      東京都
    • Year and Date
      2016-03-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] 燐ドープZnOマイクロ結晶球の構造および発光特性評価2016

    • Author(s)
      藤原 優輝, 池渕 達也, 植山 健史, 田中 稔伸, 永嵜 史明, 東畠 三洋, 中村 大輔, 岡田 龍雄
    • Organizer
      応用物理学会春季学術講演会
    • Place of Presentation
      東京都
    • Year and Date
      2016-03-20
    • Related Report
      2015 Annual Research Report
  • [Presentation] レーザアブレーションによるZnOナノ・マイクロ結晶球生成のダイナミクス2016

    • Author(s)
      中村 大輔, 下垣 哲也, 藤原 優輝, 永嵜 史明, 高尾 修平, 田崎 涼平, 東畠 三洋, 池上 浩, 岡田 龍雄
    • Organizer
      レーザー学会第489回研究会
    • Place of Presentation
      石垣市
    • Year and Date
      2016-03-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] Fabrication and bandgap engineering of doped ZnO microspheres by simple laser ablation in air2016

    • Author(s)
      Daisuke Nakamura, Tetsuya Shimogaki, Toshinobu Tanaka, Fumiaki Nagasaki, Yuki Fujiwara, Mitsuhiro Higashihata, Tatsuo Okada
    • Organizer
      SPIE Photonics West
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2016-02-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] Optical and structural properties of P-doped ZnO microsphere synthesized by pulsed laser ablation2016

    • Author(s)
      Yuki Fujiwara, Tatsuya Ikebuchi, Takeshi Ueyama, Toshinobu Tanaka, Fumiaki Nagasaki, Mitsuhiro Higashihata, Daisuke Nakamura, Tatsuo Okada
    • Organizer
      SPIE Photonics West
    • Place of Presentation
      San Francisco, USA
    • Year and Date
      2016-02-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 大気中レーザーアブレーションによるZnOマイクロ結晶球の合成2015

    • Author(s)
      中村 大輔, 下垣 哲也, 田中 稔伸, 永嵜 史明, 藤原 優輝, 東畠 三洋, 岡田 龍雄
    • Organizer
      レーザー学会第487回研究会
    • Place of Presentation
      松江市
    • Year and Date
      2015-12-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] P ドープ ZnO マイクロスフィアの作製と構造・発光特性評価2015

    • Author(s)
      藤原 優輝, 池渕 達也, 植山 健史, 田中 稔伸, 永嵜 史明, 東畠 三洋, 中村 大輔, 岡田 龍雄
    • Organizer
      応用物理学会九州支部学術講演会
    • Place of Presentation
      那覇市
    • Year and Date
      2015-12-05
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ultraviolet lasing from spherical ZnO microcrystal produced by laser ablation in air2015

    • Author(s)
      Daisuke Nakamura, Toshinobu Tanaka, Tatsuya Ikebuchi, Takeshi Ueyama, Fumiaki Nagasaki, Mitsuhiro Higashihata, Hiroshi Ikenoue, Tatsuo Okada
    • Organizer
      20th Microoptics Conference
    • Place of Presentation
      福岡市
    • Year and Date
      2015-10-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis and characterization of Sb doped ZnO microspheres by pulsed laser ablation2015

    • Author(s)
      Fumiaki Nagasaki, Toshinobu Tanaka, Tatsuya Ikebuchi, Takeshi Ueyama, Yuki Fujiwara, Tetsuya Shimogaki, Mitsuhiro Higashihata, Daisuke Nakamura, Tatsuo Okada
    • Organizer
      20th Microoptics Conference
    • Place of Presentation
      福岡市
    • Year and Date
      2015-10-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] PドープZnOマイクロスフィアの作製と特性評価2015

    • Author(s)
      藤原 優輝, 池渕 達也, 植山 健史, 田中 稔伸, 永嵜 史明, 東畠三洋, 中村 大輔, 岡田 龍雄
    • Organizer
      電気関係学会九州支部連合大会
    • Place of Presentation
      福岡市
    • Year and Date
      2015-09-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] MgドープによるZnOマイクロ球の紫外WGMレーザー発振の短波長化2015

    • Author(s)
      中村 大輔, 田中 稔伸, 永嵜 史明, 藤原 優輝, 東畠 三洋, 池上 浩, 岡田 龍雄
    • Organizer
      応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋市
    • Year and Date
      2015-09-14
    • Related Report
      2015 Annual Research Report
  • [Presentation] レーザーを用いた不純物添加ZnOマイクロ結晶球の作製2015

    • Author(s)
      中村 大輔, 下垣 哲也, 田中 稔伸, 永嵜 史明, 藤原 優輝, 東畠 三洋, 岡田 龍雄
    • Organizer
      レーザー学会第480回研究会
    • Place of Presentation
      北九州市
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis of Mg-doped ZnO microspheres by laser ablation in air and their crystal and photoluminescence properties2015

    • Author(s)
      Toshinobu Tanaka, Fumiaki Nagasaki, Tetsuya Shimogaki, Mitsuhiro Higashihata, Daisuke Nakamura, Hiroshi Ikenoue, Tatsuo Okada
    • Organizer
      International Conference on Laser Ablation
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      2015-09-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis of ZnO Micro-Spheres by Laser Ablation and Their Application to Refractive Sensor2015

    • Author(s)
      Takeshi Ueyama, Yuta Satou, Mitsuhiro Higashihata, Daisuke Nakamura, Hiroshi Ikenoue, Tatsuo Okada
    • Organizer
      International Conference on Laser Ablation
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      2015-09-01
    • Related Report
      2015 Annual Research Report
  • [Presentation] Surface refractive index dependence on the oscillation peak of photoexcited ZnO microspheres2015

    • Author(s)
      Takeshi Ueyama, Yuta Sato, Mitsuhiro Higashihata, Daisuke Nakamura, Hiroshi Ikenoue, Tatsuo Okada
    • Organizer
      7th International Congress on Laser Advanced Materials Processing
    • Place of Presentation
      福岡市
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] Ultraviolet lasing from semiconductor droplet fabricated by laser ablation2015

    • Author(s)
      Daisuke Nakamura, Toshinobu Tanaka, Takeshi Ueyama, Tatsuya Ikebuchi, Yuta Sato, Mitsuhiro Higashihata, Hiroshi Ikenoue, Tatsuo Okada
    • Organizer
      EMN meeting on droplets
    • Place of Presentation
      Phuket, Thailand
    • Year and Date
      2015-05-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 光励起ZnOマイクロ球の紫外レーザー発振における周囲媒質の影響2015

    • Author(s)
      植山 健史,佐藤 雄太,東畠 三洋,中村 大輔,池上 浩,岡田 龍雄
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川県平塚市
    • Year and Date
      2015-03-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] 大気中レーザーアブレーションによるドープZnOマイクロ球の作製2015

    • Author(s)
      田中 稔伸, 永嵜 史明, 藤原 優輝, 東畠 三洋, 中村 大輔, 岡田 龍雄
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      神奈川県平塚市
    • Year and Date
      2015-03-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis of Sb-doped ZnO microspheres by pulsed laser ablation and their photoluminescence properties2015

    • Author(s)
      T. Tanaka, T. Shimogaki, N. Nagasaki, M. Higashihata, D. Nakamura, H. Ikenoue and T. Okada
    • Organizer
      SPIE PHOTONICS WEST 2015
    • Place of Presentation
      アメリカ, サンフランシスコ市
    • Year and Date
      2015-02-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] SbドープZnOマイクロスフィアの作製とアニール処理による発光特性変化2014

    • Author(s)
      田中 稔伸, 下垣 哲也, 中村 大輔, 東畠 三洋, 岡田 龍雄
    • Organizer
      平成26年度(第67回)電気・情報関係学会九州支部連合大会
    • Place of Presentation
      鹿児島市
    • Year and Date
      2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 光励起ZnO微小球のレーザー発振における表面屈折率依存性2014

    • Author(s)
      植山 健史,佐藤 雄太,東畠 三洋,中村 大輔,池上 浩,岡田 龍雄
    • Organizer
      平成26年度(第67回)電気・情報関係学会九州支部連合大会
    • Place of Presentation
      鹿児島市
    • Year and Date
      2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 大気中レーザーアブレーションにより作製したZnOマイクロ単結晶球の発光特性2014

    • Author(s)
      中村 大輔,佐藤 雄太,池渕 達也,田中 稔伸,植山 健史,東畠 三洋,池上 浩,岡田 龍雄
    • Organizer
      レーザー学会第465回研究会
    • Place of Presentation
      鹿児島県指宿市
    • Year and Date
      2014-09-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] Optical characterization of ZnO microsphere produced by laser ablation in air2014

    • Author(s)
      D. Nakamura, N. Tetsuyama, T. Shimogaki, Y. Sato, Y. Mizokami, M. Higashihata, T. Okada
    • Organizer
      Laser Precision Microfabrication 2014
    • Place of Presentation
      リトアニア ビリニュス
    • Year and Date
      2014-06-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Emission characteristics of electrically- and optically-pumped single ZnO micro-sperical crystal2014

    • Author(s)
      D. Nakamura, T. Shimogaki, K. Fusazaki, Y. Mizokami, M. Higashihata, H. Ikenoue, T. Okada
    • Organizer
      SPIE Photonic West
    • Place of Presentation
      サンフランシスココンベンションセンター(USA)
    • Related Report
      2013 Annual Research Report
  • [Presentation] Fabrication of spherical semiconductor crystals by simple laser ablation method2013

    • Author(s)
      T. Shimogaki, K. Fusazaki, Y. Mizokami, N. Tetsuyama, M. Higashihata, H. Ikenoue, D. Nakamura, T. Okada
    • Organizer
      12th International Conference on laser Ablation
    • Place of Presentation
      Ischia(Italy)
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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