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Cavity polariton using hybrid perovskite materials

Research Project

Project/Area Number 25286072
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Optical engineering, Photon science
Research InstitutionSophia University

Principal Investigator

EMA Kazuhiro  上智大学, 理工学部, 教授 (40194021)

Co-Investigator(Kenkyū-buntansha) ERA Masanao  佐賀大学, 工学系研究科, 准教授 (30191927)
Ohtsuki Tomi  上智大学, 理工学部, 教授 (50201976)
Co-Investigator(Renkei-kenkyūsha) KUNUGITA Hideyuki  上智大学, 理工学部, 助教 (50296886)
TAKADA Noriyuki  産業技術総合研究所, 研究員 (70357359)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2015: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2013: ¥8,450,000 (Direct Cost: ¥6,500,000、Indirect Cost: ¥1,950,000)
Keywordsハイブリッド物質 / マイクロキャビティ / ポラリトン / 無機有機ハイブリッド / 共振器ポラリトン / 励起子 / 量子井戸 / 無機有機ハイブリッド材料 / LB膜
Outline of Final Research Achievements

The purpose of this study is to achieve the polariton laser at room temperature using the micro-cavity containing organic-inorganic hybrid perovskite materials which have extremely large exciton binding energies. We have measured the strong exciton-cavity coupling with a large vacuum Rabi splitting of 146 meV. However, we have not achieved an establishment of the polariton laser. We are now improving the cavity structure to achieve the polariton laser.
We have also studied the excitonic properties of three-dimensional hybrid perovskite materials. We have confirmed that the excitons exist even at room temperature, and succeeded in the estimation of the exciton binding energy to be 20 ~ 40 meV.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (28 results)

All 2016 2015 2014 2013 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results,  Open Access: 1 results,  Acknowledgement Compliant: 3 results) Presentation (17 results) (of which Int'l Joint Research: 4 results,  Invited: 7 results) Book (2 results) Remarks (1 results)

  • [Journal Article] Exciton-exciton scattering in perovskite CH3NH3PbBr3 single crystal2016

    • Author(s)
      Hideyuki Kunugita, Yuki Kiyota, Yosuke Udagawa, Yuko Takeoka, Yuiga Nakamura, Junro Sano, Tomonori Matsushita, Takashi Kondo, and Kazuhiro Ema
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 55

    • NAID

      210000146576

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Lead-halide based layered preovskite organic-inorganic superlattice films having carbazole choromophore as organic layer; hole mobility and film morphology2016

    • Author(s)
      Masanao Era, Takeshi Yasuda, Kento Mori, Norio Tomotsu, Naoki Kawano, Masanori Koshimizu, and Keisuke Asai
    • Journal Title

      J. Nanosci. and Nanothec.

      Volume: in press

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Excitonic Feature in Hybrid Perovskite CH3NH3PbBr3 Single Crystals2015

    • Author(s)
      Hideyuki Kunugita, Tsubasa Hashimoto, Yuki Kiyota, Yosuke Udagawa, Yuko Takeoka, Yuiga Nakamura, Junro Sano, Tomonori Matsushita, Takashi Kondo, Tsutomu Miyasaka, and Kazuhiro Ema
    • Journal Title

      Chem. Lett.

      Volume: 44 Issue: 6 Pages: 852-854

    • DOI

      10.1246/cl.150204

    • NAID

      130005074610

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Excitonic Feature in Hybrid Perovskite CH3NH3PbBr3 Single Crystals2015

    • Author(s)
      Hideyuki Kunugita, Tsubasa Hashimoto, Yuki Kiyota, Yosuke Udagawa, Yuko Takeoka, Yuiga Nakamura, Junro Sano, Tomonori Matsushita, Takashi Kondo, Tsutomu Miyasaka, and Kazuhiro Ema
    • Journal Title

      Chem. Lett.

      Volume: 44

    • NAID

      130005074610

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Enhancement of exaction emission in lead-halide based layered perovskite organic-inorganic superlattice films by cation mixing2015

    • Author(s)
      Masanao Era, Yumeko Komatsu, and Naotaka Sakamoto
    • Journal Title

      J. Nanosci.and Nanotech

      Volume: 15

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lead-halide based layered preovskite organic-inorganic superlattice films having carbazole choromophore as organic layer; hole mobility and film morphology2015

    • Author(s)
      Masanao Era, Takeshi Yasuda, Kento Mori, Norio Tomotsu, Naoki Kawano, Masanori Koshimizu, and Keisuke Asai
    • Journal Title

      J. Nanosci. and Nanotech.

      Volume: 15

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Cyclodextrins on Intramolecular Photoinduced Electron Transfer in a Boronic Acid Fluorophore2014

    • Author(s)
      H. Kano, D. Tanoue, H. Shimaoka, K. Katano, T. Hashimoto, H. Kunugita, S. Nanbu, T. Hayashita, and K. Ema
    • Journal Title

      Analytical Sciences

      Volume: 30 Issue: 6 Pages: 643-648

    • DOI

      10.2116/analsci.30.643

    • NAID

      130004442300

    • ISSN
      0910-6340, 1348-2246
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optimization of Langmuir-Blodgett Film Formation for Organic-Inorganic Layer Perovskite by Squeeze out Method2013

    • Author(s)
      Koichi Souda, Koichi Sakaguchi, and Masanao Era
    • Journal Title

      IEICE Transactions on Electronics

      Volume: E96.C Issue: 3 Pages: 372-373

    • DOI

      10.1587/transele.E96.C.372

    • NAID

      10031167366

    • ISSN
      0916-8524, 1745-1353
    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Exciton and bandgap energies of hybrid perovskite CH3NH3PbI32015

    • Author(s)
      Y. Nakamura, J. Sano, T. Matsushita, Y. Kiyota, Y. Udagawa, H. Kunugita, K. Ema, and T. Kondo
    • Organizer
      2015 International Conference on Solid State Devices and Materials (SSDM 2015)
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2015-09-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Excitonic Properties and Carrier Dynamics of CH3NH3PbBr3 Single Crystals2015

    • Author(s)
      Yuki Kiyota, Yosuke Udagawa, Hideyuki Kunugita, Yuko Takeoka, Yuiga Nakamura, Tomonori Matsushita, Takashi Kondo, Tsutomu Miyasaka, and Kazuhiro Ema
    • Organizer
      1st International Conference on Perovskite Solar Cells and Optoelectronics (PSCO-2015)
    • Place of Presentation
      Lausanne, Switzerland
    • Year and Date
      2015-09-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of optically high quality thin films of PbBr-based layered perovskite by using Langmuir-Blodgett technique and their application to cavity polariton laser2015

    • Author(s)
      Masanao Era, Hiroshi Era, Kazuhiro Ema and Noriyuki Takada
    • Organizer
      1st International Conference on Perovskite Solar Cells and Optoelectronics (PSCO-2015)
    • Place of Presentation
      Lausanne, Switzerland
    • Year and Date
      2015-09-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機無機ペロブスカイト化合物の励起子物性2015

    • Author(s)
      清田祐貴, 宇田川洋祐, 中村唯我, 佐野惇郎, 松下智紀, 欅田英之, 竹岡裕子, 近藤高志, 江馬一弘
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学千里山キャンパス
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] ハロゲン化鉛ペロブスカイト型半導体CH3NH3PbX3の電子状態と励起子2015

    • Author(s)
      近藤高志, 江馬一弘
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 有機無機ペロブスカイトの光電子物性と光デバイスへの応用2015

    • Author(s)
      江良正直
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Langmuir-Blodgett法によるハロゲン化鉛系ペロブスカイト薄膜の作製、構造及び キャビティポラリトンレーザへの応用2015

    • Author(s)
      江良洋、高田幸徳、江良正直
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高い励起子発光効率を有するヨウ化鉛系有機無機ペロブスカイトの基礎光物性2015

    • Author(s)
      江良正直,江馬一弘,フィリップス・リチャード
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場(名古屋市)
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Optical properties of PbI-based layered perovskite having high photoluminescence efficiency2015

    • Author(s)
      Masaano Era, Yasunori Yamada, Kazuhiro Ema, Richard T. Phillips, Kento Mori, and Norio Tomotsu
    • Organizer
      8th International Conference on Molecular Electronics and Bioelectronics
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2015-06-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機無機ペロブスカイト型材料の光物性と新機能2015

    • Author(s)
      江馬一弘
    • Organizer
      2015 日本化学会 ATP プログラムT1A「太陽エネルギー変換の新技術と展望」
    • Place of Presentation
      日本大学習志野キャンパス
    • Year and Date
      2015-03-28
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ヨウ化錫系有機無機ペロブスカイト蒸着膜の導電率その場測定2015

    • Author(s)
      江良正直
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2015-03-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機無機ペロブスカイト薄膜の作製法と基礎物性2015

    • Author(s)
      江良正直
    • Organizer
      光機能材料研究会第51回講演会
    • Place of Presentation
      東京大学
    • Year and Date
      2015-03-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Optical and excitonic properties in lead-halide-based perovskite-type crystals CH3NH3PbBr32015

    • Author(s)
      T. Hashimoto, Y. Kiyota, Y. Udagawa, R. Ishii, Y. Kagaya, H. Kunugita, Y. Takeoka, K. Ema, Y. Nakamura, J. Sano, T. Matsushita, T. Kondo, and T. Miyasaka
    • Organizer
      Fourth International Conference on Multifunctional, Hybrid and Nanomaterials (Hybrid Materials 2015)
    • Place of Presentation
      Sitges, Spain
    • Year and Date
      2015-03-09 – 2015-03-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機無機ペロブスカイトの作製法と光物性2014

    • Author(s)
      江良正直
    • Organizer
      光機能材料研究会第49回講演会
    • Place of Presentation
      東京大学
    • Year and Date
      2014-09-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Organic-Inorganic Perovskites; Their Basic Properties and Recent Topics2014

    • Author(s)
      Masanao Era
    • Organizer
      International Kick-off Symposium for Energy Materials
    • Place of Presentation
      Kumamoto University
    • Year and Date
      2014-06-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 有機無機ハイブリッド材料の光学特性と薄膜作製技術2014

    • Author(s)
      江馬一弘,竹岡祐子
    • Organizer
      光機能材料研究会・第48回講演会「ぺロブスカイト薄膜太陽電池の材料開発と最新技術」
    • Place of Presentation
      東京大学先端科学技術研究センター
    • Year and Date
      2014-05-23
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Fabrication and Optical Properties of Organic-inorganic Nanohybrids based on Self-organizing Nature of Lead Halide-based Layered Perovskites2013

    • Author(s)
      Masanao Era, Koichi Souda, Yu Shironita and Koichi Sakaguchi
    • Organizer
      26th International Microprocesses and Nanotechnology Conference
    • Place of Presentation
      Sapporo, Japan
    • Related Report
      2013 Annual Research Report
  • [Book] 「ペロブスカイト薄膜太陽電池の開発と最新技術」第2編第4章「有機無機ハイブリッドペロブスカイト材料の光学特性」2014

    • Author(s)
      江馬一弘
    • Total Pages
      215
    • Publisher
      技術教育出版社
    • Related Report
      2014 Annual Research Report
  • [Book] 光とは何か2014

    • Author(s)
      江馬一弘
    • Total Pages
      235
    • Publisher
      宝島社新書
    • Related Report
      2014 Annual Research Report
  • [Remarks] 江馬研ホームページ

    • URL

      http://soliton.ph.sophia.ac.jp/EmaLabWeb/top.html

    • Related Report
      2014 Annual Research Report

URL: 

Published: 2013-05-21   Modified: 2019-07-29  

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