Electron-state Control of Aromatic Compounds Containing Heavier Group 14 Elements by Substituent introduction and Element Substitution

• Project/Area Number: 25288021
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Organic chemistry
• Research Institution: Kyoto University
• Principal Investigator: Tokitoh Norihiro 京都大学, 化学研究所, 教授 (90197864)
• Project Period (FY): 2013-04-01 – 2016-03-31
• Project Status: Completed (Fiscal Year 2015)
• Budget Amount: ¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000); Fiscal Year 2015: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000); Fiscal Year 2014: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000); Fiscal Year 2013: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
• Keywords: 有機元素化学 / スズ / ゲルマニウム / 芳香族化合物 / 電子受容性物質

Outline of Final Research Achievements

We have succeeded in the synthesis of a series of germanium- or tin-containing aromatic compounds and revealed their properties systematically. The reduction of germabenzenes afforded the germanium analogue of phenyl anion.

Research Products

• [Journal Article] Reactions of Li/Cl Phosphinidenoid Complexes with 1,3,4,5-Tetramethylimidazol-2-ylidene: A New Route to N-Heterocyclic Carbene Adducts of Terminal Phosphinidene Complexes and an Unprecedented Transformation of an Oxaphosphirane Complex (2016)
  • Author(s): Klein, M.; Schnakenburg, G.; Espinosa Ferao, A.; Tokitoh, N.; Streubel, R.
  • Journal Title: European Journal of Inorganic Chemistry Volume: 2016 Issue: 5 Pages: 685-690
  • DOI: 10.1002/ejic.201500959
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Selenium-Substituted Phosphaalkenes Obtained through 1,2-Elimination of Chlorosilanes from Selenenylchlorophosphines Obtained through 1,2-Elimination of Chlorosilanes (2016)
  • Author(s): T. Sasamori, J. M. V. Franco, J.-D. Guo, K. Sugamata, S. Nagase, R. Streubel, N. Tokitoh
  • Journal Title: Eur. J. Inorg. Chem. Volume: 2016 Issue: 5 Pages: 678-684
  • DOI: 10.1002/ejic.201500989
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Synthesis and Structure of Lewis-Base-Free Phosphinoalumane Derivatives (2016)
  • Author(s): Agou, T.; Ikeda, S.; Sasamori, T.; Tokitoh, N.
  • Journal Title: European Journal of Inorganic Chemistry Volume: 2016 Issue: 5 Pages: 623-627
  • DOI: 10.1002/ejic.201501141
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis of 1,2-Dialkynyldisilanes Incorporated in 10-Membered-ring System (2015)
  • Author(s): Mizuhata, Y.; Egawa, Y.; Sasamori, T.; Tokitoh, N.
  • Journal Title: HETEROCYCLES Volume: 90 Issue: 2 Pages: 1111-1123
  • DOI: 10.3987/com-14-s(k)81
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Reaction of a Diaryldigermyne with Ethylene (2015)
  • Author(s): T. Sasamori, T. Sugahara, T. Agou, K. Sugamata, J.-D. Guo, S. Nagase, N. Tokitoh
  • Journal Title: Chem. Sci. Volume: 6 Issue: 10 Pages: 5526-5530
  • DOI: 10.1039/c5sc01266j
  • NAID: 120005753892
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis and Structures of a Stable Gallole Free of Lewis Base Coordination and Its Dianion (2015)
  • Author(s): T. Agou, T. Wasano, T. Sasamori, N. Tokitoh
  • Journal Title: Journal of Physical Organic Chemistry Volume: 28 Issue: 2 Pages: 104-107
  • DOI: 10.1002/poc.3344
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Oxidation of an Allene Compound Bearing 1,8-Dichloroacridene Moieties and Photolysis of the Halogenated Allene Compound for the Generation of Triplet Carbenes (2015)
  • Author(s): S.-i. Fuku-en, K. Furukawa, T. Sasamori, N. Tokitoh, M. Abe, Y. Yamamoto
  • Journal Title: J. Phys. Org. Chem Volume: 28 Issue: 2 Pages: 79-87
  • DOI: 10.1002/poc.3398
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Unexpected photochemical reactions of 2-aryl-2-ethynyltrisilane derivative (2015)
  • Author(s): Yasunobu Egawa, Yoshiyuki Mizuhata, Takahiro Sasamori, Norihiro Tokitoh
  • Journal Title: Main Group Metal Chemistry Volume: 38 Issue: 1-2 Pages: 51-55
  • DOI: 10.1515/mgmc-2014-0042
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis, Photochemical Properties, and Cytotoxicities of 2H-Naphtho[1,2-b]pyran and Its Photodimers (2015)
  • Author(s): Ota, M.; Sasamori, T.; Tokitoh, N.; Onodera, T.; Mizushina, Y.; Kuramochi, K.; Tsubaki, K.
  • Journal Title: The Journal of Organic Chemistry Volume: 80 Issue: 11 Pages: 5687-5695
  • DOI: 10.1021/acs.joc.5b00645
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Synthesis and Characterization of a 1,2-Digermabenzene (2015)
  • Author(s): T. Sasamori, T. Sugahara, T. Agou, J.-D. Guo, S. Nagase, R. Streubel, and N. Tokitoh
  • Journal Title: Organometallics Volume: 34 Issue: 11 Pages: 2106-2109
  • DOI: 10.1021/om501204u
  • Description: 印刷中
  • Peer Reviewed
• [Journal Article] Sulfurization of 4,5,6-Triphospha[3]Radialene (2015)
  • Author(s): Miyake, H.; Sasamori, T.; Tokitoh, N.
  • Journal Title: Phosphorus, Sulfur, and Silicon and the Related Elements Volume: 190 Issue: 8 Pages: 1247-1250
  • DOI: 10.1080/10426507.2014.991828
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Ring Expansion to 1-Bromo-1-alumacyclonona-2,4,6,8-tetraene by Insertion of Two Alkyne Molecules into the Al-C Bonds (2015)
  • Author(s): Agou, T.; Wasano, T.; Sasamori, T.; Guo, J.; Nagase, S.; Tokitoh, N.
  • Journal Title: Angewandte Chemie International Edition Volume: 54 Issue: 33 Pages: 9568-9571
  • DOI: 10.1002/anie.201504468
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Encapsulating Inorganic Acetylene, HBNH, Using Flanking Coordinative Interactions (2015)
  • Author(s): Swarnakar, A. K.; Hering-Junghans, C.; Nagata, K.; Ferguson, M. J.; McDonald, R.; Tokitoh, N.; Rivard, E.
  • Journal Title: Angewandte Chemie International Edition Volume: 54 Issue: 36 Pages: 10666-10669
  • DOI: 10.1002/anie.201504867
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Photochemical (E)-(Z) Isomerization of the P=C Double Bond in Triphospha[3]radialene-[M(CO)5] (M = W, Cr) Complexes (2015)
  • Author(s): Sasamori, T.; Hirano, K.; Miyake, H.; Tokitoh, N.
  • Journal Title: Chemistry Letters Volume: 44 Issue: 9 Pages: 1240-1242
  • DOI: 10.1246/cl.150422
  • NAID: 130005096872
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Formation of a Diaminoalkyne Derivative by Dialumane-mediated Homocoupling of t-Butyl Isocyanide (2015)
  • Author(s): Nagata, K.; Agou, T.; Sasamori, T.; Tokitoh, N.
  • Journal Title: Chemistry Letters Volume: 44 Issue: 11 Pages: 1610-1612
  • DOI: 10.1246/cl.150688
  • NAID: 130005108085
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] 5-N-Arylaminothiazoles as Highly Twisted Fluorescent Monocyclic Heterocycles: Synthesis and Characterization (2015)
  • Author(s): Yamaguchi, K.; Murai, T.; Hasegawa, S.; Miwa, Y.; Kutsumizu, S.; Maruyama, T.; Sasamori, T.; Tokitoh, N.
  • Journal Title: The Journal of Organic Chemistry Volume: 80 Issue: 21 Pages: 10742-10756
  • DOI: 10.1021/acs.joc.5b01963
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Syntheses and Structures of Terminal Arylalumylene Complexes (2014)
  • Author(s): 長田浩一、吾郷友宏、時任宣博
  • Journal Title: Angewandte Chemie International Edition Volume: 53 Issue: 15 Pages: 3881-3884
  • DOI: 10.1002/anie.201310559
  • NAID: 120005646490
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis, structure, and reactivity of a 1-bromoalumole (2014)
  • Author(s): 和佐野達也、吾郷友宏、笹森貴裕、時任宣博
  • Journal Title: Chemical Communications Volume: 50 Issue: 60 Pages: 8148-8150
  • DOI: 10.1039/c4cc03470h
  • NAID: 120005621953
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Coordination chemistry of 9-sila- and 9-germa-phenanthrenes ― unique coordination modes in their metallene complexes (2014)
  • Author(s): 水畑吉行、稲村晃司、時任宣博
  • Journal Title: Canadian Journal of Chemistry Volume: 92 Issue: 6 Pages: 441-446
  • DOI: 10.1139/cjc-2013-0501
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Reactions of Diaryldibrormodisilenes with N-Heterocyclic Carbenes: Formation of Formal Bis-NHC Adducts of Silyliumylidene Cations (2014)
  • Author(s): T. Agou, N. Hayakawa, T. Sasamori, T. Matsuo, D. Hashizume, N. Tokitoh
  • Journal Title: Chem. A Eur. J. Volume: 20 Issue: 30 Pages: 9246-9249
  • DOI: 10.1002/chem.201403083
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Structure of Stable Teluradiphosphirane Bearing Bulky Ferrocenyl Ligands (2014)
  • Author(s): 笹森貴裕、鈴木裕子、坂上訓康、三宅秀明、時任宣博
  • Journal Title: Chemistry Letters Volume: 43 Issue: 9 Pages: 1464-1466
  • DOI: 10.1246/cl.140483
  • NAID: 130004427170
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Reactions of Dialumene-Benzene Adduct with Diphenylacetylene: Formation of 3,4-Dialuminacyclobutene and 5,6-Dialuminabicyclo[2.1.1]hex-2-ene Derivatives (2014)
  • Author(s): 吾郷友宏、長田浩一、笹森貴裕、時任宣博
  • Journal Title: Chemistry Asian Journal Volume: 9 Issue: 11 Pages: 3099-3101
  • DOI: 10.1002/asia.201402798
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Bromination of a Stable 1,2-Bis(ferrocenyl)dibismuthene: Synthesis of a 1,2-Dibromodibismuthane Derivative (2014)
  • Author(s): 笹森貴裕、坂上訓康、時任宣博
  • Journal Title: Heteroatom Chemistry Volume: 25 Issue: 5 Pages: 306-312
  • DOI: 10.1002/hc.21154
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Isolation and Structural Characterization of a Lewis Base-free Monolithioferrocene (2014)
  • Author(s): 笹森貴裕、鈴木裕子、時任宣博
  • Journal Title: Organometallics Volume: 33 Issue: 22 Pages: 6696-6699
  • DOI: 10.1021/om500898v
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Syntheses and Structures of Stable 1-Aminoalumole Derivatives (2014)
  • Author(s): 吾郷友宏、和佐野達也、笹森貴裕、時任宣博
  • Journal Title: Organometallics Volume: 33 Issue: 23 Pages: 6963-6966
  • DOI: 10.1021/om501055f
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Unique Synthetic Approach toward a Phosphaalkene: Synthesis of a Selenium-substituted Phosphaalkene with Bulky Substituents (2014)
  • Author(s): 菅又功、笹森貴裕、時任宣博
  • Journal Title: Chem. Lett. Volume: 43 Issue: 1 Pages: 95-96
  • DOI: 10.1246/cl.130862
  • NAID: 130004427087
  • Peer Reviewed
• [Journal Article] 1,2-Bis(ferrocenyl)-Substituted Distibene and Dibismuthene: Sb=Sb and Bi=Bi Units as π Spacers between Two Ferrocenyl Units (2013)
  • Author(s): Sakagami, M.
  • Journal Title: Chem. Asian J. Volume: 8 Issue: 4 Pages: 690-693
  • DOI: 10.1002/asia.201201227
  • Peer Reviewed
• [Journal Article] A New Family of Multiple-Bond Compounds between Heavier Group 14 Elements (2013)
  • Author(s): Sasamori, T.; Tokitoh, N.
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 86 Issue: 9 Pages: 1005-1021
  • DOI: 10.1246/bcsj.20130134
  • NAID: 10031194294
  • Peer Reviewed
• [Journal Article] Synthesis and Structures of an Alumole and its Dianion (2013)
  • Author(s): T. Agou, T. Wasano, P. Jin, S. Nagase, and N. Tokitoh
  • Journal Title: Angew. Chem. Int. Ed. Volume: 52 Issue: 38 Pages: 10031-10034
  • DOI: 10.1002/anie.201304143
  • Peer Reviewed
• [Journal Article] Synthesis of a Dialumene-Benzene Adduct and Its Reactivity as a Synthetic Equivalent of a Dialumene (2013)
  • Author(s): 吾郷友宏, 長田浩一、時任宣博
  • Journal Title: Angew. Chem. Int. Ed. Volume: 52 Issue: 41 Pages: 10818-10821
  • DOI: 10.1002/anie.201305228
  • Peer Reviewed
• [Journal Article] 1,2-Bis(ferrocenyl)dipnictenes : Bimetallic Systems with a Pn=Pn Heavyπ-Spacer (Pn : P, Sb, and Bi) (2013)
  • Author(s): Sakagami, M.; Sasamori, T.; Sakai, H.; Furukawa, Y.; Tokitoh, N
  • Journal Title: Bull. Chem. Soc. Jpn Volume: 86 Issue: 10 Pages: 1132-1143
  • DOI: 10.1246/bcsj.20130174
  • NAID: 10031201269
  • Peer Reviewed
• [Presentation] 高周期典型元素を含む新規なπ電子系の創出とその構造・性質：「重い芳香族」化合物の最近の展開 (2015)
  • Author(s): 時任宣博
  • Organizer: 2015未来分子研究センター特別講演会
  • Place of Presentation: 立教大学、東京都豊島区西池袋
  • Year and Date: 2015-12-05
  • Invited
• [Presentation] Synthesis, Structures, and Properties of Stable 1,2-Disila- and 1,2-Digermabenzenes (2015)
  • Author(s): N. Tokitoh
  • Organizer: The 5th Asian Silicon Symposium (ASiS-5)
  • Place of Presentation: Jeju, Korea
  • Year and Date: 2015-10-18
  • Int'l Joint Research / Invited
• [Presentation] 高周期典型元素を含む新規なπ電子系の創出 (2015)
  • Author(s): 時任宣博
  • Organizer: 第23回触媒化学融合研究センター講演会
  • Place of Presentation: 産業技術総合研究所、茨城県つくば市
  • Year and Date: 2015-08-21
  • Invited
• [Presentation] Synthesis and Properties of Stable Alumole (2015)
  • Author(s): N. Tokitoh, T. Wasano, T. Agou and T. Sasamori
  • Organizer: The 14th International Symposium on Inorganic Ring Systems (IRIS-14)
  • Place of Presentation: Regensburg, Germany
  • Year and Date: 2015-07-26
  • Int'l Joint Research / Invited
• [Presentation] Synthesis and Properties of a Dialumene Featuring a Barrelene-type Scaffold (2015)
  • Author(s): N. Tokitoh, K. Nagata, T. Sasamori and T. Agou
  • Organizer: The 11th International Conference on Heteroatom Chemistry (ICHAC-11)
  • Place of Presentation: Caen, France
  • Year and Date: 2015-06-14
  • Int'l Joint Research / Invited
• [Presentation] 1-アミノアルモール誘導体の合成と構造 (2015)
  • Author(s): 和佐野達也・吾郷友宏・笹森貴裕・時任宣博
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] 安定な1,2-ジゲルマベンゼンの合成と構造 (2015)
  • Author(s): 菅原知紘・笹森貴裕・吾郷友宏・Guo Jing-Dong・永瀬 茂・時任宣博
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] ゲルマフェニルカリウムの合成と性質 (2015)
  • Author(s): 藤森詩織・水畑吉行・笹森貴裕・時任宣博
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] トリホスファ[3]ラジアレンを配位子とした遷移金属錯体の合成 (2015)
  • Author(s): 平野晃基・三宅秀明・笹森貴裕・時任宣博
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] かさ高いアリール基を有するジアルメン-ベンゼン付加体とLewis塩基との反応 (2015)
  • Author(s): 長田浩一・吾郷友宏・笹森貴裕・時任宣博
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] かさ高いフェロセニル基を有するクロロゲルミレンおよびゲルミレノイド類縁体の発生と反応性 (2015)
  • Author(s): 鈴木裕子・笹森貴裕・時任宣博
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-27
• [Presentation] ゲルミル置換ジゲルメンおよびゲルミレノイドの合成と構造 (2015)
  • Author(s): 江川泰暢・水畑吉行・笹森貴裕・時任宣博
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-26
• [Presentation] 安定なゲルマニウムーゲルマニウム三重結合化合物、ジゲルミンとオレフィン類との反応 (2015)
  • Author(s): 笹森貴裕・菅原知紘・菅又 功・吾郷友宏・Guo Jing-Dong・永瀬 茂・時任宣博
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2015-03-26
• [Presentation] New Aspect in the Chemistry of Aromatic Compounds Containing a Tin Atom as a Skeletal Element (2014)
  • Author(s): Mizuhata, Y.; Tokitoh, N.
  • Organizer: 8th Singapore International Chemistry Conference 2014
  • Place of Presentation: National University of Singapore, Singapore
  • Year and Date: 2014-12-16
• [Presentation] かさ高い置換基を有するジアルメン-ベンゼン付加体とアルキン類との反応 (2014)
  • Author(s): 長田浩一・吾郷友宏・笹森貴裕・時任宣博
  • Organizer: 第41回有機典型元素化学討論会
  • Place of Presentation: 山口大学
  • Year and Date: 2014-11-27
• [Presentation] Sulfurization and Coordination Chemistry of4,5,6-Triphopspha[3]radialene (2014)
  • Author(s): Tokitoh, N.; Miyake, H.; Hirano, K.; Sasamori, T.
  • Organizer: The 16th Japan-Korea Joint Symposium on Organometallic and Coordination Chemistry
  • Place of Presentation: Sendai, Japan
  • Year and Date: 2014-10-24
• [Presentation] 良い論文を書こう！ (2014)
  • Author(s): 時任宣博
  • Organizer: 第4回CSJ化学フェスタ
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2014-10-14
  • Invited
• [Presentation] スタンナベンゼンの発生とその単量体ー二量体平衡 (2014)
  • Author(s): 水畑吉行・金里脩平・能田直弥・時任宣博
  • Organizer: 第61回有機金属化学討論会
  • Place of Presentation: 九州大学
  • Year and Date: 2014-09-24
• [Presentation] New Aspects in the Coordination Chemistry of Stannaaromatics (2014)
  • Author(s): Tokitoh, N.
  • Organizer: Sweden-Kyoto Symposium
  • Place of Presentation: Stockholm, Sweden
  • Year and Date: 2014-09-11
  • Invited
• [Presentation] トリホスファ[3]ラジアレン－6 族金属カルボニル錯体の合成・構造・性質 (2014)
  • Author(s): 平野晃基・三宅秀明・笹森貴裕・時任 宣博
  • Organizer: 第25回基礎有機化学討論会
  • Place of Presentation: 東北大学
  • Year and Date: 2014-09-07
• [Presentation] Sulfrization of 4,5,6-Triphospha[3]radialene (2014)
  • Author(s): Tokitoh, N.; Miyake, H.; Sasamori, T.
  • Organizer: The 26th International Symposium on the Organic Chemistry of Sulfur
  • Place of Presentation: Istanbul, Turkey
  • Year and Date: 2014-08-26
• [Presentation] Reactions of Stable Diaryldibromodisilenes with N-Heterocyclic Carbene (2014)
  • Author(s): Tokitoh, N.; Agou, T.; Hayakawa, N.; Sasamori, T.; Matsuo, T.; Hashizume, D.
  • Organizer: The 17th International Symposium on Silicon Chemistry
  • Place of Presentation: Berlin, Germany
  • Year and Date: 2014-08-05
  • Invited
• [Presentation] Synthesis of a Dialumene-Benzene Adduct and Its Reactivity as a Synthetic Equivalent of Low-valent Aluminum Species (2014)
  • Author(s): Tokitoh, N.
  • Organizer: The 4th International Conference on MEXT Project of Integrated Research on Chemical Synthesis & ICOMC 2014 Pre-symposium in Kyoto “Synthetic Approaches to New Chemical Functions”
  • Place of Presentation: Uji, Japan
  • Year and Date: 2014-07-11
• [Presentation] Synthesis and Structure of a Gallole Dianion Bearing a Bulky Aryl Substituent (2014)
  • Author(s): Tokitoh, N.; Agou, T.; Wasano, T.
  • Organizer: The International Symposium on Reactive Intermediates and Unusual Molecules 2014 (ISRIUM2014)
  • Place of Presentation: Hiroshima, Japan
  • Year and Date: 2014-04-06
  • Invited
• [Presentation] New Aspects in the Coordination Chemistry of Stannaaromatics
  • Author(s): Tokitoh, N.; Mizuhata, Y.; Noda, N.
  • Organizer: The 14th International Conference on the Coordination and Organometallic Chemistry of Germanium, Tin and Lead (GTL-14)
  • Place of Presentation: Inverary Resort, Baddeck, Cape Breton Island, Nova Scotia, Canada
• [Presentation] New Approach towards Tellurenyl Cation Species (RTe+): Trapping as 2,5-Dihydrotellurophenium Salts and Their Retro Cylcoaddition
  • Author(s): Tokitoh, N.; Sugamata, K.; Sasamori, T.
  • Organizer: The 12th International Conference on the Chemistry of Selenium and Tellurium (ICCST-12)
  • Place of Presentation: Julian Hodge Lecture Theatre at Cardiff University, Cardiff, Wales, United Kingdom
  • Invited
• [Presentation] 4,5,6-Triphospha[3]radiallene: A New Cross-conjugated System
  • Author(s): Tokitoh, N.; Miyake, H.; Sasamori, T.; Wu, J. I-C.; Schleyer, P. v. R.
  • Organizer: The 15th Asian Chemical Congress
  • Place of Presentation: Resorts World Sentosa, Singapore
• [Presentation] ジアルメン-ベンゼン付加体の合成と反応:ジアルメン等価体としての反応性
  • Author(s): 長田浩一・吾郷友宏・時任宣博
  • Organizer: 第24回基礎有機化学討論会
  • Place of Presentation: 学習院大学目白キャンパス・東京
• [Presentation] 安定なアルモール及びそのジアニオンの合成と性質
  • Author(s): 和佐野達也 ・吾郷友宏・時任宣博
  • Organizer: 第60回有機金属化学討論会
  • Place of Presentation: 学習院大学目白キャンパス・東京
• [Presentation] Recent progress in the chemistry of heavy aromatics
  • Author(s): Tokitoh, N.
  • Organizer: Institute Colloquium & SFB 813 Lecture
  • Place of Presentation: Universitaet Bonn, Bonn, Germany
  • Invited
• [Presentation] Overview of Organic Chemistry at Kyoto University
  • Author(s): Tokitoh, N.
  • Organizer: The 1st Swiss-Kyoto Symposium, Organic Chemistry and Materials Chemistry
  • Place of Presentation: ETH Zuerich, Zuerich, Switzerland
• [Presentation] Triphospha[3]radialene and Its Anionic Species
  • Author(s): Tokitoh, N.; Miyake, H.; Sasamori, T.
  • Organizer: The 1st Swiss-Kyoto Symposium, Organic Chemistry and Materials Chemistry
  • Place of Presentation: ETH Zuerich, Zuerich, Switzerland
• [Presentation] 典型元素多重結合の化学の最近の進歩
  • Author(s): 時任宣博
  • Organizer: 東京工業大学大学院理工学研究科化学専攻講演会
  • Place of Presentation: 東京工業大学大岡山キャンパス・東京
  • Invited
• [Presentation] かさ高い置換基を有するセレン置換ホスフェニウムの合成研究
  • Author(s): 菅又 功・ビラルバフランコホセマヌエル・笹森貴裕・時任宣博
  • Organizer: 第40回有機典型元素化学討論会
  • Place of Presentation: 近畿大学11月ホール・東大阪
• [Presentation] 有機テルラニルジカチオンの創製とその構造
  • Author(s): 佐藤総一・水上真弓・相星光志・福井隆弘・野村琴広・菅又功・笹森貴裕・時任宣博
  • Organizer: 第40回有機典型元素化学討論会
  • Place of Presentation: 近畿大学11月ホール・東大阪
• [Presentation] Recent Progress in Organoelement Chemistry
  • Author(s): Tokitoh, N.
  • Organizer: National Taiwan University-Kyoto University Symposium 2013
  • Place of Presentation: National Taiwan University, Taipei, Taiwan
  • Invited
• [Presentation] 高周期典型元素を含む新規なπ電子系の創出
  • Author(s): 時任宣博
  • Organizer: 第11回京都大学福井謙一記念研究センターシンポジウム
  • Place of Presentation: 京都大学福井謙一記念研究センター・京都
  • Invited
• [Presentation] 複合的な立体保護基の組み合わせを用いたスタンナベンゼン類の合成とその性質
  • Author(s): 金里脩平・水畑吉行・能田直弥・時任宣博
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学・名古屋
• [Presentation] 種々の置換様式を有する1,2-ジアルキニルジシレン類の合成検討
  • Author(s): 江川泰暢・水畑吉行・時任宣博
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学・名古屋
• [Presentation] かさ高いアリール基を有するアルミレン白金錯体の合成と構造
  • Author(s): 長田浩一・吾郷友宏・時任宣博
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学・名古屋
• [Presentation] ハロゲン置換アルモールの合成
  • Author(s): 和佐野達也・吾郷友宏・時任宣博
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学・名古屋
• [Presentation] かさ高い置換基を用いたホスファアルメンの合成検討
  • Author(s): 池田 慎・吾郷友宏・時任宣博
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学・名古屋
• [Presentation] 末端および架橋Tbtチオラート配位子を持つニトロゲナーゼP-クラスター骨格の合成
  • Author(s): 長崎彩華・大木靖弘・時任宣博・笹森貴裕・吾郷友宏・巽 和行
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学・名古屋
• [Presentation] 単結晶X線構造解析に基づく高効率ペロブスカイト太陽電池の作製
  • Author(s): 遠藤 克・若宮淳志・笹森貴裕・時任宣博・村田靖次郎
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学・名古屋
• [Presentation] トリホスファ[3]ラジアレンを配位子とする６族金属錯体の合成と構造
  • Author(s): 三宅秀明・笹森貴裕・時任宣博
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学・名古屋
• [Presentation] 6価有機テルルPh6Teの精密結晶構造解析
  • Author(s): 一瀬 翔・小林 翔・箕浦真生・橋爪大輔・笹森貴裕・時任宣博
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学・名古屋
• [Presentation] 開環重合制御を指向したGe=Ge二重結合架橋[2]フェロセノファン類の合成検討
  • Author(s): 笹森貴裕・宮本 久・時任宣博
  • Organizer: 日本化学会第94春季年会
  • Place of Presentation: 名古屋大学・名古屋
• [Book] 現代ケイ素化学 (2013)
  • Author(s): 水畑吉行・時任宣博
  • Total Pages: 16
  • Publisher: 化学同人
• [Book] 現代ケイ素化学 (2013)
  • Author(s): 笹森貴裕・時任宣博
  • Total Pages: 20
  • Publisher: 化学同人
• [Remarks] 時任研究室
  • URL: http://boc.kuicr.kyoto-u.ac.jp/www/index.html
• [Remarks] 時任研究室
  • URL: http://boc.kuicr.kyoto-u.ac.jp/www/index.html