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Post-Synthesis Modification of Functional Porous Ionic Crystals

Research Project

Project/Area Number 25288025
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

UCHIDA Sayaka  東京大学, 総合文化研究科, 准教授 (10361510)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000)
Fiscal Year 2015: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2014: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2013: ¥11,830,000 (Direct Cost: ¥9,100,000、Indirect Cost: ¥2,730,000)
Keywordsナノ材料 / 複合材料・物性 / 自己組織化
Outline of Final Research Achievements

Ionic crystals are normally non-porous because of the isotropic and long-range Coulomb interactions. However, the use of molecular ions with appropriate elements, charges, sizes, shapes, or ligands enables the formation of pores. Polyoxometalates (POMs) are nano-sized metal-oxide macroanions, and have stimulated research in broad fields of science. Since POMs bear negative charges, they are potentially useful as building blocks of porous crystals in combination with appropriate macrocations. In this work, selective Cs+ uptake from aqueous solutions by an porous ionic crystal, and synthesis of mesoporous ionic crystals and with high proton conductivity and acid catalysis are reported.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (48 results)

All 2016 2015 2014 2013 Other

All Journal Article (12 results) (of which Peer Reviewed: 11 results,  Acknowledgement Compliant: 7 results,  Open Access: 1 results) Presentation (35 results) (of which Int'l Joint Research: 8 results,  Invited: 12 results) Book (1 results)

  • [Journal Article] Reduction-Induced Highly Selective Uptake of Cs+ by an Ionic Crystal based on Silicododecamolybdate2016

    • Author(s)
      S. Seino, R. Kawahara, Y. Ogasawara, N. Mizuno, S. Uchida
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 55 Issue: 12 Pages: 3987-3991

    • DOI

      10.1002/anie.201511633

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Functional Mesoporous Ionic Crystal based on Polyoxometalate2016

    • Author(s)
      R. Kawahara, K. Niinomi, J. N. Kondo, M. Hibino, N. Mizuno, S. Uchida
    • Journal Title

      Dalton Trans.

      Volume: 45 Issue: 7 Pages: 2805-2809

    • DOI

      10.1039/c5dt04556h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Crystalline Polyoxometalate (POM)-Polyethylene Glycol (PEG) Composites Aimed as Non-Humidified Intermediate-Temperature Proton Conductors2016

    • Author(s)
      M. Tsuboi, M. Hibino, N. Mizuno, S. Uchida
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 234 Pages: 9-14

    • DOI

      10.1016/j.jssc.2015.11.030

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] High CO2/CH4 Separation Performance Exhibited at Room Temperature by a Non-porous Ionic Crystal with 3-Methylpyridinium Cation2015

    • Author(s)
      D. Hashimoto, S. Uchida
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 9 Pages: 1179-1181

    • DOI

      10.1246/cl.150423

    • NAID

      130005096869

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Redox-Induced Reversible Uptake-Release of Cations in Porous Ionic Crystals based on Polyoxometalate: Cooperative Migration of Electrons with Alkali Metal Ions2015

    • Author(s)
      R. Kawahara, S. Uchida, N. Mizuno
    • Journal Title

      Chemistry of Materials

      Volume: 27 Issue: 6 Pages: 2092-2099

    • DOI

      10.1021/cm504526z

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Morphology-Controlled Synthesis of Cubic Cesium Hydrogen Silicododecatungstate Crystals2014

    • Author(s)
      S. Uchida, Y. Ogasawara, T. Maruichi, A. Kumamoto, Y. Ikuhara, T. Yamada, H. Kitagawa, N. Mizuno
    • Journal Title

      Crystal Growth and Design

      Volume: 14 Issue: 12 Pages: 6620-6626

    • DOI

      10.1021/cg501575x

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Porous Ionic Crystals Modified via Coordination Programming through Single-Crystal-to-Single-Crystal Transformation: Effect of Basicity2014

    • Author(s)
      S. Uchida, K. Mizuno, R. Kawahara, E. Takahashi, N. Mizuno
    • Journal Title

      Chemistry Letters

      Volume: 43 Issue: 8 Pages: 1192-1194

    • DOI

      10.1246/cl.140251

    • NAID

      130004427114

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] ポリオキソメタレートを基盤とした階層的触媒設計2014

    • Author(s)
      水野哲孝, 山口和也, 内田さやか
    • Journal Title

      触媒

      Volume: 56 Pages: 324-329

    • Related Report
      2014 Annual Research Report
  • [Journal Article] Concerted Functions of Anions and Cations in a Molecular Ionic Crystal with Stable Three-Dimensional Micropores2014

    • Author(s)
      R. Kawahara, S. Uchida, N. Mizuno
    • Journal Title

      Inorganic Chemistry

      Volume: 53 Issue: 7 Pages: 36653661-36653661

    • DOI

      10.1021/ic4031574

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Selective Sorption and Unique Packing Geometries of Unsaturated Hydrocarbons and CO2 in a Fluorine-Substituted Organic-Inorganic Ionic Crystal2013

    • Author(s)
      S. Uchida, R. Kawahara, Y. Ogasawara, N. Mizuno
    • Journal Title

      Dalton Transaction

      Volume: 42 Issue: 45 Pages: 1620916215-1620916215

    • DOI

      10.1039/c3dt51458g

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Porous Ionic Crystals Modified by Post-Synthesis of K2[Cr3O(OOCH)6(etpy)3]2[α-SiW12O40]8H2O through Single-Crystal-to-Single-Crystal Transformation2013

    • Author(s)
      S. Uchida, E. Takahashi, N. Mizuno
    • Journal Title

      Inorganic Chemistry

      Volume: 52 Issue: 16 Pages: 93209326-93209326

    • DOI

      10.1021/ic4008334

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enrichment of Tritiated Water Using Mesoporous Silica2013

    • Author(s)
      A. Taguchi, Y. Kato, Y. Torikai, M. Matsuyama, S. Uchida
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 179 Pages: 217233-217233

    • DOI

      10.1016/j.micromeso.2013.05.031

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] 多孔性イオン結晶の幾何構造制御と機能発現2016

    • Author(s)
      内田さやか
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都府、京田辺市)
    • Year and Date
      2016-03-27
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Acid Catalysis in Porous Ionic Crystals with Salophen Complex and Polyoxometalate2016

    • Author(s)
      R. Kawahara, S. Uchida
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都府、京田辺市)
    • Year and Date
      2016-03-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] レドックス型多孔性イオン結晶によるセシウムイオンの高選択的吸着2016

    • Author(s)
      内田さやか
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都府、京田辺市)
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Selective uptake of Cs+ by porous ionic crystals based on redox of polyoxometalates2015

    • Author(s)
      S. Seino, S. Uchida
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      ホノルル、米国
    • Year and Date
      2015-12-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Redox-induced selective uptake-release of cations in porous ionic crystal based on polyoxomolybdates2015

    • Author(s)
      S. Uchida
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      ホノルル、米国
    • Year and Date
      2015-12-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of heterogeneous catalysts composed of aluminum hydroxide cluster and [CoW12O40]6-2015

    • Author(s)
      T. Mura, S. Uchida
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      ホノルル、米国
    • Year and Date
      2015-12-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of heterogeneous catalyst composed of aluminum hydroxide cluster polycation and [SiV3W9O40]7-2015

    • Author(s)
      K. Mizuno, S. Uchida
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      ホノルル、米国
    • Year and Date
      2015-12-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Mesoporous ionic crystals constructed with cationic metal complexes (M = Cr3+, Fe3+) and anionic polyoxometalates: Importance of water2015

    • Author(s)
      R. Kawahara, K. Niinomi, S. Uchida
    • Organizer
      PACIFICHEM 2015
    • Place of Presentation
      ホノルル、米国
    • Year and Date
      2015-12-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Redox-Induced Highly Selctive Uptake of Cs+ by an Ionic Crystal based on Polyoxometalate2015

    • Author(s)
      S. Uchida
    • Organizer
      Topolgy/Geometry-driven Electron Systems toward New Horizon of Functional Materials
    • Place of Presentation
      名古屋大学(愛知県、名古屋市)
    • Year and Date
      2015-12-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Behavior and Functions of Water Clusters in Novel Mesoporous Ionic Crystals2015

    • Author(s)
      川原良介、新家和真、内田さやか
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良女子大学(奈良県、奈良市)
    • Year and Date
      2015-09-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] Acid reaction catalyzed by mesoporous ionic crystals2015

    • Author(s)
      新家和真、川原良介、内田さやか
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良女子大学(奈良県、奈良市)
    • Year and Date
      2015-09-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] 多核水酸化アルミニウムを用いた多孔性イオン結晶2015

    • Author(s)
      村拓人、水野広介、内田さやか
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良女子大学(奈良県、奈良市)
    • Year and Date
      2015-09-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] レドックス型多孔性イオン結晶による外部金属イオンの還元反応2015

    • Author(s)
      間明祥太郎、内田さやか
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良女子大学(奈良県、奈良市)
    • Year and Date
      2015-09-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] 酸化還元型多孔性イオン結晶によるセシウムの選択的吸着2015

    • Author(s)
      清野紗央里、内田さやか
    • Organizer
      錯体化学会第65回討論会
    • Place of Presentation
      奈良女子大学(奈良県、奈良市)
    • Year and Date
      2015-09-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] ポリ酸と多核水酸化アルミニウムイオンからなる多孔性触媒の合成2015

    • Author(s)
      水野広介、村拓人、内田さやか
    • Organizer
      第116回触媒討論会
    • Place of Presentation
      三重大学(三重県、津市)
    • Year and Date
      2015-09-18
    • Related Report
      2015 Annual Research Report
  • [Presentation] Post-Synthetic Modification of Redox-Active Porous Ionic Crystals2015

    • Author(s)
      R. Kawahara, S. Uchida
    • Organizer
      ZMPC2015
    • Place of Presentation
      札幌コンベンションセンター(北海道、札幌市)
    • Year and Date
      2015-06-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Redox-Induced Selective Uptake-Release of Cations in Porous Ionic Crystals2015

    • Author(s)
      S. Uchida
    • Organizer
      ICNM2015
    • Place of Presentation
      台北、台湾
    • Year and Date
      2015-06-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ポリ酸と多核水酸化アルミニウムイオンからなる不均一系触媒の合成2015

    • Author(s)
      水野広介、内田さやか
    • Organizer
      日本化学会第95回春季年会
    • Place of Presentation
      日本大学、船橋市、千葉県
    • Year and Date
      2015-03-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] Redox-Induced Selective Uptake of Cs+ by Porous Ionic Crystals based on Polyoxometalates2015

    • Author(s)
      清野紗央里、川原良介、内田さやか
    • Organizer
      日本化学会第95回春季年会
    • Place of Presentation
      日本大学、船橋市、千葉県
    • Year and Date
      2015-03-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Redox型多孔性イオン結晶による金属イオンの選択的導入と吸着機能制御2015

    • Author(s)
      川原良介、内田さやか
    • Organizer
      日本化学会第95回春季年会
    • Place of Presentation
      日本大学、船橋市、千葉県
    • Year and Date
      2015-03-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] 多核水酸化アルミニウムイオンを用いた多孔性イオン結晶の合成および酸触媒機能2015

    • Author(s)
      村拓人、内田さやか
    • Organizer
      日本化学会第95回春季年会
    • Place of Presentation
      日本大学、船橋市、千葉県
    • Year and Date
      2015-03-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Redox-Induced Reversible Uptake-Release of Cations2015

    • Author(s)
      Sayaka Uchida
    • Organizer
      CBNM4 Carbon-based Nanoporous Material
    • Place of Presentation
      ホテルメトロポリタン長野、長野市、長野県
    • Year and Date
      2015-03-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 多孔性材料の構造と機能解析における計算化学の活用2014

    • Author(s)
      内田さやか
    • Organizer
      触媒学会 コンピューターの利用研究会セミナー
    • Place of Presentation
      三菱化学研究センター、横浜市、神奈川県
    • Year and Date
      2014-12-16
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ポリ酸のレドックスを利用した多孔体のポストシンセシス2014

    • Author(s)
      川原良介、内田さやか
    • Organizer
      CSJ化学フェスタ2014
    • Place of Presentation
      船堀、江戸川区、東京都
    • Year and Date
      2014-10-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] 3-メチルピリジンを配位子とする Cr 錯体を用いた多孔性イオン結晶の構造と吸着機能2014

    • Author(s)
      橋本大地、内田さやか
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学、文京区、東京都
    • Year and Date
      2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] PEG 含有ポリ酸塩を基盤とした中温作動プロトン伝導体の合成2014

    • Author(s)
      坪井優季、内田さやか、日比野光宏、水野哲孝
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学、文京区、東京都
    • Year and Date
      2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 多孔性イオン結晶におけるポストシンセシス法の実践2014

    • Author(s)
      水野広介、川原良介、内田さやか、高橋恵理、水野哲孝
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学、文京区、東京都
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Redox型イオン結晶による吸着スイッチング2014

    • Author(s)
      川原良介、内田さやか
    • Organizer
      錯体化学会第64回討論会
    • Place of Presentation
      中央大学、文京区、東京都
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] 多孔性イオン結晶の吸着・分離・変換作用2014

    • Author(s)
      内田さやか
    • Organizer
      第45回触媒サマーセミナー
    • Place of Presentation
      ホテル花月園、箱根町、神奈川県
    • Year and Date
      2014-07-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 多孔性材料の構造と機能解析2014

    • Author(s)
      内田さやか
    • Organizer
      アクセルリス ユーザー・グループ・ミーティング
    • Place of Presentation
      東京コンファレンスセンター品川、品川区、東京都
    • Year and Date
      2014-06-04
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 多孔性イオン結晶の構築と機能の開拓

    • Author(s)
      内田さやか
    • Organizer
      女性化学者奨励賞受賞講演、日本化学会第94春季年会
    • Place of Presentation
      名古屋大学、名古屋、愛知県
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Hierarchically-Assembled Porous Ionic Crystals

    • Author(s)
      Sayaka Uchida
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学、名古屋、愛知県
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Crystal Structure-Function Relationships in Porous Organic-Inorganic Ionic Crystals

    • Author(s)
      Sayaka Uchida
    • Organizer
      The 12th Conference of the Asian Crystallographic Association
    • Place of Presentation
      香港科技大学、香港、中国
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] フッ素イオンを導入したイオン性結晶の合成及び不飽和炭化水素と二酸化炭素の吸着分離

    • Author(s)
      川原良介、内田さやか、水野哲孝
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学、那覇、沖縄県
    • Related Report
      2013 Annual Research Report
  • [Presentation] ポリオキソメタレートを基盤とした分子性イオン結晶の設計による機能性材料の開発

    • Author(s)
      内田さやか
    • Organizer
      平成25年度触媒学会・触媒工業交流サロン
    • Place of Presentation
      日本化学会化学会館、東京、東京都
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] ナノ空間材料ハンドブック (有賀克彦監修)2016

    • Author(s)
      内田さやか
    • Total Pages
      548
    • Publisher
      エヌ・ティー・エス
    • Related Report
      2015 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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