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Dynamic Metal Complex Clusters

Research Project

Project/Area Number 25288029
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionKyushu University

Principal Investigator

Sato Osamu  九州大学, 先導物質化学研究所, 教授 (80270693)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2015: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2014: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2013: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Keywords物性化学 / 金属錯体 / スピン / 伝導性
Outline of Final Research Achievements

The development of new materials that exhibit reversible changes in physical properties in response to external stimuli has attracted significant attention for their potential applications in molecular devices. We aimed to synthesize dynamic metal complexes and clusters with superior magnetic, conducting and dielectric properties. We successfully obtained a Co10 single molecule magnet, an Fe42 high spin cluster, and a spin crossover conductor.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (11 results)

All 2016 2015 2014 2013

All Journal Article (3 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (8 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results)

  • [Journal Article] Heterometallic FeIII/K coordination polymer with a wide thermal hysteretic spin transition around room temperature2016

    • Author(s)
      Kang, S.; Shiota, Y.; Kariyazaki, A.; Kanegawa, S.; Yoshizawa, K.; Sato, O.
    • Journal Title

      Chem. Eur. J.

      Volume: 22 Issue: 2 Pages: 532-538

    • DOI

      10.1002/chem.201503392

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Charge-Transfer Phase Transition of a Cyanide-Bridged FeII/FeIII Coordination Polymer2016

    • Author(s)
      Kuirun Zhang, Soonchul Kang,* Zi-shuo Yao, Kazusa Nakamura, Takashi Yamamoto, Yasuaki Einaga, Nobuaki Azuma, Yuji Miyazaki, Motohiro Nakano, Shinji Kanegawa, Osamu Sato*
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 20 Pages: 6047-6050

    • DOI

      10.1002/anie.201601526

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Redox Modulation of Spin Crossover within a Cobalt Metallogrid2016

    • Author(s)
      Fuxing Shen, Wei Huang, Dayu Wu, Zhe Zheng, Xing-Cai Huang, and Osamu Sato
    • Journal Title

      Inorg. Chem.

      Volume: 55 Issue: 2 Pages: 902-908

    • DOI

      10.1021/acs.inorgchem.5b02442

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] 鉄錯体の電荷移動相転移2016

    • Author(s)
      佐藤治
    • Organizer
      第8回東北大学研究会
    • Place of Presentation
      仙台
    • Year and Date
      2016-02-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Cyanide-Bridged Fe42 High-Spin Nanocage with S = 90/22015

    • Author(s)
      O. Sato
    • Organizer
      The 9th Japanese-Russian Workshop on Open Shell Compounds and Molecular Spin Devices
    • Place of Presentation
      Awaji
    • Year and Date
      2015-11-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高スピン多核錯体の開発2015

    • Author(s)
      佐藤治
    • Organizer
      九州シンクロトロン光研究センター合同シンポジウム
    • Place of Presentation
      鳥栖
    • Year and Date
      2015-08-28
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis of coordination compounds with dynamic magnetic and mechanical properties2014

    • Author(s)
      O. Sato
    • Organizer
      錯体化学討論会
    • Place of Presentation
      東京
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Control of magnetic properties through external stimuli2014

    • Author(s)
      O. Sato
    • Organizer
      ICMM2014
    • Place of Presentation
      Russia
    • Year and Date
      2014-07-07
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis and characterization of new hybrid-molecular materials consisting of organic conductive molecule and potential anionic spin crossover complex2014

    • Author(s)
      S. Kanegawa, O. Sato
    • Organizer
      ICMM2014
    • Place of Presentation
      Russia
    • Year and Date
      2014-07-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] アニオン性Fe(III)錯体と有機導電分子からなる新規複合機能性分子の合成と物性評価2014

    • Author(s)
      渡邉 健太・金川 慎治・姜 舜徹・佐藤 治
    • Organizer
      日本化学会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] TTF系導電性分子と鉄スピン転移錯体からなる新規ハイブリッド分子材料の合成と物性2013

    • Author(s)
      金川 慎治・渡邉 健太・姜 舜徹・佐藤 治
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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