| Budget Amount *help |
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2015: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2014: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2013: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
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| Outline of Final Research Achievements |
In this project, we studied how hypochlorious acid is produced from the reaction of a high-valent oxoiron complex with chloride. This study points out that the key factor to produce hypochlorious acid is the reactivity of the high-valent oxoiron intermediate that is controlled by unique coordination structures of the active sites in the enzymes. In addition, we studied how the reactivity of the hypochlorite adduct complex is controlled. The most important factor to control the reactivity of the complex is electron donor ability form the cis- and trans-ligands. Interestingly, the electron donor effect of these two ligands show different trend to the reactivity.
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