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Creation of luminescence conversion devices composed of ubiquitous elements responsive to external stimuli based on the control of self-assembly

Research Project

Project/Area Number 25288036
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Functional solid state chemistry
Research InstitutionOsaka University

Principal Investigator

TOHNAI NORIMITSU  大阪大学, 工学(系)研究科(研究院), 准教授 (30346184)

Co-Investigator(Renkei-kenkyūsha) HISAKI ICHIRO  大阪大学, 大学院工学研究科, 助教 (90419466)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2015: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2014: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2013: ¥12,610,000 (Direct Cost: ¥9,700,000、Indirect Cost: ¥2,910,000)
Keywords超分子集合体 / 有機結晶 / 固体発光 / 刺激応答性発光変換 / 有機塩 / 結晶工学 / 多孔性構造 / 超分子 / 発光変換
Outline of Final Research Achievements

The purpose of this study is to elucidate the relationship between molecular arrangements and solid state luminescent properties and to establish the methodology to dynamically design the properties by external stimuli. The supramolecular assemblies composed of luminophores were constructed with non-covalent bonds such as hydrogen bond to control ππ stacking manners between luminophores. Bisaminophenylanthracene derivatives or their organic salts as a luminophore were assembled into various molecular arrangements in crystalline state. Some of the crystals were transformed by chemical and physical stimuli to dynamically change luminescent properties; color, intensity, process and life time. Moreover, relationship between molecular arrangements and luminescent properties were clarified by comparison among luminescent phenomena of bisaminophenylanthracene derivatives.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (24 results)

All 2016 2015 2014 2013

All Journal Article (12 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 12 results,  Acknowledgement Compliant: 5 results,  Open Access: 1 results) Presentation (11 results) (of which Int'l Joint Research: 2 results,  Invited: 6 results) Book (1 results)

  • [Journal Article] Arrangement Modulation of pi-Stacked Columnar Assemblies of Octadehydrodibenzo[12]annulene: Substituent Effects of Peripheral Thienyl and Phenyl Rings2016

    • Author(s)
      Ichiro Hisaki, Keisuke Osaka, Nobuaki Ikenaka, Akinori Saeki, Norimitsu Tohnai, Shu Seki, Mikiji Miyata
    • Journal Title

      Cryst. Growth Des.

      Volume: 16 Issue: 2 Pages: 714-721

    • DOI

      10.1021/acs.cgd.5b01273

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] C3-Symmetric Macrocycle-Based, Hydrogen-Bonded, Multi-Porous Hexagonal Network as Motif of Porous Molecular Crystals2015

    • Author(s)
      2.Ichiro Hisaki, Shoichi Nakagawa, Norimitsu Tohnai, Mikiji Miyata
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 15 Issue: 10 Pages: 3008-3012

    • DOI

      10.1002/anie.201411438

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Twofold Hilical Polymerization: Thermal Solid-State Polymerization of 7-Cyano-7-(2'-haloethoxycarbonyl)-1,4-benzoquinone Methides2015

    • Author(s)
      Takahito Itoh, Kyoko Tachino, Naoki Akira, Takahiro Uno, Masataka Kubo, Norimitsu Tohnai, Mikiji Miyata
    • Journal Title

      Macromolecules

      Volume: 48 Issue: 9 Pages: 2935-2947

    • DOI

      10.1021/ma502606s

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Chirality Generation in Supramolecular Clusters: Analogues of Octacoordinated Polyhedrons2015

    • Author(s)
      Toshiyuki Sasaki, Yoko Ida, Tetsuharu Yuge, Atsushi Yamamoto, Ichiro Hisaki, Norimitsu Tohnai, Mikiji Miyata
    • Journal Title

      Crystal Growth & Design

      Volume: 15 Issue: 2 Pages: 658-665

    • DOI

      10.1021/cg5013445

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Highly Efficient Tunable Solid State Emission via the Excited-State Intramolecular Proton-Transfer (ESIPT) with 2-(2’-Hydroxy) Benzothiazole (HBT) and Fluorene motifs2015

    • Author(s)
      Vikas S. Padalkar, Daisuke Sakamaki, Shu Seki, Norimitsu Tohnai, Tomoyuki Akutagawa, and Ken-ichi Sakai
    • Journal Title

      RSC Advance

      Volume: 5 Issue: 98 Pages: 80283-80296

    • DOI

      10.1039/c5ra17980g

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Crystal Structure of Hydrogen-Bond Assisted Coaxially pi-Stacked Dimer of Hexadehydrotribenzo[12]annulene ([12]DBA) Derivative2014

    • Author(s)
      Ichiro Hisaki, Keisuke Osaka, Hajime Shigemitsu, Norimitsu Tohnai, Mikiji Miyata
    • Journal Title

      Chem. Lett.

      Volume: 43 Issue: 7 Pages: 11041106-11041106

    • DOI

      10.1246/cl.140250

    • NAID

      130004868257

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Amphiphilic Inclusion Spaces for Various Guests and Regulation of Fluorescence Intensity of 1,8-Bis(4-aminophenyl)anthracene Crystals2014

    • Author(s)
      Sugino Misa, Hatanaka Keisuke, Araki Yusuke, Hisaki Ichiro, Miyata Mikiji, Tohnai Norimitsu
    • Journal Title

      Chem. - Eur. J.

      Volume: 20 Issue: 11 Pages: 3069-3076

    • DOI

      10.1002/chem.201304541

    • Related Report
      2014 Annual Research Report 2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Water inclusion as a trigger for modulation of anthracene arrangement and fluorescence emission of organic salt2014

    • Author(s)
      Sugino Misa, Hatanaka Keisuke, Miyano Tetsuya, Hisaki Ichiro, Miyata Mikiji, Sakon Aya, Uekusa Hidehiro, Tohnai Norimitsu
    • Journal Title

      Tetrahedron Lett.

      Volume: 55 Issue: 3 Pages: 732-736

    • DOI

      10.1016/j.tetlet.2013.12.005

    • Related Report
      2014 Annual Research Report 2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of Supramolecular Hidden Chirality of Hydrogen-Bonded Networks by Advanced Graph Set Analysis2014

    • Author(s)
      Toshiyuki Sasaki, Yoko Ida, Ichiro Hisaki, Tetsuharu Yuge, Yoshiaki Uchida, Norimitsu Tohnai and Mikiji Miyata
    • Journal Title

      Chemistry-A European Journal

      Volume: 20 Issue: 9 Pages: 2478-2487

    • DOI

      10.1002/chem.201303770

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Engineering Switchable Rotors in Molecular Crystals with Open Porosity2014

    • Author(s)
      Comotti Angiolina, Bracco Silvia, Yamamoto Atsushi, Beretta Mario, Hirukawa Tomofumi, Tohnai Norimitsu, Miyata Mikiji, Sozzani Piero
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 136 Issue: 2 Pages: 618-621

    • DOI

      10.1021/ja411233p

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A facile and versatile approach to efficient enhancement of solid-state luminescence by organic-inorganic hybrid salts2013

    • Author(s)
      Tohnai Norimitsu, Sugino Misa, Araki Yusuke, Hatanaka Keisuke, Hisaki Ichiro, Miyata Mikiji
    • Journal Title

      Dalton Trans.

      Volume: 42 Issue: 45 Pages: 15922-15926

    • DOI

      10.1039/c3dt51422f

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Elucidation of Anthracene Arrangement for Excimer Emission at Ambient Conditions2013

    • Author(s)
      Sugino Misa, Araki Yusuke, Hatanaka Keisuke, Hisaki Ichiro, Miyata Mikiji, Tohnai Norimitsu
    • Journal Title

      Cryst. Growth Des.

      Volume: 13 Issue: 11 Pages: 4986-4992

    • DOI

      10.1021/cg401166v

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Construction of Versatile Porous Structures: Diamondoid Porous Organic Salts (d-POS))2015

    • Author(s)
      藤内謙光
    • Organizer
      International Chemical Congress of Pacific Basin Societies 2015(Invited)
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2015-12-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Construction of Versatile Porous Structures: Diamondoid Porous Organic Salts (d-POS))2015

    • Author(s)
      藤内謙光
    • Organizer
      The 22nd International Conference on the Chemistry of the Organic Solid State(Invited)
    • Place of Presentation
      Niigata, Japan
    • Year and Date
      2015-07-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Twofold Helical Assembly in Organic Crystal2014

    • Author(s)
      久木一朗、佐々木俊之、藤内謙光、宮田幹二
    • Organizer
      Molecular Chirality Asia 2014
    • Place of Presentation
      北京、中国
    • Year and Date
      2014-10-29 – 2014-10-31
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Hierarchical Construction of Versatile Diamondoid Porous Organic Salts (d-POS)2014

    • Author(s)
      藤内謙光、山本淳志、久木一朗、宮田幹二
    • Organizer
      IUCr 2014 23rd Congress
    • Place of Presentation
      モントリオール、カナダ
    • Year and Date
      2014-08-05 – 2014-08-12
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Affirmative Generation of Dehydrobenzoannulene Polymorphs2014

    • Author(s)
      久木一朗、藤内謙光、宮田幹二
    • Organizer
      IUCr 2014 23rd Congress
    • Place of Presentation
      モントリオール、カナダ
    • Year and Date
      2014-08-05 – 2014-08-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] Construction of Versatile Porous Structures: Diamondoid Porous Organic Salts (d-POS)2014

    • Author(s)
      藤内謙光、山本淳志、久木一朗、宮田幹二
    • Organizer
      Joint Congress of ACTS-2014 and CGOM11
    • Place of Presentation
      奈良県新公会堂(奈良市)
    • Year and Date
      2014-06-17 – 2014-06-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 結晶中の超分子隠れキラリティーの明確化と左右決定2014

    • Author(s)
      佐々木俊之、井田陽子、久木一朗、藤内謙光、宮田幹二
    • Organizer
      モレキュラー・キラリティー2014
    • Place of Presentation
      仙台国際センター(仙台市)
    • Year and Date
      2014-06-06 – 2014-06-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] Modulation of Emission Process and Molecular Arrangement in Crystal Composed of 9,10-Bisaminophenylanthracene and Mineral Acid2013

    • Author(s)
      Sugino Misa, Tohnai Norimitsu, Hisaki Ichiro, Miyata Mikiji
    • Organizer
      The 21th International Conference on the Chemistry of the Organic Solid State (ICCOSS XXI)
    • Place of Presentation
      Oxford, UK
    • Related Report
      2013 Annual Research Report
  • [Presentation] Fluorescent Color Modulation of Organic Solids by Regulation of π-Stacked Stilbene Arrangements2013

    • Author(s)
      Chien-Chih Chen, Tohnai Norimitsu, Hisaki Ichiro, Miyata Mikiji
    • Organizer
      第62回高分子年次大会
    • Place of Presentation
      京都国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] 水素結合ネットワークを利用した多孔質有機塩(POSs)の構築と そのゲスト依存的発光特性2013

    • Author(s)
      浜田智也 ・山本淳志・藤内謙光 ・久木一朗・宮田幹二
    • Organizer
      第62回高分子年次大会
    • Place of Presentation
      京都国際会議場
    • Related Report
      2013 Annual Research Report
  • [Presentation] 有機塩を用いた超分子的アプローチによる結晶構造制御と機能化2013

    • Author(s)
      藤内謙光
    • Organizer
      第17回液晶化学研究会シンポジウム
    • Place of Presentation
      産業技術総合研究所
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] Advances in Organic Crystal Chemistry. Comprehensive Reviews 20152015

    • Author(s)
      R. Tamura, M. Miyata ed. N. Tohnai
    • Total Pages
      706
    • Publisher
      Springer
    • Related Report
      2015 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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