Exotic Molecular Assemblies based on Coronene
Project/Area Number |
25288041
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Research Category |
Grant-in-Aid for Scientific Research (B)
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Allocation Type | Partial Multi-year Fund |
Section | 一般 |
Research Field |
Functional solid state chemistry
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Research Institution | Meijo University |
Principal Investigator |
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Co-Investigator(Kenkyū-buntansha) |
MAESATO Mitsuhiko 京都大学, 理学研究科, 准教授 (60324604)
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Co-Investigator(Renkei-kenkyūsha) |
TAKEDA Sadamu 北海道大学, 理学研究科, 教授 (00155011)
MIZUNO Motohiro 金沢大学, 自然科学研究科, 教授 (70251915)
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Project Period (FY) |
2013-04-01 – 2016-03-31
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Project Status |
Completed (Fiscal Year 2015)
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Budget Amount *help |
¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2015: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2014: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2013: ¥13,520,000 (Direct Cost: ¥10,400,000、Indirect Cost: ¥3,120,000)
|
Keywords | 多環芳香族炭化水素 / 軌道縮重 / コロネン / 電荷移動 / 超伝導 / 超分子ローター / キャリア注入 / 分子配列 / 電荷移動錯体 / 電界効果トランジスタ / 結晶構造 / π-d相互作用 / 分子ローター / FET |
Outline of Final Research Achievements |
Charge transfer complexes based on a highly symmetric (D6h) polycyclic aromatic hydrocarbon, coronene, were systematically prepared. For the mixed-stacked neutral complexes, we found that the dynamic properties of coronene molecules largely depend on the molecular arrangement within the stacks. The first coronene cation solid was prepared by electrooxidation. The salt belongs to the cubic system, which is exceptionally rare among molecular solids, and has no face-to-face π-π interactions. It shows a high room-temperature conductivity (1.7 Scm-1), although exhibiting semiconducting behavior associated with the charge disproportionation. In addition, we obtained the coronene cation salts with π-stacking columns of coronene. The salts have interplanar distances shorter than that in graphite and show semiconducting behavior. For the salts, we succeeded in the first observation of a static Jahn-Teller distortion of coronene cations.
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Report
(4 results)
Research Products
(83 results)
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[Journal Article] Conducting π-Columns of Highly Symmetric Coronene, the Smallest Fragment of Graphene2016
Author(s)
Y. Yoshida, K. Isomura, H. Kishida, Y. Kumagai, M. Mizuno, M. Sakata, T. Koretsune, Y. Nakano, H. Yamochi, M. Maesato, G. Saito
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Journal Title
Chem. Eur. J.
Volume: 22
Issue: 17
Pages: 6023-6030
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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[Journal Article] Spin Frustration in Antiperovskite Systems: (TTF+ or TSF+)3[(Mo6X14)2-Y-]2015
Author(s)
T. Hiramatsu, Y. Yoshida, G. Saito, A. Otsuka, H. Yamochi, Y. Shimizu, Y. Hattori, Y. Nakamura, H. Kishida, H. Ito, K. Kirakci, S. Cordier, C. Perrin
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Journal Title
J. Mater. Chem. C
Volume: 3
Issue: 42
Pages: 11046-11054
DOI
NAID
Related Report
Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
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[Journal Article] Local response to light excitation in the charge-ordered phase of (EDO-TTF)2SbF62015
Author(s)
M. Servol, N. Moisan, E. Collet, H. Cailleau, W. Kaszub, L. Toupet, D. Boschetto, T. Ishikawa, A. Moreac, S. Koshihara, M. Maesato, M. Uruichi, X. F. Shao, Y. Nakano, H. Yamochi, G. Saito, M. Lorenc
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Journal Title
Phys. Rev. B
Volume: 92
Issue: 2
DOI
NAID
Related Report
Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
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[Journal Article] Hybrid Materials of Ni NP@MOF prepared by a Simple Synthetic Method2015
Author(s)
M. Mukoyoshi, H. Kobayashi, K. Kusada, M. Hayashi, T. Yamada, M. Maesato, Jared M. Taylor, Y. Kubota, K. Kato, M. Takata, T. Yamamoto, S. Matsumura, H. Kitagawa
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Journal Title
Chemical Communications
Volume: 51
Issue: 62
Pages: 10169-10172
DOI
Related Report
Peer Reviewed / Open Access
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[Journal Article] Isotropic Three-Dimensional Molecular Conductor Based on Coronene Radical Cation2014
Author(s)
Y. Yoshida, M. Maesato, Y. Kumagai, M. Mizuno, K. Isomura, H. Kishida, M. Izumi, Y. Kubozono, A. Otsuka, H. Yamochi, G. Saito, K. Kirakci, S. Cordier, C. Perrin
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Journal Title
Eur. J. Inorg. Chem.
Volume: 2014
Issue: 24
Pages: 3871-3878
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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[Presentation] Coronene-based cation radical salts with segregated columns2015
Author(s)
Y. Yoshida, K. Isomura, H. Kishida, Y. Kumagai, M. Mizuno, M. Sakata, T. Koretsune, Y. Nakano, H. Yamochi, M. Maesato, G. Saito
Organizer
The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015)
Place of Presentation
米国(ハワイ州ホノルル)
Year and Date
2015-12-15
Related Report
Int'l Joint Research
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[Presentation] Quantum fluctuations in frustrated organic complexes κ-(ET)2X2015
Author(s)
Y. Shimizu, A. Ono, M. Itoh, M. Yoshida, M. Takigawa, M. Maesato, A. Otsuka, H. Yamochi, T. Hiramatsu, Y. Yoshida, G. Saito
Organizer
The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015)
Place of Presentation
米国(ハワイ州ホノルル)
Year and Date
2015-12-15
Related Report
Int'l Joint Research
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[Presentation] Coronene-based supramolecular rotors2015
Author(s)
Y. Yoshida, Y. Kumagai, M. Mizuno, K. Isomura, H. Kishida, G. Saito
Organizer
The International Chemical Congress of Pacific Basin Societies (Pacifichem 2015)
Place of Presentation
米国(ハワイ州ホノルル)
Year and Date
2015-12-15
Related Report
Int'l Joint Research
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[Presentation] New quantum spin-liquid candidates, valence-bond solid, and superconductors κ-(BEDT-TTF)2X (X=Ag2(CN)3, B(CN)4, CF3SO3, Ag(CN)[N(CN)2], etc.)2015
Author(s)
G. Saito, T. Hiramatsu, Y. Yoshida, A. Otsuka, M. Maesato, Y. Shimizu, H. Ito, H. Kishida
Organizer
11th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2015)
Place of Presentation
ドイツ(バイエルン州バートゴギング)
Year and Date
2015-09-06
Related Report
Int'l Joint Research
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[Presentation] Quantum Spin Systems in κ-ET salts2015
Author(s)
M. Maesato, Y. Shimizu, A. Otsuka, T. Hiramatsu, Y. Yoshida, G. Saito
Organizer
11th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2015)
Place of Presentation
ドイツ(バイエルン州バートゴギング)
Year and Date
2015-09-06
Related Report
Int'l Joint Research
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[Presentation] Formation of π-π Stacking of Cationic Coronene2015
Author(s)
Y. Yoshida, K. Isomura, H. Kishida, Y. Kumagai, M. Mizuno, M. Sakata, T. Koretsune, Y. Nakano, H. Yamochi, M. Maesato, G. Saito
Organizer
11th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM2015)
Place of Presentation
ドイツ(バイエルン州バートゴギング)
Year and Date
2015-09-06
Related Report
Int'l Joint Research
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[Presentation] 分離積層構造を有するコロネン陽イオンラジカル塩2015
Author(s)
吉田幸大, 磯村和秀, 岸田英夫, 坂田雅文, 藤井雄佑, 加賀山朋子, 前里光彦, 齋藤軍治
Organizer
日本化学会第95春季年会
Place of Presentation
日本大学理工学部船橋キャンパス
Year and Date
2015-03-26 – 2015-03-29
Related Report
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[Presentation] C3h, D6h, D4h対称性分子におけるヤーン・テラー歪み,および電子構造に関する理論的解析2015
Author(s)
大江佳毅, 中野義明, 高橋佑輔, 大塚晃弘, 矢持秀起, 吉田幸大, 齋藤軍治, D. V. Konarev, R. N. Lyubovskaya
Organizer
第13回京都大学低温物質科学研究センター講演会・研究交流会
Place of Presentation
京都大学百周年時計台記念館
Year and Date
2015-02-10
Related Report
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[Presentation] コロネンラジカル陽イオンを用いた3次元伝導性超分子ローターの開発2014
Author(s)
吉田幸大, 前里光彦, 熊谷翼秀, 水野元博, 磯村和秀, 岸田英夫, 和泉正成, 久保園芳博, 大塚晃弘, 矢持秀起, 齋藤軍治
Organizer
第8回分子科学討論会
Place of Presentation
広島大学東広島キャンパス
Year and Date
2014-09-21 – 2014-09-24
Related Report
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[Presentation] First Coronene Cation Radical Salt: Isotropic Three-Dimensional Molecular Conductor2014
Author(s)
Y. Yoshida, M. Maesato, Y. Kumagai, M. Mizuno, K. Isomura, H. Kishida, M. Izumi, Y. Kubozono, A. Otsuka, H. Yamochi, G. Saito, K. Kirakci, S. Cordier, C. Perrin
Organizer
International Conference on Science and Technology of Synthetic Metals (ICSM2014)
Place of Presentation
フィンランド・トゥルク
Year and Date
2014-06-30 – 2014-07-05
Related Report
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[Presentation] Superconductivity Emerging from Spin Liquid2014
Author(s)
M. Maesato, T. Hiramatsu, Y. Yoshida, Y. Shimizu, A. Otsuka, G. Saito, H. Kitagawa
Organizer
International Conference on Science and Technology of Synthetic Metals (ICSM2014)
Place of Presentation
フィンランド・トゥルク
Year and Date
2014-06-30 – 2014-07-05
Related Report
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