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Decarboxylative Route to Organofluorine Compounds

Research Project

Project/Area Number 25288044
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Synthetic chemistry
Research InstitutionGunma University

Principal Investigator

Amii Hideki  群馬大学, 理工学府, 教授 (00284084)

Co-Investigator(Kenkyū-buntansha) 園山 正史  群馬大学, 大学院理工学府, 教授 (40242242)
Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2015: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2013: ¥10,270,000 (Direct Cost: ¥7,900,000、Indirect Cost: ¥2,370,000)
Keywords有機合成化学 / フッ素 / 脱炭酸 / 炭素―炭素結合形成 / ヘテロ元素化合物 / ラジカル反応 / 脱炭酸反応 / カルバニオン / フッ素官能基
Outline of Final Research Achievements

Fluorine-containing organic molecules play a pivotal role in the remarkable progress of medicinal, agricultural, and material sciences. Difluoromethylene compounds have been considerable synthetic targets because of their wide utility. Among them, difluoromethylated aromatic compounds (Ar-CF2-R) have received a great deal of attention in the design of bioactive molecules. Previously, we reported the reaction sequence involving cross-coupling and decarboxylation to afford difluoromethyl aromatics (Ar-CF2H). Herein we developed versatile decarboxylative transformations for the synthesis of aromatic compounds bearing functionalized difluoromethyl groups. Upon heating in DMSO or NMP at 170 °C with CuI, potassium 2-aryl-2,2-difluoroacetates underwent decarboxylation to generate aryldifluoromethyl anions (ArCF2-), which reacted with electrophiles to afford a variety of gem-difluoromethylene compounds in moderate to good yields.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (86 results)

All 2017 2016 2015 2014 2013

All Journal Article (14 results) (of which Peer Reviewed: 14 results,  Open Access: 4 results,  Acknowledgement Compliant: 7 results) Presentation (68 results) (of which Int'l Joint Research: 12 results,  Invited: 27 results) Book (3 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] 便利!汎用試薬を使うトリフルオロメチル化反応2017

    • Author(s)
      杉石露佳, 網井秀樹
    • Journal Title

      化学

      Volume: 72 Pages: 66-67

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Convenient Method for Catalytic Aromatic Pentafluoroethylation Using Potassium (Pentafluoroethyl)trimethoxyborate2017

    • Author(s)
      Tsuyuka Sugiishi, Daisuke Kawauchi, Mizuki Sato, Tatsuya Sakai, Hideki Amii
    • Journal Title

      Synthesis

      Volume: 49 Issue: 08 Pages: 1874-1878

    • DOI

      10.1055/s-0036-1589477

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Trifluoromethylation of Aryl Iodides Catalyzed by the Copper(I)-Phen Complex2016

    • Author(s)
      Naoto Shimizu, Hideaki Kondo, Masahiro Oishi, Kenichi Fujikawa, Kazuki Komoda, and Hideki Amii
    • Journal Title

      Organic Syntheses

      Volume: 93 Pages: 147-162

    • DOI

      10.15227/orgsyn.093.0147

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Lateral Diffusion and Molecular Interaction in a Bilayer Membrane Consisting of Partially Fluorinated Phospholipids2016

    • Author(s)
      Y. Okamoto, T. Motegi, K. Morita, T. Takagi, H. Amii, T. Kanamori, M. Sonoyama, R. Tero
    • Journal Title

      Langmuir

      Volume: 32 Issue: 41 Pages: 10712-10718

    • DOI

      10.1021/acs.langmuir.6b02874

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Surface Properties of a Single Perfluoroalkyl Group on Water Surfaces Studied by Surface Potential Measurements2016

    • Author(s)
      Takafumi Shimoaka, Yuki Tanaka, Nobutaka Shioya, Kohei Morita, Masashi Sonoyama, Hideki Amii, Toshiyuki Takagi, Takeshi Hasegawa
    • Journal Title

      J. Colloid Interface Sci.

      Volume: 483 Pages: 353-359

    • DOI

      10.1016/j.jcis.2016.08.055

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Origin of Complicated Infrared Spectra of Perfluoroalkyl Compounds Involving a Nor- mal Alkyl Group2015

    • Author(s)
      Takeshi Hasegawa, Takafumi Shimoaka, Yuki Tanaka, Nobutaka Shioya, Kohei Morita, Masashi Sonoyama, Hideki Amii, Toshiyuki Takagi, Toshiyuki Kanamori
    • Journal Title

      Chem. Lett.

      Volume: 44 Issue: 6 Pages: 834-836

    • DOI

      10.1246/cl.150198

    • NAID

      130005074608

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Carbon-carbon bond cleavage for Cu-mediated aromatic trifluoromethylations and pentafluoroethylations2015

    • Author(s)
      Tsuyuka Sugiishi, Hideki Amii, Kohsuke Aikawa, and Koichi Mikami
    • Journal Title

      Beilstein Journal of Organic Chemistry

      Volume: 11 Pages: 2661-2670

    • DOI

      10.3762/bjoc.11.286

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Highly Controlled Ring-Opening of Siloxydifluorocyclopropanes: A Versatile Route to Cyclic Fluoroketones2015

    • Author(s)
      Yoshiya Kageshima, Chiharu Suzuki, Kojun Oshiro, Hideki Amii
    • Journal Title

      Synlett

      Volume: 26 Issue: 01 Pages: 63-66

    • DOI

      10.1055/s-0034-1379599

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Enhancement of stereoselectivities in asymmetric synthesis using fluorinated solvents, auxiliaries, and catalysts2015

    • Author(s)
      Tsuyuka Sugiishi, Masato Matsugi, Hiroshi Hamamoto, and Hideki Amii
    • Journal Title

      RSC Advances

      Volume: 5 Issue: 22 Pages: 17269-17282

    • DOI

      10.1039/c4ra11860j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Efficient Generation and Increased Reactivity in Cationic Gold via Bronsted Acid or Lewis Acid Assisted Activation of an Imidogold2014

    • Author(s)
      Junbin Han, Naoto Shimizu, Zhichao Lu, Hideki Amii, Gerald B. Hammond, and Bo Xu
    • Journal Title

      Organic Letters

      Volume: 16 Issue: 13 Pages: 3500-3503

    • DOI

      10.1021/ol501443m

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ruppert-Prakash試薬(CF3SiMe3)の新しい使い方2014

    • Author(s)
      網井秀樹
    • Journal Title

      Fluorous Topics

      Volume: 1 Pages: 4-6

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 進化し続ける芳香族トリフルオロメチル化法2014

    • Author(s)
      網井秀樹
    • Journal Title

      ファルマシア

      Volume: 50 Pages: 19-23

    • NAID

      130005122141

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation and structure of a fluorinated [2.2]paracyclophan-1-ene2013

    • Author(s)
      Hideki Amii, Ryotaro Hayashi, Motoharu Seo, Yukako Katahira, Akira Kobayashi, and Kenji Uneyama
    • Journal Title

      J. Fluorine Chem.

      Volume: 152 Pages: 90-93

    • DOI

      10.1016/j.jfluchem.2013.04.001

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Physicochemical Studies of Bacteriorhodopsin Reconstituted in Partially Fluorinated Phosphatidylcholine Bilayers2013

    • Author(s)
      Yoshino, M., Kikukawa, T., Takahashi, H., Takagi, T., Yokoyama, Y., Amii, H., Baba, T., Kanamori, T., Sonoyama, M.
    • Journal Title

      J. Phys. Chem. B

      Volume: 117 Issue: 18 Pages: 5422-5429

    • DOI

      10.1021/jp311665z

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] アリールジフルオロメチルアニオン種を用いる炭素-炭素結合形成反応2017

    • Author(s)
      甲谷渉, 杉石露佳, 網井秀樹
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学(横浜)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 官能基を有する芳香族モノフルオロメチル化合物の変換反応2017

    • Author(s)
      下川あい, 森岡亮, 杉石露佳, 網井秀樹
    • Organizer
      日本化学会第97春季年会
    • Place of Presentation
      慶応義塾大学(横浜)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
  • [Presentation] 脱炭酸反応を活用するジフルオロメチレン化合物の合成2017

    • Author(s)
      網井秀樹
    • Organizer
      日本学術振興会フッ素化学第155委員会第107回定例研究会
    • Place of Presentation
      芝蘭会館(京都市)
    • Year and Date
      2017-01-19
    • Related Report
      2016 Annual Research Report
  • [Presentation] Recent Progress in Catalytic Aromatic Trifluoromethylation2016

    • Author(s)
      Hideki Amii
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2016 (C&FC 2016)
    • Place of Presentation
      Howard Civil Service International House (Taipei, Taiwan)
    • Year and Date
      2016-11-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] アリールジフルオロメチルラジカルの発生と反応2016

    • Author(s)
      上山晃平, 春日嶺, 杉石露佳, 網井秀樹
    • Organizer
      第39回フッ素化学討論会
    • Place of Presentation
      アバンセ(佐賀市)
    • Year and Date
      2016-09-29
    • Related Report
      2016 Annual Research Report
  • [Presentation] Decarboxylative Route to Organofluorine Compounds2016

    • Author(s)
      Hideki Amii
    • Organizer
      The International Symposium on Pure & Applied Chemistry (ISPAC 2016)
    • Place of Presentation
      Borneo Convention Center (Kuching, Malaysia)
    • Year and Date
      2016-08-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Selective Synthesis of gem-Difluoromethylene Compounds2016

    • Author(s)
      Hideki Amii
    • Organizer
      18th European Symposium on Fluorine Chemistry
    • Place of Presentation
      Hotel Ramada Encore Kyiv (Kyiv, Ukraine)
    • Year and Date
      2016-08-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] A Convenient Protocol for Catalytic Aromatic Pentafluoroethylation Using Potassium (Pentafluoroethyl)trimethoxyborate2016

    • Author(s)
      Tsuyuka Sugiishi, Daisuke Kawauchi, Mizuki Sato, Tatsuya Sakai, Hideki Amii
    • Organizer
      20th International Symposium on Homogeneous Catalysis (ISHCXX)
    • Place of Presentation
      Kyoto Terrsa (Kyoto)
    • Year and Date
      2016-07-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] A Convenient Decarboxylative Route to Difluoromethylene Compounds2016

    • Author(s)
      Hideki Amii
    • Organizer
      The 12th International Symposium on Organic Reactions (ISOR-12)
    • Place of Presentation
      Kyoto Terrsa (Kyoto)
    • Year and Date
      2016-04-22
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 置換基を有するトリフルオロメチルイソベンゾフランの発生と応用2016

    • Author(s)
      彦部圭政,品田瞬,稲葉公則,仁科勇太,網井秀樹
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 含フッ素フタリドの不斉合成2016

    • Author(s)
      坂井達也,稲葉公則,柴田哲男,網井秀樹
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] α-(チオフェニル)ジフルオロメチル化アレーンの合成化学的応用2016

    • Author(s)
      上山晃平,木村仁美,杉石露佳,網井秀樹
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 臭化アリールを用いる触媒的芳香族ペルフルオロアルキル化反応2016

    • Author(s)
      小茂田和希,久保田結衣,杉石露佳,芹澤宏希,相川光介,三上幸一,網井秀樹
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] フルオロアルキル化ホウ素化合物の炭素-炭素結合形成反応への応用2016

    • Author(s)
      河内大佑,佐藤瑞記,坂井達也,中島慧乃,網井秀樹
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] フローマイクロリアクターを用いた有機フッ素化合物の選択的合成2016

    • Author(s)
      網井秀樹
    • Organizer
      日本学術振興会フッ素化学第155委員会第103回定例研究会
    • Place of Presentation
      芝蘭会館(京都市)
    • Year and Date
      2016-01-20
    • Related Report
      2015 Annual Research Report
  • [Presentation] β-炭素脱離による触媒的芳香族トリフルオロメチル化とペンタフルオロエチル化2016

    • Author(s)
      小茂田和希, 清水直登, 久保田結衣, 杉石露佳, 芹澤宏希, 相川光介, 三上幸一, 網井秀樹
    • Organizer
      第71回有機合成化学協会関東支部シンポジウム
    • Place of Presentation
      東京農工大学(小金井市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 触媒的フッ素官能基導入反応の新設計と応用2016

    • Author(s)
      網井秀樹
    • Organizer
      Ambitious物質科学セミナー
    • Place of Presentation
      北海道大学(札幌市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 触媒的含フッ素官能基導入反応の新展開2016

    • Author(s)
      網井秀樹
    • Organizer
      第31回有機合成化学セミナー
    • Place of Presentation
      筑波大学(つくば市)
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Highly Selective Synthesis of Organofluorine Compounds Using Flow Microreactors2015

    • Author(s)
      Hideki Amii
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem 2015)
    • Place of Presentation
      Hilton Hawaiian Village (Honolulu, USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] An origin of complicated infrared spectra of perfluoroalkyl compounds involving a normal alkyl group2015

    • Author(s)
      Takeshi Hasegawa, Takafumi Shimoaka, Yuki Tanaka, Nobutaka Shioya, Kohei Morita, Masashi Sonoyama, Hideki Amii, Toshiyuki Takagi, Toshiyuki Kanamori
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem 2015)
    • Place of Presentation
      Hilton Hawaiian Village (Honolulu, USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Ingenious Decarboxylative Route to Organofluorine Compounds2015

    • Author(s)
      Hideki Amii
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies (Pacifichem 2015)
    • Place of Presentation
      Hilton Hawaiian Village (Honolulu, USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 急進展する有機フッ素化学:基礎から最近の合成技術まで2015

    • Author(s)
      網井秀樹
    • Organizer
      平成27年度後期(秋季)有機合成化学講習会「有機合成化学が拓く未来 -新反応から新技術まで-」
    • Place of Presentation
      日本薬学会長井記念館長井記念ホール(東京都渋谷区)
    • Year and Date
      2015-11-16
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 有機フッ素化合物の触媒的合成の新展開2015

    • Author(s)
      網井秀樹
    • Organizer
      第12回触媒相模セミナー
    • Place of Presentation
      相模中央化学研究所(綾瀬市)
    • Year and Date
      2015-11-12
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Generation and Reactions of Fluoroalkyl Carbanion by Deprotonation2015

    • Author(s)
      Taku Kitahara, Tsuyuka Sugiishi, and Hideki Amii
    • Organizer
      The 13th International Kyoto Conference on New Aspect of Organic Chemistry (IKCOC-13)
    • Place of Presentation
      Rihga Royal Hotel (Kyoto)
    • Year and Date
      2015-11-09
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ジハロシクロプロピルシリルエーテルの環開裂フッ素化反応2015

    • Author(s)
      村松由香利,岸田真里,北川紗央合,吉川葉,鈴木千春,網井 秀樹,関山秀雄,桐原正之
    • Organizer
      第41回反応と合成の進歩シンポジウム
    • Place of Presentation
      近畿大学(東大阪市)
    • Year and Date
      2015-10-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] フローマイクロリアクターを用いたヘキサフルオロベンゼンの求核置換反応の制御2015

    • Author(s)
      高野綾,村田啓幸,網井秀樹
    • Organizer
      第38回フッ素化学討論会
    • Place of Presentation
      日本橋公会堂(東京都中央区)
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] 脱炭酸二量化によるジアリールテトラフルオロエタン類の合成2015

    • Author(s)
      春日嶺,網井秀樹
    • Organizer
      第38回フッ素化学討論会
    • Place of Presentation
      日本橋公会堂(東京都中央区)
    • Year and Date
      2015-09-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] Cu-Catalyzed Aromatic Perfluoroalkylation via beta-Carbon Elimination,2015

    • Author(s)
      Kazuki Komoda, Naoto Shimizu, Hiroki Serizawa, Kosuke Aikawa, Koichi Mikami, and Hideki Amii
    • Organizer
      The 21st International Symposium on Fluorine Chemistry (21st ISFC) & the 6th International Symposium on Fluorous Technologies
    • Place of Presentation
      Politecnico di Milano (Como, Italy)
    • Year and Date
      2015-08-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Decarboxylative Route to Difluoromethylene Compounds2015

    • Author(s)
      Hideki Amii
    • Organizer
      The 21st International Symposium on Fluorine Chemistry (21st ISFC) & the 6th International Symposium on Fluorous Technologies
    • Place of Presentation
      Politecnico di Milano (Como, Italy)
    • Year and Date
      2015-08-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 脱プロトン化によるフルオロアルキルカルボアニオンの発生と反応2015

    • Author(s)
      北原拓, 杉石露佳, 網井秀樹
    • Organizer
      日本化学会第95回春季年会
    • Place of Presentation
      日本大学(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] フローマイクロリアクターを用いた芳香族求核置換反応の制御2015

    • Author(s)
      高野綾,村田啓幸,網井秀樹
    • Organizer
      日本化学会第95回春季年会
    • Place of Presentation
      日本大学(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] ジハロシクロプロピルシリルエーテルの環開裂フッ素化反応2015

    • Author(s)
      岸田真理,北川紗央合,村松由香利,鈴木千春,網井秀樹,桐原正之
    • Organizer
      日本化学会第95回春季年会
    • Place of Presentation
      日本大学(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機化合物へのフッ素官能基の導入と応用2015

    • Author(s)
      網井秀樹
    • Organizer
      第4回フッ素化学研究講演会
    • Place of Presentation
      静岡市清水文化会館マリナート(静岡市)
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 触媒的芳香族トリフルオロメチル化とその関連反応2015

    • Author(s)
      網井秀樹
    • Organizer
      名古屋大学大学院理学研究科講演会
    • Place of Presentation
      名古屋大学(名古屋市)
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 触媒的芳香族トリフルオロメチル化と関連反応の新開発2015

    • Author(s)
      網井秀樹
    • Organizer
      日本化学会関東支部埼玉地区学術講演会
    • Place of Presentation
      埼玉大学(さいたま市)
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Optical Properties of Silyl-Substituted Polyfluorobenzenes2015

    • Author(s)
      Masaki Ono and Hideki Amii
    • Organizer
      5th International Symposium on Element Innovation
    • Place of Presentation
      Kiryu City Performing Arts Center (Kiryu)
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ペンタフルオロエチル化ホウ素反応剤のクロスカップリング反応への応用2015

    • Author(s)
      河内大佑,佐藤瑞記,網井秀樹
    • Organizer
      平成27年度日本化学会関東支部群馬地区研究交流発表会
    • Place of Presentation
      群馬工業高等専門学校(前橋)
    • Related Report
      2015 Annual Research Report
  • [Presentation] シリル基を有するフッ素化芳香族化合物の光学的特性の調査2015

    • Author(s)
      小野雅樹,網井秀樹
    • Organizer
      平成27年度日本化学会関東支部群馬地区研究交流発表会
    • Place of Presentation
      群馬工業高等専門学校(前橋)
    • Related Report
      2015 Annual Research Report
  • [Presentation] 急進展する芳香族フルオロアルキル化反応2014

    • Author(s)
      網井秀樹
    • Organizer
      第19回有機フッ素化学セミナー(岡山)
    • Place of Presentation
      岡山大学(岡山市)
    • Year and Date
      2014-12-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] New Strategies for Aromatic Fluoroalkylation2014

    • Author(s)
      Hideki Amii
    • Organizer
      Japan/Russian Conference on Fluorine Chemistry and Friends 2014
    • Place of Presentation
      Nagoya Institute of Technology (Nagoya)
    • Year and Date
      2014-12-08 – 2014-12-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Decarboxylative Transformations for the Synthesis of Aromatic Compounds bearing Functionalized Difluoromethyl Groups2014

    • Author(s)
      Hitomi Kimura, Eri Tomizawa, Tatsuya Kawamatsu, and Hideki Amii
    • Organizer
      The Ninth International Symposium on the Integrated Synthesis (ISIS-9)
    • Place of Presentation
      Awaji Yumebutai International Conference Center (Awaji)
    • Year and Date
      2014-11-14 – 2014-11-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] Generation and Synthetic Applications of Trifluoromethyl Isobenzofurans2014

    • Author(s)
      Hideki Amii
    • Organizer
      Vietnam Malaysia International Chemical Congress (VMICC)
    • Place of Presentation
      Hanoi Daewoo Hotel (Hanoi, Vietnam)
    • Year and Date
      2014-11-07 – 2014-11-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 含フッ素置換基を有するフタリドの合成とその応用2014

    • Author(s)
      稲葉公則, 品田瞬, 仁科勇太, 網井秀樹
    • Organizer
      第37回フッ素化学討論会
    • Place of Presentation
      大阪府立男女共同参画・青少年センター(大阪市)
    • Year and Date
      2014-10-30 – 2014-10-31
    • Related Report
      2014 Annual Research Report
  • [Presentation] Aromatic Perfluoroalkylation Involving Copper-Catalyzed beta-Carbon Elimination2014

    • Author(s)
      Kazuki Komoda, Naoto Shimizu, and Hideki Amii
    • Organizer
      The 2nd International Conference on Organometallics and Catalysis
    • Place of Presentation
      Todaiji Temple Cultural Cente (Nara)
    • Year and Date
      2014-10-26 – 2014-10-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] ジフルオロシクロプロパン,シクロプロペンの合成,反応と特性2014

    • Author(s)
      網井秀樹
    • Organizer
      日本学術振興会フッ素化学第155委員会第98回研究会
    • Place of Presentation
      東京農工大学(東京都小金井市)
    • Year and Date
      2014-10-09 – 2014-10-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] パーフルオロアルキル基を導入したDimyristoylphosphatidylcholine二分子膜の物性・構造2014

    • Author(s)
      森田康平, 高橋浩, 網井秀樹, 高木俊之, 金森敏幸, 長谷川健, 園山正史
    • Organizer
      第8回分子科学討論会
    • Place of Presentation
      広島大学(広島県東広島市)
    • Year and Date
      2014-09-21 – 2014-09-24
    • Related Report
      2014 Annual Research Report
  • [Presentation] DMPCアシル鎖末端へのパーフルオロアルキル基導入による膜物性への影響2014

    • Author(s)
      森田康平, 高橋浩, 網井秀樹, 園山正史, 高木俊之, 金森敏幸, 長谷川健
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学(東京都新宿区)
    • Year and Date
      2014-09-03 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] 触媒的芳香族トリフルオロメチル化と関連反応2014

    • Author(s)
      網井秀樹
    • Organizer
      第30回若手化学者のための化学道場(有機合成化学協会中国四国支部主催)
    • Place of Presentation
      鷲羽山下電ホテル(岡山県倉敷市)
    • Year and Date
      2014-08-29 – 2014-08-30
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 触媒的芳香族トリフルオロメチル化と関連反応2014

    • Author(s)
      網井秀樹
    • Organizer
      第26回万有札幌シンポジウム ―有機合成化学の挑戦―
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2014-07-05
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] An Efficient Synthesis of Fluoroalkyl-Substituted Phthalides2014

    • Author(s)
      Masanori Inaba, Shun Shinada, Yuta Nishina, and Hideki Amii
    • Organizer
      International Conference on Fluorine Chemistry 2014 Tokyo (ICFC)
    • Place of Presentation
      PACIFICO YOKOHAMA (Yokohama)
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Decarboxylative Transformations for the Synthesis of gem-Difluoromethylene Compounds2014

    • Author(s)
      Hitomi Kimura, Eri Tomizawa, and Hideki Amii
    • Organizer
      International Conference on Fluorine Chemistry 2014 Tokyo (ICFC)
    • Place of Presentation
      PACIFICO YOKOHAMA (Yokohama)
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] 脱炭酸反応によるジフルオロメチレン化合物の新合成戦略2014

    • Author(s)
      網井秀樹
    • Organizer
      名古屋工業大学ナノライフものづくり研究会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 脱炭酸反応に基づく芳香族化合物への(α-チオフェニル)ジフルオロメチル基の導入2014

    • Author(s)
      木村仁美、富澤恵理、網井秀樹
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] フローマイクロリアクターを用いた2,2,2-トリフルオロ-1-(フェニルスルホニル)エチルカルバニオンの発生と反応2014

    • Author(s)
      網井秀樹、村田啓幸、永木愛一郎、吉田潤一
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] パーフルオロアルキル鎖長の異なるDMPCアナログ分子の合成と膜物性の解析2014

    • Author(s)
      森田康平、高橋 浩、網井秀樹、園山正史、高木俊之、金森敏幸・長谷川健
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋
    • Related Report
      2013 Annual Research Report
  • [Presentation] Generation and Synthetic Applications of Trifluoromethylated Isobenzofuran2013

    • Author(s)
      Hideki Amii
    • Organizer
      4th Japan-Korea-China Joint Seminar on Fluorine Chemistry
    • Place of Presentation
      Nagoya
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Catalytic Aromatic Trifluoromethylation and Related Reactions2013

    • Author(s)
      Hideki Amii
    • Organizer
      4th International Fluorine Workshop
    • Place of Presentation
      Tokyo
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 触媒的芳香族トリフルオロメチル化とその関連反応2013

    • Author(s)
      網井秀樹
    • Organizer
      近畿化学協会 合成部会・平成25年度第1回合成フォーラム
    • Place of Presentation
      尼崎
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 有機化合物への含フッ素官能基導入法:最近の進展2013

    • Author(s)
      網井秀樹
    • Organizer
      平成25年度物質・デバイス領域共同研究拠点 物質機能化学研究領域部会 第1回 研究集会~フッ素が切り拓く新材料科学~
    • Place of Presentation
      東京
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Copper-Catalyzed Aromatic Trifluoromethylation via β-Carbon Elimination2013

    • Author(s)
      Hideki Amii
    • Organizer
      17th European Symposium on Fluorine Chemistry
    • Place of Presentation
      Paris, France
    • Related Report
      2013 Annual Research Report
  • [Presentation] フッ素化合物合成におけるマイクロフロー・テクノロジー:最近の進展2013

    • Author(s)
      網井秀樹
    • Organizer
      近畿化学協会フロー・マイクロ合成研究会・第27回公開講演会
    • Place of Presentation
      大阪
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] フッ素官能基導入クロスカップリング反応の新展開2013

    • Author(s)
      網井秀樹
    • Organizer
      平成25年度 有機合成夏期セミナー「明日の有機合成化学」
    • Place of Presentation
      大阪
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] β-Carbon Elimination for Catalytic Aromatic Trifluoromethylation2013

    • Author(s)
      Hideki Amii
    • Organizer
      10th International Symposium on Carbanion Chemistry
    • Place of Presentation
      Kyoto
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 脱炭酸反応によるジフルオロメチレン化合物の合成2013

    • Author(s)
      富澤恵理、川松達矢、木村仁美、網井秀樹
    • Organizer
      第36回フッ素化学討論会
    • Place of Presentation
      筑波
    • Related Report
      2013 Annual Research Report
  • [Presentation] ケイ素置換ジフルオロシクロプロペンの光物性2013

    • Author(s)
      鈴木千春、霞 征和、網井秀樹
    • Organizer
      第36回フッ素化学討論会
    • Place of Presentation
      筑波
    • Related Report
      2013 Annual Research Report
  • [Presentation] フッ素系アルコールを活用する不斉触媒反応の創出2013

    • Author(s)
      網井秀樹
    • Organizer
      フルオラス科学研究会第6回シンポジウム
    • Place of Presentation
      岡山
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Synthetic Applications of Trifluoromethyl Isobenzofuran2013

    • Author(s)
      Y. Nishina, S. Shinada, and H. Amii
    • Organizer
      8th International Symposium on Integrated Synthesis (ISIS-8)
    • Place of Presentation
      Nara
    • Related Report
      2013 Annual Research Report
  • [Presentation] シクロプロペンの共役系有機分子としての可能性探索2013

    • Author(s)
      鈴木千春、霞 征和、網井秀樹
    • Organizer
      第7回有機π電子系シンポジウム
    • Place of Presentation
      高崎
    • Related Report
      2013 Annual Research Report
  • [Book] フッ素化学入門20152015

    • Author(s)
      網井秀樹(分担執筆), (独)日本学術振興会編・フッ素化学第155委員会 編
    • Total Pages
      357
    • Publisher
      三共出版
    • Related Report
      2014 Annual Research Report
  • [Book] フッ素の化学 in ”炭素とケイ素の元素科学”2014

    • Author(s)
      網井秀樹, 鈴木千春, 高橋綾(分担執筆), 海野雅史編集, 松本英之・大谷朝男監修
    • Publisher
      群馬大学エレメントイノベーション
    • Related Report
      2014 Annual Research Report
  • [Book] Encyclopedia of Reagents for Organic Synthesis2013

    • Author(s)
      H. Amii, Y. Katahira, and A. Kobayashi
    • Publisher
      Wiley
    • Related Report
      2013 Annual Research Report
  • [Patent(Industrial Property Rights)] ジフルオロメチレン化合物の製造方法2013

    • Inventor(s)
      網井秀樹, 富澤恵理, 木村仁美, 瀧花亮三
    • Industrial Property Rights Holder
      国立大学法人群馬大学、セントラル硝子株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-206694
    • Filing Date
      2013-10-01
    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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