| Budget Amount *help |
¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2013: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
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| Outline of Final Research Achievements |
In order to promote the cross-coupling reaction of organometallic compounds with aryl halides, the aid of transition metal catalysis has been considered to be indispensable. By utilizing a single electron as a catalyst, we have developed the transition metal-free cross-coupling reactions of aryl halides with organometallic compounds such as arylmagnesium, arylzinc, alkylzinc, alkynylzinc and arylboron reagents, as well as magnesium diarylamides and benzene derivatives.
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