Transition Metal-Free Cross-Coupling Reactions of Organometallic Compounds
| Project/Area Number |
25288046
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kwansei Gakuin University (2015)
Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2014: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2013: ¥9,490,000 (Direct Cost: ¥7,300,000、Indirect Cost: ¥2,190,000)
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| Keywords | クロスカップリング反応 / ラジカル反応 / ハロゲン化アリール / 有機合成化学 / 有機化学 |
|---|
| Outline of Final Research Achievements |
In order to promote the cross-coupling reaction of organometallic compounds with aryl halides, the aid of transition metal catalysis has been considered to be indispensable. By utilizing a single electron as a catalyst, we have developed the transition metal-free cross-coupling reactions of aryl halides with organometallic compounds such as arylmagnesium, arylzinc, alkylzinc, alkynylzinc and arylboron reagents, as well as magnesium diarylamides and benzene derivatives.
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Report
(4 results)
Research Products
(21 results)
