Synthesis of linear and branched oligomers with the coupling reaction of heteroaromatic compounds
| Project/Area Number |
25288049
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kobe University |
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Principal Investigator |
Mori Atsunori 神戸大学, 工学(系)研究科(研究院), 教授 (90210111)
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| Co-Investigator(Renkei-kenkyūsha) |
UEDA Yasukiyo 神戸大学, 大学院・工学研究科, 教授 (40116190)
SUGIE Atsushi 神戸大学, 大学院・工学研究科, 助教 (80605907)
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| Project Period (FY) |
2013-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2016: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2015: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2014: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2013: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
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| Keywords | ヘテロ芳香族化合物 / 分岐状オリゴマー / 鎖状オリゴマー / Ｃ－Ｈカップリング / 遷移金属触媒 / ヘテロ芳香族 / オリゴチオフェン / ポリチオフェン / カップリング反応 / チオフェン / チエニレンビニレン / 溝呂木－Heck型反応 / C-Hカップリング / チエニレン－ビニレン / N-ヘテロ環状カルベン / シロキサン結合 / デンドリマー / ニッケル触媒 / 色素増感太陽電池 / カルバゾール / シアノアクリル酸 / 有機色素 / CHカップリング / 分岐状チオフェン / 太陽電池 |
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| Outline of Final Research Achievements |
Linear and branched heteroaromatic oligomers were synthesized using C-H coupling reactions catalyzed by transition metal complexes, in which tolerance of various functional groups were studied. Further functional group transformation reactions were developed to undergo additional extension of the heteroaromatic unit. Disiloxane moieties was successfully introduced into olikgothiophenes to improve solubilities towared organic solvents. Water-soluble group was also examined to introduce as a functional group. Heteroaromatic oligomers bearing vinylene spacer were also prepared.
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Report
(5 results)
Research Products
(48 results)
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[Presentation] つる巻き状分子不斉の創出2016
Author(s)
森 敦紀
Organizer
平成28年度有機合成化学北陸セミナー
Place of Presentation
石川県青少年総合研修センター（石川県・金沢市）
Year and Date
2016-10-07
Related Report
Invited
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