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Preparation of Organic-Inorganic Hybrid Monoliths and Their Functions

Research Project

Project/Area Number 25288090
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Organic and hybrid materials
Research InstitutionOsaka University

Principal Investigator

Uyama Hiroshi  大阪大学, 工学(系)研究科(研究院), 教授 (70203594)

Project Period (FY) 2013-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥18,590,000 (Direct Cost: ¥14,300,000、Indirect Cost: ¥4,290,000)
Fiscal Year 2015: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2014: ¥5,850,000 (Direct Cost: ¥4,500,000、Indirect Cost: ¥1,350,000)
Fiscal Year 2013: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Keywordsモノリス / 有機無機ハイブリッド / 相分離 / 多孔質体 / アフィニティークロマトグラフィー / 鈴木-宮浦カップリング / 固定化触媒 / セルロース / 抗菌性
Outline of Final Research Achievements

Monolith, a three-dimensional porous material having a continuous interconnected nanoscale pore structure in a single piece, has received much attention as functional materials. This study deals with development of functional organic-inorganic monoliths based on thermally induced phase separation technique for fabrication of polymer monoliths. For application of immobilized catalysts, Pd was loaded on monoliths of acrylic resin or poly(ethylene-co-vinyl alcohol), and the obtained organic-inorganic monolith was used as catalyst for Suzuki-Miyaura coupling. The metal-immobilized monolith was applied for matrix of affinity chromatography.

Report

(5 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (41 results)

All 2017 2016 2015 2014 2013 Other

All Int'l Joint Research (1 results) Journal Article (22 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 21 results,  Acknowledgement Compliant: 7 results) Presentation (17 results) (of which Int'l Joint Research: 8 results,  Invited: 16 results) Remarks (1 results)

  • [Int'l Joint Research] 西北大学(中国)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] A hierarchically porous cellulose monolith: A template-freefabricated, morphology-tunable, and easily functionalizable platform2017

    • Author(s)
      Y. Xin, Q. Xiong, Q. Bai, M. Miyamoto, C. Li, Y. Shen, H. Uyama
    • Journal Title

      Carbohydrate Polymers

      Volume: 157 Pages: 429-437

    • DOI

      10.1016/j.carbpol.2016.10.006

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Mesoporous Poly(ethylene-co-vinyl alcohol) Monolith Captured with Silver Nanoparticles as a SERS Substrate: Facile Fabrication and Ultra-High Sensitivity2015

    • Author(s)
      G. Wang, H. Yoshikawa, E. Tamiya, H. Uyama
    • Journal Title

      RSC Adv.

      Volume: 5 Issue: 33 Pages: 25777-25780

    • DOI

      10.1039/c5ra03585f

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] One-pot Fabrication of Palladium Nanoparticles Captured in Mesoporous Polymeric Monoliths and Their Catalytic Application in C-C Coupling Reactions2015

    • Author(s)
      G. Wang, D. Kundu, H. Uyama
    • Journal Title

      J. Colloid Interface Sci.

      Volume: 451 Pages: 184-188

    • DOI

      10.1016/j.jcis.2015.03.061

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Reactive Poly(ethylene-co-vinyl alcohol) Monoliths with Tunable Pore Morphology for Enzyme Immobilization2015

    • Author(s)
      G. Wang, H. Uyama
    • Journal Title

      Colloid Polym. Sci.

      Volume: 293 Issue: 8 Pages: 2429-2435

    • DOI

      10.1007/s00396-015-3637-1

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Phase Separation Approach to a Reactive Polycarbonate Monolith for “Click” Modifications2015

    • Author(s)
      Y. Xin, J. Sakamoto, A. J. van derVlies, U. Hasegawa, H. Uyama
    • Journal Title

      Polymer

      Volume: 66 Pages: 52-57

    • DOI

      10.1016/j.polymer.2015.04.008

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Facile Fabrication of Mesoporous Poly(ethylene-co-vinyl alcohol)/Chitosan Blend Monoliths2015

    • Author(s)
      G. Wang, Y. Xin, H. Uyama
    • Journal Title

      Carbohydr. Polym

      Volume: 132 Pages: 345-352

    • DOI

      10.1016/j.carbpol.2015.06.040

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Pepsin immobilization on an aldehyde-modified polymethacrylate monolith and its application for protein analysis2014

    • Author(s)
      Han, W., Yamauchi, M., Hasegawa, U., Noda, M., Fukui, K., van der Vlies, Uchiyama, S., and Uyama, H.
    • Journal Title

      J. Biosci. Bioeng.

      Volume: 119 Issue: 5 Pages: 505-510

    • DOI

      10.1016/j.jbiosc.2014.10.018

    • NAID

      110009962601

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Green Composite of Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) Reinforced with Porous Cellulose2014

    • Author(s)
      Nao Hosoda, Takashi Tsujimoto, Hiroshi Uyama
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 2 Issue: 2 Pages: 248-253

    • DOI

      10.1021/sc400290y

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In Situ Mineralization of Hydroxyapatite on Poly(vinyl alcohol) Monolithic Scaffolds for Tissue Engineering2014

    • Author(s)
      X. Sun, H. Uyama
    • Journal Title

      Colloid Polym. Sci.

      Volume: 292 Issue: 5 Pages: 1073-1078

    • DOI

      10.1007/s00396-013-3155-y

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Palladium-Loaded Mesoporous Polymer Monolith as Reusable Heterogeneous Catalyst for Cross-Coupling Reactions2014

    • Author(s)
      D. Kundu, A. K. Patra, J. Sakamoto, H. Uyama
    • Journal Title

      React. Funct. Polym.

      Volume: 79 Pages: 8-13

    • DOI

      10.1016/j.reactfunctpolym.2014.03.002

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Acid Functionalized Mesoporous PAN Monolith as Reusable Heterogeneous Organocatalyst2014

    • Author(s)
      A. K. Patra, D. Kundu, J. Sakamoto, H. Uyama
    • Journal Title

      Microporous Mesoporous Mater.

      Volume: 193 Pages: 122-126

    • DOI

      10.1016/j.micromeso.2014.03.024

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Porous Acrylate Monolith Supported Pd Nanoparticles: Highly Active and Reusable Catalyst for Suzuki-Miyaura Reaction in Water2014

    • Author(s)
      M. Nandi, H. Uyama
    • Journal Title

      RSC Adv.

      Volume: 4 Issue: 40 Pages: 20847-20855

    • DOI

      10.1039/c4ra02057j

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Poly(γ-glutamic acid)/Hydroxyapatite Monolith via Biomineralization for Bone Tissue Engineering2014

    • Author(s)
      S.-B. Park, U. Hasegawa, A. J. van der Vlies, M.-H. Sung, H. Uyama
    • Journal Title

      J. Biomater. Sci., Polym. Ed.

      Volume: 25 Issue: 17 Pages: 1875-1890

    • DOI

      10.1080/09205063.2014.953404

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enzyme Immobilization on Polymethacrylate-based Monolith Fabricated via Thermally Induced Phase Separation2014

    • Author(s)
      W. Han, Y. Xin, U. Hasegawa, H. Uyama
    • Journal Title

      Polym. Degrad. Stab.

      Volume: 109 Pages: 362-366

    • DOI

      10.1016/j.polymdegradstab.2014.05.032

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Facile Fabrication of Poly(methyl methacrylate) Monolith via Thermally Induced Phase Separation by Utilizing Unique Cosolvency2014

    • Author(s)
      S. Yoneda, W. Han, U. Hasegawa, H. Uyama
    • Journal Title

      Polymer

      Volume: 55 Issue: 15 Pages: 3212-3216

    • DOI

      10.1016/j.polymer.2014.05.031

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of poly(γ-glutamic acid) monolith by thermally induced phase separation and its application2013

    • Author(s)
      S. B. Park, T Fujimoto, E Mizohata, T Inoue, M.- H. Sung, and H. Uyama
    • Journal Title

      J. Microbiol. Biotechnol. 23

      Volume: 23 Pages: 942-952

    • DOI

      10.1016/j.polymdegradstab.2013.11.019

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Poly(γ-glutamic acid) Monolith by Thermally Induced Phase Separation and Its Application2013

    • Author(s)
      S.-Bin Park, T. Fujimoto, E. Mizohata, T. Inoue, M.-H. Sung, H. Uyama
    • Journal Title

      J. Microbiol. Biotechnol

      Volume: 23 Issue: 7 Pages: 942-952

    • DOI

      10.4014/jmb.1302.02030

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Polyethylenimine-modified Monolith and Its Application for Copper Ion Adsorption2013

    • Author(s)
      Y. Xin, H. Uyama
    • Journal Title

      Polym. Res. J.

      Volume: 7 Pages: 149-158

    • Related Report
      2013 Annual Research Report
  • [Journal Article] Fabrication of a Poly(vinyl alcohol) Monolith via Thermally Impacted Non-Solvent-Induced Phase Separation2013

    • Author(s)
      X. Sun, T. Fujimoto, H. Uyama
    • Journal Title

      Polym. J

      Volume: 45 Issue: 10 Pages: 1101-1106

    • DOI

      10.1038/pj.2013.18

    • NAID

      10031200090

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication and Electrochemical Capacitive Behaviors of a Carbon Nanotube-Coated Polymer Monolith2013

    • Author(s)
      K. Okada, J. Maruyama, H. Uyama
    • Journal Title

      Electrochemistry

      Volume: 81 Issue: 10 Pages: 789-791

    • DOI

      10.5796/electrochemistry.81.789

    • NAID

      10031191942

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Macroscopic Cavities within A Microporous 3-D Network: A Poly(γ-glutamic acid) Monolith Prepared by Combination of Particulate Templates and a Phase Separation Technique2013

    • Author(s)
      S.-Bin Park, J. Sakamoto, M.-H. Sung, H. Uyama
    • Journal Title

      Polymer

      Volume: 22 Issue: 22 Pages: 6114-6118

    • DOI

      10.1016/j.polymer.2013.09.014

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Poly(vinyl alcohol)/Sodium Alginate Blend Monolith with Nanoscale Porous Structure2013

    • Author(s)
      X. Sun, H. Uyama
    • Journal Title

      Nanoscale Res. Lett.

      Volume: 8 Issue: 1 Pages: 411-415

    • DOI

      10.1186/1556-276x-8-411

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] Fabrication of Functional Porous Materials by Phase Separation2017

    • Author(s)
      H. Uyama
    • Organizer
      Pure and Applied Chemistry International Conference 2017 (PACCON 2017)
    • Place of Presentation
      Centra Government Complex Hotel & Convention Centre(バンコク、タイ)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication of Mesoporous Polymer Monoliths by Phase Separation2016

    • Author(s)
      H. Uyama
    • Organizer
      EMN Meeting on Mesoporous Materials
    • Place of Presentation
      Grandior Prague Hotel(プラハ、チェコ)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication of Functional Porous Polymeric Nanomaterials by Phase Separation2016

    • Author(s)
      H. Uyama
    • Organizer
      Science & Technology-2016
    • Place of Presentation
      Holiday Inn Singapore Atrium(シンガポール)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication of Functional Porous Polymeric Nanomaterials by Phase Separation2016

    • Author(s)
      H. Uyama
    • Organizer
      BIT’S Annual World Congress of Smart Materials
    • Place of Presentation
      Grand Copthorne Waterfront Hotel(シンガポール)
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] バイオポリマーの多孔化技術と用途展開2015

    • Author(s)
      宇山 浩
    • Organizer
      第87回高分子材料セミナー
    • Place of Presentation
      日本材料学会(京都市)
    • Year and Date
      2015-01-30
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 相分離を利用した機能性モノリスの開発2015

    • Author(s)
      宇山 浩
    • Organizer
      産学高分子研究会
    • Place of Presentation
      大阪大学待兼山会館(豊中市)
    • Related Report
      2015 Annual Research Report
  • [Presentation] Fabrication of Porous Monolithic Materials of Reactive Polymers for Protein Purification2015

    • Author(s)
      H. Uyama
    • Organizer
      International Conference and Expo on Separation Techniques
    • Place of Presentation
      DoubleTree by Hilton Hotel San Francisco Airport(サンフランシスコ、アメリカ)
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Reactive Polymer Monoliths for Bio-related Applications2015

    • Author(s)
      H. Uyama
    • Organizer
      International Conference and Expo on Separation Techniques
    • Place of Presentation
      DoubleTree by Hilton Hotel San Francisco Airport(サンフランシスコ、アメリカ)
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Recent Progress on Functional Polymer Monoliths Prepared2015

    • Author(s)
      H. Uyama
    • Organizer
      Japan-Taiwan Bilateral Workshop on Nano-Science 2015
    • Place of Presentation
      大阪大学銀杏会館(吹田市)
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabrication of Functional Porous Polymeric Materials by Phase Separation2015

    • Author(s)
      H. Uyama
    • Organizer
      IUPAC 11th International Conference on Advanced Polymers via Macromolecular Engineering
    • Place of Presentation
      横浜パシフィコ(横浜市)
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Fabriacation of Functional Porous Polymeric Materials by Phase Separation2014

    • Author(s)
      H. Uyama
    • Organizer
      IUPAC 10th International Conference on Novel Materials and Their Synthesis
    • Place of Presentation
      Zhengzhou (Korea)
    • Year and Date
      2014-10-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 相分離を利用した機能性モノリスの開発2014

    • Author(s)
      宇山 浩
    • Organizer
      産学高分子研究会
    • Place of Presentation
      大阪大学待兼山会館(豊中市)
    • Year and Date
      2014-06-02
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 高分子ナノ多孔体-多様な用途開発に向けた新展開-

    • Author(s)
      宇山 浩
    • Organizer
      第26回環境工学連合講演会
    • Place of Presentation
      日本学術会議講堂
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Fabrication of Functional Porous Polymeric Materials by Phase Separation

    • Author(s)
      H. Uyama
    • Organizer
      Collaborative Conference on 3D & Materials Research
    • Place of Presentation
      Jeju (Korea)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Fabrication of Functional Porous Materials of Biobased Polymers by Phase Separation

    • Author(s)
      H. Uyama
    • Organizer
      The 4th International Conference on Biobased Polymers
    • Place of Presentation
      Seoul (Korea)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Fabrication of Functional Porous Materials of Biobased Polymers by Phase Separation

    • Author(s)
      H. Uyama
    • Organizer
      Japan-Taiwan Bilateral Workshop on Nano-Science 2013
    • Place of Presentation
      鹿児島大学
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] Functional Polymer Monoliths with Nanoscale Porous Structure

    • Author(s)
      H. Uyama
    • Organizer
      3rd International Conference on Nanotek & Expo
    • Place of Presentation
      Las Vegas (USA)
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Remarks] 大阪大学大学院工学研究科応用化学専攻宇山研究室

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~uyamaken/

    • Related Report
      2013 Annual Research Report

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Published: 2013-05-21   Modified: 2019-07-29  

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