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Analysis on crystallization behaviors of bi-axially oriented films with various processing histories

Research Project

Project/Area Number 25288097
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Polymer/Textile materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

Kikutani Takeshi  東京工業大学, 理工学研究科, 教授 (70153046)

Co-Investigator(Kenkyū-buntansha) TAKARADA Wataru  東京工業大学, 大学院理工学研究科, 助教 (50467031)
UMEMOTO Susumu  東京工業大学, 大学院理工学研究科, 助教 (90168758)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥15,470,000 (Direct Cost: ¥11,900,000、Indirect Cost: ¥3,570,000)
Keywords結晶化速度 / 分子配向 / ポリエチレンテレフタレート / 一軸配向 / 二軸配向 / 高分子 / 配向 / フィルム / 繊維 / 配向結晶化 / 収縮 / 配向緩和
Outline of Final Research Achievements

Crystallization rate of oriented poly(ethylene terephthalate) (PET) was investigated using high-speed DSC analysis. Quantitative analysis method was established by applying pre-thermal treatment to remove thermal shrinkage. There was a difference between uni-axially oriented fibers and equi-biaxially oriented films on the Avrami index and the trend of crystallization rate to crystallization temperature. In addition, uni-axialli orientation had greater effect on crystallization rate than qui-biaxially orientation in same degree of orientation if that of equi-biaxially oriented film was calculated based on intrinsic birefringence of planner orientation, 0.122.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Annual Research Report
  • 2013 Annual Research Report
  • Research Products

    (14 results)

All 2016 2015 2014 Other

All Journal Article (2 results) (of which Peer Reviewed: 1 results) Presentation (12 results) (of which Int'l Joint Research: 2 results,  Invited: 2 results)

  • [Journal Article] Crystallization of poly(ethylene terephthalate) filaments by infusion of ethanol upon cold drawing2015

    • Author(s)
      Rina Khanum, Wataru Takarada, Arun Aneja, Takeshi Kikutani
    • Journal Title

      Polymer

      Volume: 59 Pages: 26-34

    • DOI

      10.1016/j.polymer.2014.12.071

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Morphology and crystallization behavior of nylon 6-clay/neat nylon 6 bicomponent nanocomposite fibers2014

    • Author(s)
      Shahin Kazemi, Mohammad Reza Mohaddes Mojtahedi, Wataru Takarada, Takeshi Kikutani
    • Journal Title

      Journal of Applied Polymer Science

      Volume: 131 Issue: 6

    • DOI

      10.1002/app.39996

    • Related Report
      2013 Annual Research Report
  • [Presentation] Analysis on crystallization behavior of oriented poly(ethylene terephthalate) fibers and films2016

    • Author(s)
      Seiji Shibata, Wataru Takarada, Takeshi Kikutani
    • Organizer
      Polymer Processing Society 32th annual meeting
    • Place of Presentation
      Lyon, France
    • Year and Date
      2016-07-25
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 一軸及び二軸配向ポリエチレンテレフタレートの結晶化速度解析2016

    • Author(s)
      柴田晟至 , 宝田亘 , 鞠谷雄士
    • Organizer
      第65回高分子学会年次大会
    • Place of Presentation
      神戸
    • Year and Date
      2016-05-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] Analysis on crystallization behavior of equi-biaxially stretched amorphous poly(ethylene terephthalate) films2015

    • Author(s)
      Seiji Shibata, Wataru Takarada, Takeshi Kikutani
    • Organizer
      AWPP2015
    • Place of Presentation
      Singapore
    • Year and Date
      2015-12-01
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 配向非晶ポリエチレンテレフタレートフィルムの冷結晶化挙動解析2015

    • Author(s)
      柴田晟至 , 宝田亘 , 鞠谷雄士
    • Organizer
      平成27年度 繊維学会秋季研究発表会
    • Place of Presentation
      京都
    • Year and Date
      2015-10-22
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高速DSCを用いた配向非晶ポリエチレンテレフタレートフィルムの結晶化挙動解析2015

    • Author(s)
      柴田晟至 , 宝田亘 , 鞠谷雄士
    • Organizer
      第26回成形加工学会年次大会
    • Place of Presentation
      東京
    • Year and Date
      2015-06-03
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高速DSCを用いた配向非晶ポリエチレンテレフタレート繊維の結晶化挙動解析2014

    • Author(s)
      柴田晟至 , 宝田亘 , 鞠谷雄士
    • Organizer
      成形加工シンポジア ’14
    • Place of Presentation
      朱鷺メッセ(新潟・新潟市)
    • Year and Date
      2014-11-06 – 2014-11-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] Analysis on crystallization behavior of oriented polymers utilizing differential scanning calorimetry of high heating rate2014

    • Author(s)
      Seiji Shibata, Wataru Takarada, Takeshi Kikutani
    • Organizer
      International Symposium on Fiber Science and Technology
    • Place of Presentation
      Tokyo Fashion Town Building (Koto-ku, Tokyo, Japan)
    • Year and Date
      2014-09-29 – 2014-10-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] 溶融紡糸・延伸法による中空糸膜の製造における未延伸糸の構造と中空糸膜の性能の関係2014

    • Author(s)
      杉浦聡, 宝田亘, 鞠谷雄士
    • Organizer
      高分子討論会
    • Place of Presentation
      長崎大(長崎・長崎市)
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of polymer viscosities on the fiber structure and membrane properties of polypropylene / polyethylene bicomponent hollow fibers2014

    • Author(s)
      Satoshi Sugiura, Wataru Takarada, Takeshi Kikutani
    • Organizer
      Polymer Processing Society 30th annual meeting
    • Place of Presentation
      Cleveland, USA
    • Year and Date
      2014-06-08 – 2014-06-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Film stretching behavior - fundamental analysis through in-situ measurements

    • Author(s)
      Takeshi Kikutani
    • Organizer
      Polymer Processing Society Asia/Australia Conference
    • Place of Presentation
      Mumbai, India
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Presentation] 高速DSCを用いた配向高分子の結晶化挙動解析

    • Author(s)
      柴田晟至,宝田亘,鞠谷雄士
    • Organizer
      繊維製品消費科学会 関東支部 第48回卒業論分発表会
    • Place of Presentation
      共立女子大学
    • Related Report
      2013 Annual Research Report
  • [Presentation] Contribution of Flow-Induced Crystallization on Surface Roughness Development In Melt Spinning of Blend Fibers for Artificial Hair

    • Author(s)
      Takeshi Kikutani
    • Organizer
      AWPP2013
    • Place of Presentation
      Goa, India
    • Related Report
      2013 Annual Research Report
    • Invited

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Published: 2013-05-21   Modified: 2019-07-29  

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